Nickel carbonate

ChemicalBook > CAS DataBase List > Nickel carbonate

Product Name: Nickel carbonate
CAS No.: 3333-67-3
Chemical Name: Nickel carbonate
Synonyms: NICKEL(II) CARBONATE;ci77779;c.i.77779;cino77779;NICKEL CARBONATE;nickle carbonate;Nickel(II)Carbona;nickelmonocarbonate;nickel(2+)carbonate;NICKELOUS CARBONATE
CBNumber: CB1374836
Molecular Formula: CNiO3
Formula Weight: 118.7
MOL File: 3333-67-3.mol

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Nickel carbonate Property

Melting point:: decomposes [CRC10]
Density: 4.390
solubility: soluble in dilute acid solutions
form: Solid
color: Light Green
Water Solubility: Soluble in dilute acids. Insoluble in cold water.
Solubility Product Constant (Ksp): pKsp: 6.85
Exposure limits: ACGIH: TWA 0.2 mg/m3
NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3
Stability:: Stable. Incompatible with strong acids.
CAS DataBase Reference: 3333-67-3(CAS DataBase Reference)
EPA Substance Registry System: Nickel carbonate (3333-67-3)

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Safety

Hazard Codes: Xn,N
Risk Statements: 22-40-43-50/53
Safety Statements: 22-36/37-60-61
RIDADR: UN3077
RTECS: QR6200000
TSCA: Yes
HazardClass: 9
PackingGroup: III
HS Code: 2836991780
Hazardous Substances Data: 3333-67-3(Hazardous Substances Data)

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H317May cause an allergic skin reaction

H332Harmful if inhaled

H334May cause allergy or asthma symptoms or breathing difficulties if inhaled

H341Suspected of causing genetic defects

H350May cause cancer

H360May damage fertility or the unborn child

H372Causes damage to organs through prolonged or repeated exposure

H400Very toxic to aquatic life

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P201Obtain special instructions before use.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P284Wear respiratory protection.

P405Store locked up.

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N-Bromosuccinimide Price

Alfa Aesar

Product number: 022897
Product name: Nickel(II) carbonate, anhydrous, 98%
Packaging: 50g
Price: $57.6
Updated: 2024/03/01

Alfa Aesar

Product number: 022897
Product name: Nickel(II) carbonate, anhydrous, 98%
Packaging: 250g
Price: $181
Updated: 2024/03/01

Oakwood

Product number: 094638
Product name: Nickel(II)carbonate
Purity: 99%
Packaging: 1Kg
Price: $100
Updated: 2021/12/16

Oakwood

Product number: 094638
Product name: Nickel(II)carbonate
Purity: 99%
Packaging: 25g
Price: $15
Updated: 2021/12/16

AK Scientific

Product number: V0090
Product name: Nickel(II)carbonate
Packaging: 5g
Price: $21
Updated: 2021/12/16

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Nickel carbonate Chemical Properties,Usage,Production

Chemical Properties

Nickel carbonate is a light green crystalline substance, which is almost insoluble (0.093 g/L) in water (25°C), nonsoluble in hot water, and soluble in acids. Nickel carbonate is available primarily as basic nickel carbonate (NiCO3· 2Ni(OH)2 · 4H2O), which is not soluble in water and soluble in ammonia and dilute acids. In the natural environment, nickel carbonate tetrahydrate can be found as zaratite.

Physical properties

NiCO₃: Light green rhombohedral crystals; decomposes on heating; practically insoluble in water, 93 mg/L at 25°C; dissolves in acids.
2NiCO₃?3Ni(OH)₂?4H₂O: Light green crystals or brown powder; decomposes on heating; insoluble in water; decomposes in hot water; soluble in acids and in ammonium salts solutions.
Zaratite: Emerald greed cubic crystals; density 2.6 g/cm³; insoluble in water; soluble in ammonia and dilute acids.

Uses

Nickel(II) carbonate is used in sulphamate baths, metal phosphating, electroplating and ceramic applications. It acts as a precursor to catalysts and an intermediate in the hydrometallurgical purification of nickel from its ores.

