4-Methyl-3-nitroaniline

Product Name: 4-Methyl-3-nitroaniline
CAS No.: 119-32-4
Chemical Name: 4-Methyl-3-nitroaniline
Synonyms: META NITRO PARA TOLUIDINE;FAST RED GL BASE;3-NITRO-4-METHYLANILINE;MNPT;Gl-amin;FAST RED GL;FAST RED G BASE;5-Nitro-4-toluidine;3-NITRO-P-TOLUIDINE;LABOTEST-BB LTBB000623
CBNumber: CB2287373
Molecular Formula: C7H8N2O2
Formula Weight: 152.15
MOL File: 119-32-4.mol

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4-Methyl-3-nitroaniline Property

Melting point:: 74-77 °C(lit.)
Boiling point:: 169 °C (21 mmHg)
Density: 1.312
vapor density: 5.8
refractive index: 1.6276 (estimate)
Flash point:: 157 °C
storage temp.: Store below +30°C.
solubility: <1g/l
form: Powder
pka: 2.96±0.10(Predicted)
color: Ochre to orange or brown
BRN: 638984
InChIKey: GDIIPKWHAQGCJF-UHFFFAOYSA-N
CAS DataBase Reference: 119-32-4(CAS DataBase Reference)
NIST Chemistry Reference: Benzenamine, 4-methyl-3-nitro-(119-32-4)
EPA Substance Registry System: 4-Methyl-3-nitroaniline (119-32-4)

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Safety

Hazard Codes: T,N,Xi
Risk Statements: 23/24/25-33-51/53
Safety Statements: 28-36/37-45-61-28A
RIDADR: UN 2660 6.1/PG 3
WGK Germany: 2
RTECS: XU8227250
Hazard Note: Irritant
TSCA: Yes
HazardClass: 6.1
PackingGroup: III
HS Code: 29214300
Toxicity: LD50 orl-rat: 6860 mg/kg 28ZPAK -,133,72

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H373May cause damage to organs through prolonged or repeated exposure

H411Toxic to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P314Get medical advice/attention if you feel unwell.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: M59807
Product name: 4-Methyl-3-nitroaniline
Purity: 97%
Packaging: 25g
Price: $46.9
Updated: 2023/01/07

TCI Chemical

Product number: N0278
Product name: 4-Methyl-3-nitroaniline
Packaging: 25g
Price: $73
Updated: 2024/03/01

Alfa Aesar

Product number: A12538
Product name: 4-Methyl-3-nitroaniline, 98%
Packaging: 25g
Price: $66.65
Updated: 2024/03/01

Alfa Aesar

Product number: A12538
Product name: 4-Methyl-3-nitroaniline, 98%
Packaging: 100g
Price: $197.65
Updated: 2024/03/01

Usbiological

Product number: N2680-02
Product name: 3-Nitro-4-toluidine
Packaging: 5g
Price: $425
Updated: 2021/12/16

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4-Methyl-3-nitroaniline Chemical Properties,Usage,Production

Description

4-Methyl-3-nitroaniline is one of the intermediates or products in the photochemical transformations (λ=254 nm) of 2,4-dinitrotoluene (2,4-DNT) in aqueous solutions containing the cationic surfactant cetyltrimethylammonium (CTA) and the anionic nucleophile borohydride (BH₄^-)[1].

Chemical Properties

Orange Crystalline Solid

Uses

4-Methyl-3-nitroaniline is a compound useful in organic synthesis. It is used to make pigments and dyes. It could also be used in Environmental Testing. It could be used as raw material to synthesized N-(4-methyl-3-nitrophenyl)-4-(4-methylpiperazin-1-ylmethyl)benzamide through acylation[2].

Definition

ChEBI: 4-Amino-2-nitrotoluene is a C-nitro compound.

