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Isonicotinic acid

Product Name
Isonicotinic acid
CAS No.
55-22-1
Chemical Name
Isonicotinic acid
Synonyms
INA;4-PYRIDINECARBOXYLIC ACID;4-PICOLINIC ACID;PYRIDINE-3-CARBOXYLIC ACID;PYRIDINE-4-CARBOXYLIC ACID;Isonicotic acid;Isonicotinic;4-Carboxypyridine;NEF5;bidinjiausn
CBNumber
CB1462924
Molecular Formula
C6H5NO2
Formula Weight
123.11
MOL File
55-22-1.mol
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Isonicotinic acid Property

Melting point:
≥300 °C (lit.)
Boiling point:
260 °C (15 mmHg)
Density 
1,47g/cm
refractive index 
1.5423 (estimate)
Flash point:
260°C/15mm
storage temp. 
no restrictions.
solubility 
6g/l
pka
4.96(at 25℃)
form 
powder
color 
yellow to tan
PH
3-4 (6g/l, H2O, 20℃)(saturated solution)
Water Solubility 
5.2 g/L (20 ºC)
Merck 
14,5187
BRN 
109599
InChIKey
TWBYWOBDOCUKOW-UHFFFAOYSA-N
CAS DataBase Reference
55-22-1(CAS DataBase Reference)
NIST Chemistry Reference
Isonicotinic acid(55-22-1)
EPA Substance Registry System
Isonicotinic acid (55-22-1)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
2
RTECS 
NS1103000
TSCA 
Yes
HS Code 
29333999
Toxicity
LD50 orally in Rabbit: 5000 mg/kg
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
I17508
Product name
Isonicotinic acid
Purity
99%
Packaging
5g
Price
$27.6
Updated
2024/03/01
Sigma-Aldrich
Product number
I17508
Product name
Isonicotinic acid
Purity
99%
Packaging
100g
Price
$31.6
Updated
2024/03/01
Sigma-Aldrich
Product number
8.00736
Product name
4-Pyridinecarboxylic acid
Purity
for synthesis
Packaging
5G
Price
$34.2
Updated
2024/03/01
Sigma-Aldrich
Product number
8.00736
Product name
4-Pyridinecarboxylic acid
Purity
for synthesis
Packaging
250g
Price
$86.3
Updated
2024/03/01
TCI Chemical
Product number
I0207
Product name
Isonicotinic Acid
Purity
>99.0%(HPLC)(T)
Packaging
25g
Price
$23
Updated
2024/03/01
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Isonicotinic acid Chemical Properties,Usage,Production

Chemical Properties

isonicotinic acid is also known as pyridine-4-carboxylic acid. white to light yellow crystal powder or white needle crystals. odorless, sublimable. molecular weight 123.11. melting point 319°C . slightly soluble in cold water, soluble in hot water, insoluble in alcohol, benzene and ether. isonicotinic acid is an amphoteric compound that is soluble in both acids and bases. soluble in hot water and ethanol, slightly soluble in cold water and ether. stable to heat and oxidation.

Uses

Isonicotinic acid is a metabolite of isoniazid. It is an isomer of nicotinic acid. The chronic toxicity of isonicotinic acid is slightly higher than that of isonicotinic acid hydrazide ( INH ) .
Isonicotinic acid is a moderately basic compound (based on its pKa). Isonicotinic acid is an organic compound with a carboxyl group on a pyridine ring. The carboxyl group for isonicotinic acid is on the 4-position instead of the 3-position for nicotinic acid. It is an isomer of nicotinic acid. Isonicotinic acid is a metabolite of isoniazid.
Isonicotinic acid considered to be inactive isomer of nicotinic acid. Isonicotinic acid is a metabolite of pyridine-4-carboxy hydrazide (isonicotinyl hydrazide; isoniazid) a front-line weapon in the battle against tuberculosis. Isonicotinic acid and its derivatives are used in manufacturing pharmaceuticals and agrochemicals.
Used in the biological study of differentiation induced by nicotinic acid, nicotinamide and isonicotinic acid in human leukemia cell lines

Definition

ChEBI: Isonicotinic acid is a pyridinemonocarboxylic acid in which the carboxy group is at position 4 of the pyridine ring. It has a role as a human metabolite and an algal metabolite. It is a conjugate acid of an isonicotinate.