Uses

Nickel carbonate is used to prepare nickel catalysts and several specialty compounds of nickel. It also is used as a neutralizing agent in nickel plating solutions. Other applications are in coloring glass and in the manufacture of ceramic pigments.

Preparation

Anhydrous nickel carbonate is produced as a precipitate when calcium carbonate is heated with a solution of nickel chloride in a sealed tube at 150°C. Alternatively, treating nickel powder with ammonia and carbon dioxide followed by boiling off ammonia yields pure carbonate.
When sodium carbonate is added to a solution of Ni(II) salts, basic nickel carbonate precipitates out in impure form.

Reactions

Nickel carbonate is the starting material for preparing many nickel salts. It reacts with dilute acids evolving carbon dioxide, and upon evaporation of the solution corresponding nickel salts are formed. The nitrate, sulfate and phosphate salts are prepared from carbonate. Similarly, reactions with hydrofluoric, hydrochloric, hydrobromic, or hydriodic acids yield hydrated nickel halides: namely NiF2•4H2O, NiCl2•6H2O, NiBr2•6H2O, and NiI2•6H2O, respectively:
NiCO3 + HCl → NiCl2•6H2O + CO2
NICKEL CARBONATE 611Nickel carbonate decomposes to nickel oxide when strongly ignited:
NiCO3 → NiO + CO2
Nickel carbonate, when dissolved in aqueous thiocyanic acid, yields a yellow brown precipitate of hydrated nickel thiocyanate:
2 NiCO3 + 2HSCN → Ni(SCN)2 + CO2 + H2O
Nickel carbonate forms many double salts, such as, Na2CO3•NiCO3•10H2O with alkali metal carbonates. However, such double carbonates usually are prepared by mixing an alkali metal or ammonium bicarbonate solution with a nickel salt solution, followed by crystallization.

Hazard

Confirmed carcinogen.

Safety Profile

Confirmed human carcinogen. When heated to decomposition it emits toxic vapors of nickel.

Nickel carbonate Preparation Products And Raw materials

Raw materials

Nitric acid Sulfuric acid Sodium carbonate

Preparation Products

Nickel chloride Nickel(II) chloride hexahydrate Nickel bis(sulphamidate) Nickel(II) oxide Cobalt acetate Nickelous acetate Nickel(II) nitrate hexahydrate Nickel oxide Nickel(II) acetate tetrahydrate Nickel sulfate hexahydrate Nickel fluoride 1-HYDROXY-2-BUTANONE

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View Lastest Price from Nickel carbonate manufacturers

HebeiShuoshengImportandExportco.,Ltd

Product: Nickel carbonate 3333-67-3
Price: US $6.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 2000KG/Month
Release date: 2024-08-02

Hebei Zhuanglai Chemical Trading Co.,Ltd

Product: Nickel Carbonate 3333-67-3
Price: US $120.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 10ton
Release date: 2024-05-21

Hebei Longbang Technology Co., Ltd

Product: Nickel carbonate 3333-67-3
Price: US $6.00/kg
Min. Order: 1kg
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Supply Ability: 2000KG/Month
Release date: 2024-05-20

3333-67-3, Nickel carbonateRelated Search:

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nickelmonocarbonate

PHENOLSTANDARD,SOLUTION

Nickel Carbonate, Powder

Carbonic acid nickel(II) salt

Nickel (II) carbonate≥98%

c.i.77779

carbonicacid,nickel(2+)salt

Carbonicacid,nickel(2+)salt(1:1)

carbonicacid,nickel(2++)salt(1:1)

Carbonicacid,nickelsalt

carbonicacid,nickelsalt(1:1)

NICKELOUS CARBONATE PWD

cino77779

nickel(2+)carbonate

nickel(2+)carbonate(nico3)

Nickel(II)Carbona

nickel(ii)carbonate(1:1)

nickelcarbonate(1:1)

NICKELCARBONATE,99.998%

NICKEL HYDROXIDE CARBONATE

NICKEL CARBONATE (OUS)

NICKEL CARBONATE

NICKEL(II) CARBONATE

NICKELOUS CARBONATE

ci77779

Nickel carbonate anhydrous

nickle carbonate

3333-67-3

NiCO3

CH2O3NI

Inorganics

INORGANIC & ORGANIC CHEMICALS