N-Methyl-4-nitroaniline

Uses Biodegradation

Product Name: N-Methyl-4-nitroaniline
CAS No.: 100-15-2
Chemical Name: N-Methyl-4-nitroaniline
Synonyms: Nitronaniline;4-nitro-n-methylaniline;Methyl-4-nitroaniline;N-methy-4-nitroanline;Intedanib Impurity 10;N-Methyl-p-nitraniline;Miglinide intermediate;N-METHYL-P-NITROANILINE;N-METHYL-4-NITROANILINE;P-NITRO-N-METHYLANILINE
CBNumber: CB1387643
Molecular Formula: C7H8N2O2
Formula Weight: 152.15
MOL File: 100-15-2.mol

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N-Methyl-4-nitroaniline Property

Melting point:: 149-151 °C(lit.)
Boiling point:: 294.61°C (rough estimate)
Density: 1.2010
vapor density: 5.25 (vs air)
refractive index: 1.6276 (estimate)
storage temp.: Keep in dark place,Inert atmosphere,Room temperature
solubility: Chloroform (Slightly), Methanol (Slightly)
form: Solid
pka: 0.56±0.12(Predicted)
color: Yellow to Very Dark Yellow
Water Solubility: <0.1 g/100 mL at 19 ºC
BRN: 637920
Stability:: Stable. Combustible. Incompatible with strong oxidizing agents.
InChIKey: XIFJZJPMHNUGRA-UHFFFAOYSA-N
CAS DataBase Reference: 100-15-2(CAS DataBase Reference)
NIST Chemistry Reference: Benzenamine, N-methyl-4-nitro-(100-15-2)
EPA Substance Registry System: N-Methyl-p-nitroaniline (100-15-2)

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Safety

Hazard Codes: T,Xi
Risk Statements: 23/24/25-33-36/37/38
Safety Statements: 28-36/37/39-45-26
RIDADR: 2811
WGK Germany: 3
Hazard Note: Highly Toxic/Irritant
TSCA: Yes
HazardClass: 6.1
PackingGroup: III
HS Code: 29214200

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H373May cause damage to organs through prolonged or repeated exposure

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P310IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

P314Get medical advice/attention if you feel unwell.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 269638
Product name: N-Methyl-4-nitroaniline
Purity: 97%
Packaging: 25g
Price: $53.1
Updated: 2025/07/31

Sigma-Aldrich

Product number: 269638
Product name: N-Methyl-4-nitroaniline
Purity: 97%
Packaging: 100g
Price: $157.7
Updated: 2025/07/31

TRC

Product number: M323460
Product name: N-Methyl-4-nitroaniline
Packaging: 25g
Price: $80
Updated: 2021/12/16

Oakwood

Product number: 003432
Product name: N-Methyl-4-nitroaniline
Purity: 97%
Packaging: 100g
Price: $95
Updated: 2021/12/16

Activate Scientific

Product number: AS106648
Product name: N-Methyl-4-nitroaniline
Purity: 97%
Packaging: 100g
Price: $110
Updated: 2021/12/16

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N-Methyl-4-nitroaniline Chemical Properties,Usage,Production

Uses

N-methyl-4-nitroaniline is a stabilizer for gunpowder, a desensitizing agent for molten cast explosive TNAZ, a widely used organic intermediate, and N-methyl-4-nitroaniline can be used as a reference substance by its polarizing properties.
N-methyl-4-nitroaniline is an attractive candidate for its appealing capability to retain the nitrogen oxides, good thermal stability, and facile synthesis from abundant and inexpensive starting materials.

Biodegradation

N-Methyl-4-nitroaniline is used as an additive to lower the melting temperature of energetic materials in the synthesis of insensitive explosives. Although the biotransformation of N-Methyl-4-nitroaniline under anaerobic condition has been reported, its aerobic microbial degradation has not been documented yet. A soil microcosms study showed the efficient aerobic degradation of N-Methyl-4-nitroaniline by the inhabitant soil microorganisms.

Chemical Properties

brownish-yellow crystalline powder

Uses

N-Methyl-4-nitroaniline is a versatile reactant used in the synthesis of oxindoles using Pd-catalyzed cyclization of chloroacetanilides.

General Description

Brownish-yellow prisms with violet reflex (from ethanol) or yellow powder.

Air & Water Reactions

N-Methyl-4-nitroaniline may be sensitive to prolonged exposure to air. Insoluble in water.

Reactivity Profile

N-Methyl-4-nitroaniline has a vigorous exothermic reaction with carbaryl sulfate when heated above 167° F.

Fire Hazard

Flash point data for N-Methyl-4-nitroaniline are not available; however, N-Methyl-4-nitroaniline is probably combustible.

Purification Methods

Crystallise the aniline from aqueous EtOH. [Beilstein 12 H 714.]

N-Methyl-4-nitroaniline Preparation Products And Raw materials

Raw materials

4'-Nitroacetanilide Iodomethane

Preparation Products

4-(4-Nitrophenyl)azoresorcinol 6-NITROQUINOLINE DISPERSE ORANGE 3 disodium 3-[[4-[[4-amino-6(or 7)-sulphonatonaphthyl]azo]phenyl]azo]-6-[(2,4-diaminophenyl)azo]-4-hydroxynaphthalene-2-sulphonate 2-Amino-5-nitrophenol 2-Amino-5-nitrobenzophenone CHROMOTROPE 2B NITARSONE

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N-Methyl-4-nitroaniline Suppliers

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View Lastest Price from N-Methyl-4-nitroaniline manufacturers

Hebei Zhuanglai Chemical Trading Co Ltd

Product: N-Methyl-4-nitroaniline 100-15-2
Price: US $10.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 20 ton
Release date: 2024-11-27

Hebei Chuanghai Biotechnology Co., Ltd

Product: N-Methyl-4-nitroaniline 100-15-2
Price: US $30.00-10.00/KG
Min. Order: 50KG
Purity: 99%
Supply Ability: 500000kg
Release date: 2024-10-24

Henan Aochuang Chemical Co.,Ltd.

Product: N-Methyl-4-nitroaniline 100-15-2
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: 1Ton
Release date: 2022-09-30

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100-15-2

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100-15-2