ChemicalBook > CAS DataBase List > 4-Methyl-3-nitroaniline
4-Methyl-3-nitroaniline
- Product Name
- 4-Methyl-3-nitroaniline
- CAS No.
- 119-32-4
- Chemical Name
- 4-Methyl-3-nitroaniline
- Synonyms
- META NITRO PARA TOLUIDINE;FAST RED GL BASE;3-NITRO-4-METHYLANILINE;MNPT;Gl-amin;FAST RED GL;FAST RED G BASE;5-Nitro-4-toluidine;3-NITRO-P-TOLUIDINE;LABOTEST-BB LTBB000623
- CBNumber
- CB2287373
- Molecular Formula
- C7H8N2O2
- Formula Weight
- 152.15
- MOL File
- 119-32-4.mol
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4-Methyl-3-nitroaniline Property
- Melting point:
- 74-77 °C(lit.)
- Boiling point:
- 169 °C (21 mmHg)
- Density
- 1.312
- vapor density
- 5.8
- refractive index
- 1.6276 (estimate)
- Flash point:
- 157 °C
- storage temp.
- Store below +30°C.
- solubility
- <1g/l
- form
- Powder
- pka
- 2.96±0.10(Predicted)
- color
- Ochre to orange or brown
- BRN
- 638984
- InChIKey
- GDIIPKWHAQGCJF-UHFFFAOYSA-N
- CAS DataBase Reference
- 119-32-4(CAS DataBase Reference)
- NIST Chemistry Reference
- Benzenamine, 4-methyl-3-nitro-(119-32-4)
- EPA Substance Registry System
- 4-Methyl-3-nitroaniline (119-32-4)
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Safety
- Hazard Codes
- T,N,Xi
- Risk Statements
- 23/24/25-33-51/53
- Safety Statements
- 28-36/37-45-61-28A
- RIDADR
- UN 2660 6.1/PG 3
- WGK Germany
- 2
- RTECS
- XU8227250
- Hazard Note
- Irritant
- TSCA
- Yes
- HazardClass
- 6.1
- PackingGroup
- III
- HS Code
- 29214300
- Toxicity
- LD50 orl-rat: 6860 mg/kg 28ZPAK -,133,72
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H373May cause damage to organs through prolonged or repeated exposure
H411Toxic to aquatic life with long lasting effects
- Precautionary statements
-
P273Avoid release to the environment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P314Get medical advice/attention if you feel unwell.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- M59807
- Product name
- 4-Methyl-3-nitroaniline
- Purity
- 97%
- Packaging
- 25g
- Price
- $46.9
- Updated
- 2023/01/07
TCI Chemical
- Product number
- N0278
- Product name
- 4-Methyl-3-nitroaniline
- Packaging
- 25g
- Price
- $73
- Updated
- 2024/03/01
Alfa Aesar
- Product number
- A12538
- Product name
- 4-Methyl-3-nitroaniline, 98%
- Packaging
- 25g
- Price
- $66.65
- Updated
- 2024/03/01
Alfa Aesar
- Product number
- A12538
- Product name
- 4-Methyl-3-nitroaniline, 98%
- Packaging
- 100g
- Price
- $197.65
- Updated
- 2024/03/01
Usbiological
- Product number
- N2680-02
- Product name
- 3-Nitro-4-toluidine
- Packaging
- 5g
- Price
- $425
- Updated
- 2021/12/16
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4-Methyl-3-nitroaniline Chemical Properties,Usage,Production
Description
4-Methyl-3-nitroaniline is one of the intermediates or products in the photochemical transformations (λ=254 nm) of 2,4-dinitrotoluene (2,4-DNT) in aqueous solutions containing the cationic surfactant cetyltrimethylammonium (CTA) and the anionic nucleophile borohydride (BH4-)[1].
Chemical Properties
Orange Crystalline Solid
Uses
4-Methyl-3-nitroaniline is a compound useful in organic synthesis. It is used to make pigments and dyes. It could also be used in Environmental Testing. It could be used as raw material to synthesized N-(4-methyl-3-nitrophenyl)-4-(4-methylpiperazin-1-ylmethyl)benzamide through acylation[2].
Definition
ChEBI: 4-Amino-2-nitrotoluene is a C-nitro compound.
Synthesis Reference(s)
Tetrahedron Letters, 30, p. 251, 1989 DOI: 10.1016/S0040-4039(00)95173-6
Reactivity Profile
4-Methyl-3-nitroaniline is incompatible with acids, acid chlorides, acid anhydrides, chloroformates and strong oxidizing agents (NTP, 1992).
Hazard
Toxic by ingestion.
Fire Hazard
Excerpt from ERG Guide 153 [Substances - Toxic and/or Corrosive (Combustible)]: Combustible material: may burn but does not ignite readily. When heated, vapors may form explosive mixtures with air: indoors, outdoors and sewers explosion hazards. Those substances designated with a (P) may polymerize explosively when heated or involved in a fire. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. Runoff may pollute waterways. Substance may be transported in a molten form. (ERG, 2020)
Safety Profile
Poison by ingestion andintravenous routes. Combustible when exposed to heat orflame. To fight fire, use CO2, spray, foam. When heated todecomposition it emits toxic fumes of NOx.
Purification Methods
Crystallise the aniline from hot water (charcoal), then ethanol and dry it in a vacuum desiccator. [Beilstein 12 H 966.]
References
[1] Diehl C, et al. Surfactant-assisted UV-photolysis of nitroarenes. Chemosphere, 2002; 46: 553-560.
[2] Koroleva E, et al. Synthesis of new amides of the N -methylpiperazine series. Russian Journal of Organic Chemistry, 2011; 47: 1556–1563.
4-Methyl-3-nitroaniline Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 4-Methyl-3-nitroaniline manufacturers
Taizhou Suze Chemical Materials Co.,Ltd.
- Product
- 4-Methyl-3-nitroaniline 119-32-4
- Price
- US $0.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 50 tons
- Release date
- 2022-11-21
Honest Joy Holdings Limited
- Product
- 4-Methyl-3-nitroaniline 119-32-4
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 98.3%
- Supply Ability
- 100 tons
- Release date
- 2022-02-21
Career Henan Chemical Co
- Product
- 4-Methyl-3-nitroaniline 119-32-4
- Price
- US $8.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 10TON
- Release date
- 2018-12-18
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