Synthesis Reference(s)

Tetrahedron Letters, 30, p. 251, 1989 DOI: 10.1016/S0040-4039(00)95173-6

Reactivity Profile

4-Methyl-3-nitroaniline is incompatible with acids, acid chlorides, acid anhydrides, chloroformates and strong oxidizing agents (NTP, 1992).

Hazard

Toxic by ingestion.

Fire Hazard

Excerpt from ERG Guide 153 [Substances - Toxic and/or Corrosive (Combustible)]: Combustible material: may burn but does not ignite readily. When heated, vapors may form explosive mixtures with air: indoors, outdoors and sewers explosion hazards. Those substances designated with a (P) may polymerize explosively when heated or involved in a fire. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. Runoff may pollute waterways. Substance may be transported in a molten form. (ERG, 2020)

Safety Profile

Poison by ingestion andintravenous routes. Combustible when exposed to heat orflame. To fight fire, use CO2, spray, foam. When heated todecomposition it emits toxic fumes of NOx.

Purification Methods

Crystallise the aniline from hot water (charcoal), then ethanol and dry it in a vacuum desiccator. [Beilstein 12 H 966.]

References

[1] Diehl C, et al. Surfactant-assisted UV-photolysis of nitroarenes. Chemosphere, 2002; 46: 553-560.
[2] Koroleva E, et al. Synthesis of new amides of the N -methylpiperazine series. Russian Journal of Organic Chemistry, 2011; 47: 1556–1563.

4-Methyl-3-nitroaniline Preparation Products And Raw materials

Raw materials

Preparation Products

6-Methoxy-1H-indole-3-carboxylic acid 6-Bromoindole-3-carboxaldehyde Rhodamine 6G

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4-Methyl-3-nitroaniline Suppliers

Americas 1 Belgium 3 Canada 2 China 145 Czech Republic 2 Europe 3 France 1 Germany 8 India 39 Japan 6 Slovakia 1 Switzerland 4 The Netherlands 2 Ukraine 1 United Kingdom 18 United States 49 Global 285

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 4006608290; 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40241
Advantage: 62

3B Pharmachem (Wuhan) International Co.,Ltd.

Tel: 821-50328103-801 18930552037
Fax: 86-21-50328109
Email: 3bsc@sina.com
Country: China
ProdList: 15848
Advantage: 69

Alfa Aesar

Tel: 400-6106006
Fax: 021-67582001/03/05
Email: saleschina@alfa-asia.com
Country: China
ProdList: 30132
Advantage: 84

TAIYUAN RHF CO.,LTD.

Tel: +86 351 7031519
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TCI (Shanghai) Development Co., Ltd.

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Beijing dtftchem Technology Co., Ltd.

Tel: 010-60275820 13031183356
Fax: 010-60270825
Email: elainezt@sina.com
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Energy Chemical

Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
Email: sales8178@energy-chemical.com
Country: China
ProdList: 44751
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Capot Chemical Co., Ltd

Tel: +86 (0) 571 85 58 67 18
Fax: 0086-571-85864795
Email: sales@capotchem.com
Country: China
ProdList: 18217
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Beijing Ouhe Technology Co., Ltd

Tel: 010-82967028 13552068683
Fax: +86-10-82967029
Email: 2355560935@qq.com
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ProdList: 12426
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JinYan Chemicals(ShangHai) Co.,Ltd.

Tel: 13817811078
Fax: 86-021-50426522,50426273
Email: sales@jingyan-chemical.com
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ProdList: 9984
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View Lastest Price from 4-Methyl-3-nitroaniline manufacturers

Taizhou Suze Chemical Materials Co.,Ltd.

