ChemicalBook > CAS DataBase List > Nickel carbonate

Nickel carbonate

Product Name
Nickel carbonate
CAS No.
3333-67-3
Chemical Name
Nickel carbonate
Synonyms
NICKEL(II) CARBONATE;ci77779;c.i.77779;cino77779;NICKEL CARBONATE;nickle carbonate;Nickel(II)Carbona;nickelmonocarbonate;nickel(2+)carbonate;NICKELOUS CARBONATE
CBNumber
CB1374836
Molecular Formula
CNiO3
Formula Weight
118.7
MOL File
3333-67-3.mol
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Nickel carbonate Property

Melting point:
decomposes [CRC10]
Density 
4.390
solubility 
soluble in dilute acid solutions
form 
Solid
color 
Light Green
Water Solubility 
Soluble in dilute acids. Insoluble in cold water.
Solubility Product Constant (Ksp)
pKsp: 6.85
Exposure limits
ACGIH: TWA 0.2 mg/m3
NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3
Stability:
Stable. Incompatible with strong acids.
CAS DataBase Reference
3333-67-3(CAS DataBase Reference)
EPA Substance Registry System
Nickel carbonate (3333-67-3)
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Safety

Hazard Codes 
Xn,N
Risk Statements 
22-40-43-50/53
Safety Statements 
22-36/37-60-61
RIDADR 
UN3077
RTECS 
QR6200000
TSCA 
Yes
HazardClass 
9
PackingGroup 
III
HS Code 
2836991780
Hazardous Substances Data
3333-67-3(Hazardous Substances Data)
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H317May cause an allergic skin reaction

H332Harmful if inhaled

H334May cause allergy or asthma symptoms or breathing difficulties if inhaled

H341Suspected of causing genetic defects

H350May cause cancer

H360May damage fertility or the unborn child

H372Causes damage to organs through prolonged or repeated exposure

H400Very toxic to aquatic life

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P201Obtain special instructions before use.

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P284Wear respiratory protection.

P405Store locked up.

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N-Bromosuccinimide Price

Alfa Aesar
Product number
022897
Product name
Nickel(II) carbonate, anhydrous, 98%
Packaging
50g
Price
$57.6
Updated
2024/03/01
Alfa Aesar
Product number
022897
Product name
Nickel(II) carbonate, anhydrous, 98%
Packaging
250g
Price
$181
Updated
2024/03/01
Oakwood
Product number
094638
Product name
Nickel(II)carbonate
Purity
99%
Packaging
1Kg
Price
$100
Updated
2021/12/16
Oakwood
Product number
094638
Product name
Nickel(II)carbonate
Purity
99%
Packaging
25g
Price
$15
Updated
2021/12/16
AK Scientific
Product number
V0090
Product name
Nickel(II)carbonate
Packaging
5g
Price
$21
Updated
2021/12/16
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Nickel carbonate Chemical Properties,Usage,Production

Chemical Properties

Nickel carbonate is a light green crystalline substance, which is almost insoluble (0.093 g/L) in water (25°C), nonsoluble in hot water, and soluble in acids. Nickel carbonate is available primarily as basic nickel carbonate (NiCO3· 2Ni(OH)2 · 4H2O), which is not soluble in water and soluble in ammonia and dilute acids. In the natural environment, nickel carbonate tetrahydrate can be found as zaratite.

Physical properties

NiCO3: Light green rhombohedral crystals; decomposes on heating; practically insoluble in water, 93 mg/L at 25°C; dissolves in acids.
2NiCO3?3Ni(OH)2?4H2O: Light green crystals or brown powder; decomposes on heating; insoluble in water; decomposes in hot water; soluble in acids and in ammonium salts solutions.
Zaratite: Emerald greed cubic crystals; density 2.6 g/cm3; insoluble in water; soluble in ammonia and dilute acids.

Uses

Nickel(II) carbonate is used in sulphamate baths, metal phosphating, electroplating and ceramic applications. It acts as a precursor to catalysts and an intermediate in the hydrometallurgical purification of nickel from its ores.

