3-Bromothioanisole
- Product Name
- 3-Bromothioanisole
- CAS No.
- 33733-73-2
- Chemical Name
- 3-Bromothioanisole
- Synonyms
- (3-bromophenyl)(methyl)sulfane;3-BROMOTHIOANISOLE;M-BROMOTHIOANISOLE;3-BROMOTHIOANISOLE 98%;3-Bromothioanisole >m-bromothioanisole(MBTA);M-BROMO(METHYLTHIO)BENZENE;1-Methylthio-3-bromobenzene;3-BROMOPHENYL METHYL SULFIDE;3-(Methylthio)phenyl bromide
- CBNumber
- CB1725894
- Molecular Formula
- C7H7BrS
- Formula Weight
- 203.1
- MOL File
- 33733-73-2.mol
3-Bromothioanisole Property
- Boiling point:
- 124-125 °C10 mm Hg(lit.)
- Density
- 1.51 g/mL at 25 °C(lit.)
- refractive index
- n20/D 1.628(lit.)
- Flash point:
- >230 °F
- storage temp.
- Keep in dark place,Inert atmosphere,Room temperature
- solubility
- soluble in Chloroform, Ethyl Acetate
- form
- clear liquid to slightly cloudy liquid
- color
- Colorless to Yellow
- Specific Gravity
- 1.510
- Sensitive
- Stench
- BRN
- 2078598
- CAS DataBase Reference
- 33733-73-2(CAS DataBase Reference)
Safety
- Hazard Codes
- Xi
- Risk Statements
- 36/37/38
- Safety Statements
- 23-24/25-37-26
- RIDADR
- UN 3334
- WGK Germany
- 3
- Hazard Note
- Irritant/Stench
- HazardClass
- IRRITANT, STENCH
- HS Code
- 29309090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405Store locked up.
N-Bromosuccinimide Price
- Product number
- 549053
- Product name
- 3-Bromothioanisole
- Purity
- 97%
- Packaging
- 5g
- Price
- $37.5
- Updated
- 2025/07/31
- Product number
- B2346
- Product name
- 3-Bromothioanisole
- Purity
- >98.0%(GC)
- Packaging
- 5g
- Price
- $96
- Updated
- 2025/07/31
- Product number
- B2346
- Product name
- 3-Bromothioanisole
- Purity
- >98.0%(GC)
- Packaging
- 25g
- Price
- $280
- Updated
- 2025/07/31
- Product number
- B688165
- Product name
- 3-Bromothioanisole
- Packaging
- 2.5g
- Price
- $105
- Updated
- 2021/12/16
- Product number
- 003661
- Product name
- 3-Bromothioanisole
- Purity
- 98%
- Packaging
- 1g
- Price
- $10
- Updated
- 2021/12/16
3-Bromothioanisole Chemical Properties,Usage,Production
Chemical Properties
Pale-Yellow Liquid
Uses
3-Bromothioanisole is a useful reagent for the preparation of (Z)-1,2-diborylalkenes via sodium-metal-promoted reductive 1,2-syn-diboration of alkynes with reduction-??resistant trimethoxyborane.
Synthesis
624-92-0
89598-96-9
33733-73-2
GENERAL METHOD: 3-bromophenylboronic acid (1.0 mmol), dimethyl disulfide (2.0 mmol), di-tert-butyl peroxide (DTBP, 3.0 mmol) and acetonitrile (CH3CN, 2.0 mL) were added sequentially to a sealed tube. The reaction mixture was stirred at 120 °C in air for 12 hours. After completion of the reaction, it was cooled to room temperature and the reaction mixture was diluted with deionized water (5 mL) and subsequently extracted with ethyl acetate (EtOAc, 4 × 10 mL). The organic phases were combined, washed with saturated saline (3 × 10 mL), dried over anhydrous magnesium sulfate (MgSO4), filtered and concentrated. The crude product was purified by silica gel column chromatography with ethyl acetate/hexane as eluent (v/v = 1:30 to 1:100). The resulting 3-bromothioanisole was characterized by spectroscopic analyses (NMR hydrogen spectroscopy, carbon spectroscopy, etc.) and compared with the data of known compounds (see Supporting Information for details).
References
[1] Synlett, 2016, vol. 27, # 15, p. 2269 - 2273
3-Bromothioanisole Preparation Products And Raw materials
Raw materials
Preparation Products
3-Bromothioanisole Suppliers
- Tel
- 03-36680489
- Fax
- 03-3668-0520
- Sales-JP@TCIchemicals.com
- Country
- Japan
- ProdList
- 28387
- Advantage
- 80
- Tel
- --
- Fax
- --
- labchem-tec@wako-chem.co.jp
- Country
- Japan
- ProdList
- 6819
- Advantage
- 80
View Lastest Price from 3-Bromothioanisole manufacturers
- Product
- 3-Bromothioanisole 33733-73-2
- Price
- US $0.00-0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 20 mt
- Release date
- 2024-12-03
- Product
- 3-Bromothioanisole 33733-73-2
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 20T
- Release date
- 2024-08-15
- Product
- 3-Bromothioanisole 33733-73-2
- Price
- US $100.00/drum
- Min. Order
- 1drum
- Purity
- 99
- Supply Ability
- 5000
- Release date
- 2023-09-07