ChemicalBook > CAS DataBase List > 3-Bromothioanisole

3-Bromothioanisole

Product Name
3-Bromothioanisole
CAS No.
33733-73-2
Chemical Name
3-Bromothioanisole
Synonyms
(3-bromophenyl)(methyl)sulfane;3-BROMOTHIOANISOLE;M-BROMOTHIOANISOLE;3-BROMOTHIOANISOLE 98%;3-Bromothioanisole >m-bromothioanisole(MBTA);M-BROMO(METHYLTHIO)BENZENE;1-Methylthio-3-bromobenzene;3-BROMOPHENYL METHYL SULFIDE;3-(Methylthio)phenyl bromide
CBNumber
CB1725894
Molecular Formula
C7H7BrS
Formula Weight
203.1
MOL File
33733-73-2.mol
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3-Bromothioanisole Property

Boiling point:
124-125 °C10 mm Hg(lit.)
Density 
1.51 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.628(lit.)
Flash point:
>230 °F
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
solubility 
soluble in Chloroform, Ethyl Acetate
form 
clear liquid to slightly cloudy liquid
color 
Colorless to Yellow
Specific Gravity
1.510
Sensitive 
Stench
BRN 
2078598
CAS DataBase Reference
33733-73-2(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
23-24/25-37-26
RIDADR 
UN 3334
WGK Germany 
3
Hazard Note 
Irritant/Stench
HazardClass 
IRRITANT, STENCH
HS Code 
29309090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
549053
Product name
3-Bromothioanisole
Purity
97%
Packaging
5g
Price
$37.5
Updated
2025/07/31
TCI Chemical
Product number
B2346
Product name
3-Bromothioanisole
Purity
>98.0%(GC)
Packaging
5g
Price
$96
Updated
2025/07/31
TCI Chemical
Product number
B2346
Product name
3-Bromothioanisole
Purity
>98.0%(GC)
Packaging
25g
Price
$280
Updated
2025/07/31
TRC
Product number
B688165
Product name
3-Bromothioanisole
Packaging
2.5g
Price
$105
Updated
2021/12/16
Frontier Specialty Chemicals
Product number
JK372151
Product name
3-Bromothioanisole
Packaging
5g
Price
$38
Updated
2021/12/16
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3-Bromothioanisole Chemical Properties,Usage,Production

Chemical Properties

Pale-Yellow Liquid

Uses

3-Bromothioanisole is a useful reagent for the preparation of (Z)-1,2-diborylalkenes via sodium-metal-promoted reductive 1,2-syn-diboration of alkynes with reduction-??resistant trimethoxyborane.

Synthesis

624-92-0

89598-96-9

33733-73-2

GENERAL METHOD: 3-bromophenylboronic acid (1.0 mmol), dimethyl disulfide (2.0 mmol), di-tert-butyl peroxide (DTBP, 3.0 mmol) and acetonitrile (CH3CN, 2.0 mL) were added sequentially to a sealed tube. The reaction mixture was stirred at 120 °C in air for 12 hours. After completion of the reaction, it was cooled to room temperature and the reaction mixture was diluted with deionized water (5 mL) and subsequently extracted with ethyl acetate (EtOAc, 4 × 10 mL). The organic phases were combined, washed with saturated saline (3 × 10 mL), dried over anhydrous magnesium sulfate (MgSO4), filtered and concentrated. The crude product was purified by silica gel column chromatography with ethyl acetate/hexane as eluent (v/v = 1:30 to 1:100). The resulting 3-bromothioanisole was characterized by spectroscopic analyses (NMR hydrogen spectroscopy, carbon spectroscopy, etc.) and compared with the data of known compounds (see Supporting Information for details).

References

[1] Synlett, 2016, vol. 27, # 15, p. 2269 - 2273

3-Bromothioanisole Preparation Products And Raw materials

Raw materials

Preparation Products

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3-Bromothioanisole Suppliers

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View Lastest Price from 3-Bromothioanisole manufacturers

Hebei Chuanghai Biotechnology Co., Ltd
Product
3-Bromothioanisole 33733-73-2
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20 mt
Release date
2024-12-03
Shaanxi Dideu Medichem Co. Ltd
Product
3-Bromothioanisole 33733-73-2
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20T
Release date
2024-08-15
Hebei Fengqiang Trading Co., LTD
Product
3-Bromothioanisole 33733-73-2
Price
US $100.00/drum
Min. Order
1drum
Purity
99
Supply Ability
5000
Release date
2023-09-07

33733-73-2, 3-BromothioanisoleRelated Search:

Kresoxim-methyl Hydrogen Sulfide 3-Bromoanisole CARBONYL SULFIDE Thioanisole Decabromodiphenyl oxide Anisole Anise oil 2-Thiobarbituric acid Thioacetamide Butylated hydroxyanisole POLY(1,4-PHENYLENE SULFIDE) Guaiacol 4-Methoxyphenol Dimethyl sulfide Sodium thiosulfate Sodium sulfide Thiophanate-methyl

  • 3-BROMOPHENYL METHYL SULFIDE
  • 3-BROMOTHIOANISOLE
  • 1-BROMO-3-(METHYLTHIO)BENZENE
  • M-BROMO(METHYLTHIO)BENZENE
  • M-BROMOTHIOANISOLE
  • 3-Bromophenyl methyl sulphide, 1-Bromo-3-(methylsulphanyl)benzene, 1-Bromo-3-(methylthio)benzene
  • Benzene,1-broMo-3-(Methylthio)-
  • 1-bromo-3-methylsulfanylbenzene
  • 1-bromo-3-[[(3-bromophenyl)methylthio]methyl]benzene
  • 3-Bromophenyl methyl sulphide
  • 3-Bromothioanisol/3-Bromophenyl methyl sulphide
  • m-bromothioanisole(MBTA)
  • 2-Bromophenyl methyl sulphide
  • 3-BROMOTHIOANISOLE / 3-BROMOPHENYL METHYL SULPHIDE
  • 3-BROMOTHIOANISOLE 98%
  • 1-Methylthio-3-bromobenzene
  • 3-(Methylthio)phenyl bromide
  • m-Bromophenyl(methyl) sulfide
  • Methyl[3-bromophenyl] sulfide
  • (3-bromophenyl)(methyl)sulfane
  • 1-Bromo-3-(methylthio)benzene 3-Bromophenyl Methyl Sulfide
  • 1-broMo-3-Methylsulphanyl-benzene
  • 3-Bromothioanisole &gt
  • 33733-73-2
  • ARYL HALIDE
  • Building Blocks
  • Organic Building Blocks
  • Sulfides/Disulfides
  • Sulfur Compounds
  • Aromatics
  • Sulfur & Selenium Compounds
  • Miscellaneous
  • Aromatics Compounds