ChemicalBook > CAS DataBase List > 1-Adamantanemethanol

1-Adamantanemethanol

Product Name
1-Adamantanemethanol
CAS No.
770-71-8
Chemical Name
1-Adamantanemethanol
Synonyms
AKOS BC-0668;1-amantadinol;Adamantanemethanol;1-Adamantlcarbinol;1-adamantanemethol;RARECHEM AQ TC 1004;CHEMBRDG-BB 4013930;1-ADAMANTYLMETHANOL;1-Adamantylcarbinol;1-ADAMANTANEMETHANOL
CBNumber
CB1448137
Molecular Formula
C11H18O
Formula Weight
166.26
MOL File
770-71-8.mol
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1-Adamantanemethanol Property

Melting point:
114-117 °C (lit.)
Boiling point:
234.5°C (rough estimate)
Density 
0.8802 (rough estimate)
refractive index 
1.5000 (estimate)
storage temp. 
Sealed in dry,Room Temperature
pka
15.51±0.10(Predicted)
form 
Crystalline Powder
color 
White
Water Solubility 
Insoluble in water. Solubility in methanol (almost transparency).
BRN 
1853339
InChI
InChI=1S/C11H18O/c12-7-11-4-8-1-9(5-11)3-10(2-8)6-11/h8-10,12H,1-7H2
InChIKey
MDVGOOIANLZFCP-UHFFFAOYSA-N
SMILES
C12(CO)CC3CC(CC(C3)C1)C2
CAS DataBase Reference
770-71-8(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
22-24/25-36-26
WGK Germany 
3
HazardClass 
IRRITANT
HS Code 
29061900
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

TCI Chemical
Product number
H0420
Product name
1-Adamantanemethanol
Purity
>99.0%(GC)
Packaging
1g
Price
$20
Updated
2024/03/01
TCI Chemical
Product number
H0420
Product name
1-Adamantanemethanol
Purity
>99.0%(GC)
Packaging
5g
Price
$56
Updated
2024/03/01
Alfa Aesar
Product number
B23831
Product name
1-Adamantanemethanol, 98%
Packaging
5g
Price
$51.65
Updated
2024/03/01
Alfa Aesar
Product number
B23831
Product name
1-Adamantanemethanol, 98%
Packaging
1g
Price
$17.1
Updated
2022/04/27
TCI Chemical
Product number
H0420
Product name
1-Adamantanemethanol
Purity
>99.0%(GC)
Packaging
25g
Price
$92
Updated
2024/03/01
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1-Adamantanemethanol Chemical Properties,Usage,Production

Description

1-Adamantanemethanol acts as guest molecule and forms β-cyclodextrin complexes. It reacts with 3,4,5,6-tetrafluorophthalonitrile to yield 3,4,5,6-tetra-(1-adamantylmethoxy)phthalonitrile.

Chemical Properties

white crystalline powder

Uses

1-Adamantanemethanol was used in the synthesis of axially disubstituted silicon(IV) phthalocyanines. It is used as a reagent in the synthesis of adamantane and noradamantane based histone deacetylase (HDAC) inhibitors for the treatment of cancer. It is also used as a reagent in the synthesis of (1-adamantyl)methyl glycidyl ether, a versatile building block for living polymerization.
References
Gopalan, B., et al.: Bioorg. Med. Chem. Lett., 23, 2532 (2013);
Suzuki, T., et al.: J. Med. Chem., 55, 9562 (2012);
Moers, C., et al.: Macromol. Rapid Comm., 35, 1075 (2014)

Purification Methods

Dissolve the adamantane in Et2O, wash it with aqueous 0.1N NaOH and H2O, dry over CaCl2, evaporate and recrystallise the residue from aqueous MeOH. [Stetter et al. Chem Ber 92 1629 1959, Beilstein 6 IV 400.]

1-Adamantanemethanol Preparation Products And Raw materials

Raw materials

Preparation Products

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1-Adamantanemethanol Suppliers

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View Lastest Price from 1-Adamantanemethanol manufacturers

Ouhuang Engineering Materials (Hubei) Co., Ltd
Product
1-Adamantane Methanol 770-71-8
Price
US $10.00/kg
Min. Order
1kg
Purity
99.6%
Supply Ability
100000
Release date
2024-04-24
Hebei Duling International Trade Co. LTD
Product
1-Adamantanemethanol 770-71-8
Price
US $37.00-33.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
1000kg
Release date
2023-01-06
Hebei Fengqiang Trading Co., LTD
Product
1-Adamantane Methanol 770-71-8
Price
US $100.00/bag
Min. Order
1bag
Purity
99
Supply Ability
5000
Release date
2023-08-23

770-71-8, 1-AdamantanemethanolRelated Search:

Altrenogest Amantadine Methanol Tris(hydroxymethyl)aminomethane methylol cellulose Adamantane Tris(hydroxymethyl)nitromethane Trimethylolpropane CARBOXYMETHYLCELLULOSE SODIUM SALT 2-Hydroxyethyl methacrylate 1-Adamantanecarboxylic acid 2-(1-Adamantyl)propan-2-ol 2-Adamantone-5-carboxylic acid FMOC-DAB(ADPOC)-OH FMOC-LYS(ADPOC)-OH AMANTANIUM BROMIDE Ethyl adamantane-1-carboxylate 3,5-DIMETHYL-1-ADAMANTANEMETHANOL, 98%(GC)

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