Uses

Nickel carbonate is used to prepare nickel catalysts and several specialty compounds of nickel. It also is used as a neutralizing agent in nickel plating solutions. Other applications are in coloring glass and in the manufacture of ceramic pigments.

Preparation

Anhydrous nickel carbonate is produced as a precipitate when calcium carbonate is heated with a solution of nickel chloride in a sealed tube at 150°C. Alternatively, treating nickel powder with ammonia and carbon dioxide followed by boiling off ammonia yields pure carbonate.
When sodium carbonate is added to a solution of Ni(II) salts, basic nickel carbonate precipitates out in impure form.

Reactions

Nickel carbonate is the starting material for preparing many nickel salts. It reacts with dilute acids evolving carbon dioxide, and upon evaporation of the solution corresponding nickel salts are formed. The nitrate, sulfate and phosphate salts are prepared from carbonate. Similarly, reactions with hydrofluoric, hydrochloric, hydrobromic, or hydriodic acids yield hydrated nickel halides: namely NiF2•4H2O, NiCl2•6H2O, NiBr2•6H2O, and NiI2•6H2O, respectively:
NiCO3 + HCl → NiCl2•6H2O + CO2
NICKEL CARBONATE 611Nickel carbonate decomposes to nickel oxide when strongly ignited:
NiCO3 → NiO + CO2
Nickel carbonate, when dissolved in aqueous thiocyanic acid, yields a yellow brown precipitate of hydrated nickel thiocyanate:
2 NiCO3 + 2HSCN → Ni(SCN)2 + CO2 + H2O
Nickel carbonate forms many double salts, such as, Na2CO3•NiCO3•10H2O with alkali metal carbonates. However, such double carbonates usually are prepared by mixing an alkali metal or ammonium bicarbonate solution with a nickel salt solution, followed by crystallization.

Hazard

Confirmed carcinogen.

Safety Profile

Confirmed human carcinogen. When heated to decomposition it emits toxic vapors of nickel.

Nickel carbonate Preparation Products And Raw materials

Raw materials

Nitric acid Sulfuric acid Sodium carbonate

Preparation Products

Nickel chloride Nickel(II) chloride hexahydrate Nickel bis(sulphamidate) Nickel(II) oxide Cobalt acetate Nickelous acetate Nickel(II) nitrate hexahydrate Nickel oxide Nickel(II) acetate tetrahydrate Nickel sulfate hexahydrate Nickel fluoride 1-HYDROXY-2-BUTANONE
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Nickel carbonate Suppliers

Argentina 1 Australia 2 Belgium 3 Brazil 1 Canada 3 China 230 Europe 1 France 1 Germany 4 India 74 Italy 1 Japan 4 Malaysia 1 Mexico 4 Russia 1 Singapore 1 South Korea 1 The Netherlands 1 United Kingdom 8 United States 48 Global 390
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View Lastest Price from Nickel carbonate manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
Nickel Carbonate 3333-67-3
Price
US $120.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
10ton
Release date
2024-05-21
Hebei Saisier Technology Co., LTD
Product
Nickel carbonate 3333-67-3
Price
US $6.00/KG
Min. Order
1KG
Purity
More than 99%
Supply Ability
2000KG/Month
Release date
2024-04-30
Hebei Mujin Biotechnology Co.,Ltd
Product
Nickel Carbonate 3333-67-3
Price
US $15.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20ton
Release date
2021-10-09

3333-67-3, Nickel carbonateRelated Search:

Pralmorelin Diphenolic acid Sodium carbonate 4-(Diethylamino)salicylaldehyde Calcium carbonate 5-Chlorovaleric acid Dimethyl carbonate Nickel sulfate DL-α-Tocopherol LANTHANUM CARBONATE POTASSIUM CARBONATE, SESQUIHYDRATE HOLMIUM CARBONATE Guanidine carbonate SODIUM CARBONATE, MONOHYDRATE Ethyl methyl carbonate Cobalt carbonate Magnesium carbonate hydrate Potassium carbonate

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