Product: 4-Methyl-3-nitroaniline 119-32-4
Price: US $0.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 50 tons
Release date: 2022-11-21

Honest Joy Holdings Limited

Product: 4-Methyl-3-nitroaniline 119-32-4
Price: US $0.00/KG
Min. Order: 1KG
Purity: 98.3%
Supply Ability: 100 tons
Release date: 2022-02-21

Career Henan Chemical Co

Product: 4-Methyl-3-nitroaniline 119-32-4
Price: US $8.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 10TON
Release date: 2018-12-18

119-32-4, 4-Methyl-3-nitroanilineRelated Search:

4-METHYL-3-NITROPHENYL ISOCYANATE 2,4-DINITROPHENYLACETIC ACID 2-(2,4-Dinitrobenzyl)pyridine 2,4-Dinitrotoluene 2,4-Dinitrobenzaldehyde Musk ketone 9-DICYANOMETHYLENE-2,4,7-TRINITROFLUORENE MUSK TIBETEN 2,4-DINITROBENZOIC ACID 2,4,5,7-TETRANITRO-9-FLUORENONE Musk xylene 2,4,7-TRINITRO-9-FLUORENONE 3,5-Dinitro-2-methylbenzoic acid 4-Methyl-3-nitroaniline 1,1,3,3,5-PENTAMETHYL-4,6-DINITROINDANE 2,4-DINITROBENZYL CHLORIDE 4-Nitro-3-trifluoromethyl aniline 2-METHYL-5-NITROANILINE HYDRATE 97

LABOTEST-BB LTBB000623

LABOTEST-BB LTBB000402

FAST RED G BASE

FAST RED GL

FAST RED GL BASE

5-nitro-4-toluidin

5-Nitro-4-toluidine

Gl-amin

p-Toluidine, 3-nitro-

4-methyl-3-nitro-benzenamin

4-Amino-2-nitrotoluene~3-Nitro-p-toluidine

4-Methyl-3-Nitro Benzeneamine

4-METHYL-3-NITROANILINE OEKANAL, 250 MG

Benzenamine, 4-methyl-3-nitro-

m-Nitro-ρ-toluidine

3-NITRO-PARA-TOLUIDINE

Red Base GL

3-Nitro-p-toluidine (NH2=1)

4-METHYL-3-NITROANILINE 98%

4-METHYL-3-NITROLANILINE

META NITRO PARA TOLUIDINE

3-NITRO-P-TOLUIDINE

3-NITRO-4-TOLUIDINE

3-NITRO-4-METHYLANILINE

3-NITRO-4-AMINOTOLUENE

4-AMINO-1-METHYL-2-NITROBENZENE

4-AMINO-6-NITROTOLUENE

4-AMINO-2-NITROTOLUENE

4-METHYL-3-NITROBENZENAMINE

4-METHYL-3-NITROANILINE

1-AMINO-4-METHYL-2-NITROBENZENE

2-NITRO-4-METHYL ANILINE

2-NITRO-4-AMINOTOLUENE

2-Nitro-4-toluidine

MNPT

M-NITRO-O-TOLUIDINE

m-Nitro-p-toluidine'

RED G BASE

RED GL BASE

TIMTEC-BB SBB007596

3-nitro-4-aminomethylbenzene

3-nitro-4-toluidin

3-nitro-p-toluidin

3-Nitro-4-methylaniline, 3-Nitro-p-toluidine, 4-Amino-2-nitro-toluene

3-Nitro-4-methylbenzenamine

4-Methyl-3-nitroaniline,97%

3-Nitro-4-methylaniline / 4-Amino-2-nitrotoluene

4-Amino-2-nitrotoluene (4-Methyl-3-nitroaniline)

4-Amino-2-nitrotoluene, 5-Amino-2-methylnitrobenzene

NSC 7731

4-Amino-1-methyl-2-nitrobenzene 3-Nitro-p-toluidine

4-Methyl-3-nitroaniline, 97% 25GR

4-Methyl-3-nitroaniline, 97% 5GR

p-Toluidine, 3-nitro- (8CI)

4-Amino-2-nitrotoluene, 5-Amino-2-methylnitrobenzene, 3-Nitro-p-toluidine

3-Nitro-methylaniline

4-Methyl-3-nitroaniline ISO 9001：2015 REACH

4-Methyl-2-Nitroaniline (MNPT)