ChemicalBook > CAS DataBase List > 4-(Methylthio)phenylboronic acid

4-(Methylthio)phenylboronic acid

Product Name
4-(Methylthio)phenylboronic acid
CAS No.
98546-51-1
Chemical Name
4-(Methylthio)phenylboronic acid
Synonyms
AKOS BRN-0127;RARECHEM AH PB 0130;4-BORONOTHIOANISOLE;4-(Methylthio)phenyl;4-THIOANISOLEBORONIC ACID;THIOANISOLE-4-BORONIC ACID;4-Methylthiopenylboronic Acid;4-THIOMETHYLPHENYLBORONIC ACID;P-(METHYLTHIO)PHENYLBORONIC ACID;4-(METHYLTHIO)PHENYLBORONIC ACID
CBNumber
CB1483149
Molecular Formula
C7H9BO2S
Formula Weight
168.02
MOL File
98546-51-1.mol
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4-(Methylthio)phenylboronic acid Property

Melting point:
210-214 °C (lit.)
Boiling point:
333.5±44.0 °C(Predicted)
Density 
1.22±0.1 g/cm3(Predicted)
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
solubility 
soluble in Methanol
pka
8.56±0.10(Predicted)
form 
Crystalline Powder
color 
Off-white
BRN 
3247219
CAS DataBase Reference
98546-51-1(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
37/39-26-36-7/9
WGK Germany 
3
TSCA 
No
HazardClass 
IRRITANT
HS Code 
29163990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
456802
Product name
4-(Methylthio)phenylboronic acid
Purity
≥95%
Packaging
5g
Price
$42.36
Updated
2024/03/01
Sigma-Aldrich
Product number
456802
Product name
4-(Methylthio)phenylboronic acid
Purity
≥95%
Packaging
1g
Price
$20
Updated
2023/06/20
TCI Chemical
Product number
M1458
Product name
4-(Methylthio)phenylboronic Acid (contains varying amounts of Anhydride)
Packaging
1g
Price
$22
Updated
2024/03/01
TCI Chemical
Product number
M1458
Product name
4-(Methylthio)phenylboronic Acid (contains varying amounts of Anhydride)
Packaging
5g
Price
$86
Updated
2024/03/01
Alfa Aesar
Product number
B23454
Product name
4-(Methylthio)benzeneboronic acid, 97%
Packaging
1g
Price
$25.65
Updated
2024/03/01
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4-(Methylthio)phenylboronic acid Chemical Properties,Usage,Production

Chemical Properties

Off-white crystalline powder

Uses

Reactant involved in:

  • Suzuki-Miyaura cross coupling reactions with 2-aryl-1-bromo-1-nitroethenes or alkynyl bromides
  • Addition reactions with naphthyridine N-oxides
  • Oxyarylation of Heck reaction intermediates for synthesis of THF derivatives
  • Sulfoxidation reactions
  • Copper-catalyzed halogenation

4-(Methylthio)phenylboronic acid Preparation Products And Raw materials

Raw materials

Trimethyl borate 4-Bromothiophenol n-Butyllithium Dimethyl sulfate

Preparation Products

6-(4-METHYLSULFANYLPHENYL)PYRIDINE-2-CARBALDEHYDE
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View Lastest Price from 4-(Methylthio)phenylboronic acid manufacturers

Career Henan Chemical Co
Product
4-(Methylthio)phenylboronic acid 98546-51-1
Price
US $1.00/g
Min. Order
1g
Purity
95%~99%
Supply Ability
per week 100kg
Release date
2019-09-10

98546-51-1, 4-(Methylthio)phenylboronic acidRelated Search:

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  • Boronic acid, [4-(methylthio)phenyl]-
  • 4-(Methylthio)phenylboronic acid ,98%
  • 4-(Methylthiophenyl)boronic acid, min. 97%
  • 4-(Methylthio)phenylboronic acid,97%
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  • 4-(Methylthio)phenyl
  • 4-(Methylsulfanyl)phenylboronic acid, May contain varying amounts of anhydride, 95%
  • [4-(methylthio)phenyl]boronic acid(SALTDATA: FREE)
  • 98546-51-1
  • 98456-51-1
  • BORONIC ACID
  • Boronic Acids and Derivatives
  • Aryl
  • Organometallic Reagents
  • Boronic Acids
  • B (Classes of Boron Compounds)
  • Aryl Boronic Acids
  • Boronic Acids and Derivatives
  • Chemical Synthesis
  • Monosubstituted Aryl Boronic Acids
  • B (Classes of Boron Compounds)
  • organic or inorganic borate
  • Boronic Acid
  • Azoles
  • blocks
  • BoronicAcids
  • Boric Acid
  • Aryl
  • Organoborons
  • Boronic acids
  • Organometallic Reagents
  • Boronate Ester
  • Potassium Trifluoroborate