ChemicalBook > CAS DataBase List > BOC-SAR-OH

BOC-SAR-OH

Product Name: BOC-SAR-OH
CAS No.: 13734-36-6
Chemical Name: BOC-SAR-OH
Synonyms: BOC-SAR;BOC-SARCOSINE;2-((tert-butoxycarbonyl)(Methyl)aMino)acetic acid;BOC-SAR-OH;BOC-MEGLY-OH;Boc-L-Sar-OH;BOC-N-ME-GLY-OH;N-BOC-SARCOSINE;N-T-BOC-SARCOSIN;N-t-Boc-sarcosine
CBNumber: CB2253437
Molecular Formula: C8H15NO4
Formula Weight: 189.21
MOL File: 13734-36-6.mol

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BOC-SAR-OH Property

Melting point:: 88-90 °C
Boiling point:: 324.46°C (rough estimate)
Density: 1.2321 (rough estimate)
refractive index: 1.4540 (estimate)
storage temp.: 2-8°C
solubility: Chloroform (Sparingly), DMSO (Sparingly), Methanol (Slightly)
form: Crystals or Crystalline Powder
pka: 4.03±0.10(Predicted)
color: White
BRN: 2046827
Stability:: Hygroscopic
InChI: InChI=1S/C8H15NO4/c1-8(2,3)13-7(12)9(4)5-6(10)11/h5H2,1-4H3,(H,10,11)
InChIKey: YRXIMPFOTQVOHG-UHFFFAOYSA-N
SMILES: C(O)(=O)CN(C(OC(C)(C)C)=O)C
CAS DataBase Reference: 13734-36-6(CAS DataBase Reference)
EPA Substance Registry System: Glycine, N-[(1,1-dimethylethoxy)carbonyl]-N-methyl- (13734-36-6)

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Safety

Safety Statements: 24/25
WGK Germany: 3
F: 21
TSCA: Yes
HazardClass: IRRITANT
HS Code: 29241990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 8.53062
Product name: Boc-Sar-OH
Purity: Novabiochem?
Packaging: 5G
Price: $24.6
Updated: 2025/07/31

Sigma-Aldrich

Product number: 8.53062
Product name: Boc-Sar-OH
Purity: Novabiochem?
Packaging: 25g
Price: $55.9
Updated: 2025/07/31

Sigma-Aldrich

Product number: 8.53062
Product name: Boc-Sar-OH
Purity: Novabiochem?
Packaging: 100g
Price: $155
Updated: 2025/07/31

Sigma-Aldrich

Product number: 15495
Product name: Boc-Sar-OH
Purity: ≥99.0% (T)
Packaging: 5g
Price: $37.1
Updated: 2023/06/20

Sigma-Aldrich

Product number: 15495
Product name: Boc-Sar-OH
Purity: ≥99.0% (T)
Packaging: 25g
Price: $97.5
Updated: 2023/06/20

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BOC-SAR-OH Chemical Properties,Usage,Production

Chemical Properties

white crystals or crystalline powder

Uses

Boc-N-methylglycine is used in the preparation of Clavatustide A (C563723) and Clavatustide B (C563725), which have been shown to suppress the proliferation of human hepatocellular carcinoma cells under specific conditions.

reaction suitability

reaction type: Boc solid-phase peptide synthesis

Synthesis

107-97-1

24424-99-5

13734-36-6

Triethylamine (23.5 mL, 168.3 mmol) and di-tert-butyl dicarbonate (12.9 mL, 56.1 mmol) were sequentially added to an aqueous (375 mL) solution of sarcosine (5.0 g, 56.1 mmol), and the reaction mixture was stirred for 6 hours at room temperature. After completion of the reaction, hydrochloric acid solution (320 mL, 1 M aqueous solution) and ethyl acetate were added for acidification and extraction. After separation of the aqueous layer, the aqueous layer was further extracted with ethyl acetate. The organic phases were combined, dried with anhydrous sodium sulfate, filtered and concentrated under reduced pressure to give a colorless oil. The oily substance was crystallized at -15 °C to afford the target product 2-((tert-butoxycarbonyl)(methyl)amino)acetic acid (10.6 g, quantitative yield) as a white solid and a mixture of rotary isomers was observed.