Preparation

Isonicotinic acid is synthesized by continuous oxidation with 4-methylpyridine as raw material and vanadium pentoxide as catalyst. The purity of the industrial product isonicotinic acid is more than 95%, and the yield of the above method is 70-75%. The consumption of 4-methylpyridine per ton of product is 1070kg.

Application

Isonicotinic acid (IN) can be used as:
An organocatalyst in the one pot four component condensation reaction, to synthesize pyranopyrazoles based heterocyclic compounds.
An organic ligand for the preparation of copper(I) halide coordination polymer [CuBr(IN)]n, by hydrothermal method.
As a starting material for the synthesis of cation-dimers with potent antimalarial activity.

Purification Methods

Crystallise the acid repeatedly from water and dry it under vacuum at 110o or sublime it at 260o/15mm (m 319o). [Beilstein 22 III/IV 518, 22/2 V 188.]

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Isonicotinic acid Suppliers

Shanghai Aladdin Bio-Chem Technology Co.,LTD
Tel
400-400-6206333 18521732826
Fax
021-50323701
Email
market@aladdin-e.com
Country
China
ProdList
25003
Advantage
65
Shandong Vantage Specialty Chemicals Biotechnology Co., Ltd.
Tel
133-96369453 18678026865
Fax
0536-2101172
Email
sdfantai@163.com
Country
China
ProdList
862
Advantage
58
Macheng jinxin biotechnology co., LTD
Tel
18271582018
Email
1126319697@qq.com
Country
China
ProdList
1525
Advantage
58
Anhui Dexinjia Biopharm Co., Ltd
Tel
0531-82375878 15269101859
Email
2710825968@qq.com
Country
China
ProdList
303
Advantage
58
Shanghai Taijilin Industrial Co., Ltd.
Tel
021-021-50630626 18964684208
Fax
021-50563898
Email
kate@tajilin.com
Country
China
ProdList
1230
Advantage
58
Shouguang Jiasheng Chemical Co., Ltd.
Tel
0536-7971999 18232719690
Fax
0536-7971999
Email
sgjiasheng@hotmail.com
Country
China
ProdList
388
Advantage
58
J & K SCIENTIFIC LTD.
Tel
010-82848833 400-666-7788
Fax
86-10-82849933
Email
jkinfo@jkchemical.com
Country
China
ProdList
94657
Advantage
76
Meryer (Shanghai) Chemical Technology Co., Ltd.
Tel
021-61259108 18621169109
Fax
86-21-61259102
Email
market03@meryer.com
Country
China
ProdList
40228
Advantage
62
3B Pharmachem (Wuhan) International Co.,Ltd.
Tel
821-50328103-801 18930552037
Fax
86-21-50328109
Email
3bsc@sina.com
Country
China
ProdList
15839
Advantage
69
future industrial shanghai co., ltd
Tel
400-0066400 13621662912
Fax
021-55660885
Email
sales@jonln.com
Country
China
ProdList
1995
Advantage
65
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View Lastest Price from Isonicotinic acid manufacturers

HebeiShuoshengImportandExportco.,Ltd
Product
Isonicotinic acid 55-22-1
Price
US $6.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
2000KG/Month
Release date
2024-08-02
HEBEI SHENGSUAN CHEMICAL INDUSTRY CO.,LTD
Product
Isonicotinic acid 55-22-1
Price
US $99.00-80.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
5000
Release date
2024-08-21
Hebei Longbang Technology Co., Ltd
Product
Isonicotinic acid 55-22-1
Price
US $6.00/kg
Min. Order
1kg
Purity
More than 99%
Supply Ability
2000KG/Month
Release date
2024-05-22

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