References

[1] Tetrahedron Letters, 2017, vol. 58, # 7, p. 602 - 605
[2] Journal of the American Chemical Society, 2003, vol. 125, # 35, p. 10664 - 10671
[3] Synthesis, 1996, # 10, p. 1246 - 1258
[4] Patent: WO2005/39506, 2005, A2. Location in patent: Page/Page column 93-94
[5] Patent: WO2005/39506, 2005, A2. Location in patent: Page/Page column 93-94

BOC-SAR-OH Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from BOC-SAR-OH manufacturers

Sichuan HongRi Pharma-Tech Co.,Ltd

Product: Boc-Sar-OH 13734-36-6
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: 1T
Release date: 2023-11-14

Anhuyan (Hainan) Biotechnology Co., LTD

Product: BOC-SAR-OH 13734-36-6
Price: US $0.00/G/KG
Min. Order: 1G/KG
Purity: 99%
Supply Ability: 10000000KG
Release date: 2025-02-12

Hebei Chuanghai Biotechnology Co,.LTD

Product: N-Boc-Sarcosine 13734-36-6
Price: US $5.00-2.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10000kg
Release date: 2024-08-13

13734-36-6, BOC-SAR-OHRelated Search:

BOC-ORN-OH Boc-N-beta-Trityl-L-asparagine N-tert-Butoxycarbonyl-L-glutamic acid gamma-tert-butyl ester Boc-L-aspartic acid 4-tert-butyl ester Boc-6-AMinocaproic acid BOC-NLE-OH DCHA Succinimido (S)-2-[(tert-butoxycarbonyl)amino]propionate Boc-L-glutamic acid 5-cyclohexyl ester Boc-D-aspartic acid 4-benzyl ester BOC-GLU(OFM)-OH BOC-PHE-SER-ARG-AMC ACETATE SALT BOC-4-IODO-L-PHENYLALANINE Boc-N-methyl-L-leucine BOC-D-MEPHE-OH DCHA N-tert-Butyloxycarbonyl-N-methyl-O-benzyl-L-threonine BOC-N-Methyl-L-alanine BOC-HYP(BZL)-OH Sarcosine

BOC-SARCOSINE

BOC-SAR

BOC-SAR-OH

Boc-N-methylglycine, Boc-sarcosine

2-[methyl-[(2-methylpropan-2-yl)oxy-oxomethyl]amino]acetate

N-[(1,1-dimethylethoxy)carbonyl]sarcosine

Glycine, N-[(1,1-dimethylethoxy)carbonyl]-N-methyl-

Glycine, N-methyl-N-(t-butoxycarbonyl)-

n-[(1,1-dimethylethoxy)carbonyl]-n-methyl-glycin

N-[(1,1-Dimethylethoxy)carbonyl]-N-methylglycine

N-t-Boc-sarcosine

BOC-Sarcosine, 99+%

N-T-BUTYLOXYCARBONYL-SARCOSINE, N-T-BUTYLOXYCARBONYL-N-METHYL-GLYCINE

(Tert-Butoxy)Carbonyl Sar-OH

N-tert-Butoxycarbonyl-N-methylglycine

N-Boc-Sarcosine (Boc-Sar-OH) ,99% (GC)

[(tert-Butoxycarbonyl)(methyl)amino]acetic acid, Sarcosine, N-BOC proteced

N-Methylglycine, N-BOC protected

Boc-N-methylglycine≥ 98% (HPLC)

BOC-N-ME-GLY-OH

BOC-N-METHYLGLYCINE

BOC-N-ALPHA-METHYLGLYCINE

BOC-MEGLY-OH

RARECHEM EM WB 0206

T-BUTYLOXYCARBONYLSARCOSINE

N-(TERT-BUTOXYCARBONYL)SARCOSINE

N-TERT-BUTYLOXYCARBONYL-SARCOSINE

N-TERT-BUTYLOXYCARBONYL-N-METHYL-GLYCINE

N-T-BUTOXYCARBONYL SARCOSINE

N-T-BOC-SARCOSIN

N-BOC-SARCOSINE

N-BOC-N-METHYLGLYCINE

N-ALPHA-T-BUTOXYCARBONYL-N-ALPHA-METHYL-GLYCINE

N-ALPHA-T-BUTOXYCARBONYL SARCOSINE

N-ALPHA-T-BOC-N-ALPHA-METHYLGLYCINE

N-ALPHA-T-BOC-SARCOSINE

[(tert-Butoxycarbonyl)(methyl)amino]acetic acid

Boc-Sar-OH >=99.0% (T)

Boc-L-Sar-OH

BOC-SAR-OH;BOC-N-METHYLGLYCINE

2-((tert-butoxycarbonyl)(Methyl)aMino)acetic acid

BOC-SAR-OH USP/EP/BP

Tert butoxycarbonyl-l-sarcosine

2-[methyl-[(2-methylpropan-2-yl)oxycarbonyl]amino]acetic acid

Isavuconazole Impurity 70

Tert-butoxycarbonyl sarcosine

BOC(Methyl)amino]acetic acid

13734-36-6

734-36-6

CH33COCONCH3CH2COOH

Amino Acid Derivatives

Specialty Synthesis

Peptide Synthesis

Amino Acids

Sarcosine [Sar]

Unusual Amino Acids