ChemicalBook > CAS DataBase List > Glycidyl phenyl ether

Glycidyl phenyl ether

Product Name
Glycidyl phenyl ether
CAS No.
122-60-1
Chemical Name
Glycidyl phenyl ether
Synonyms
PGE;2-(PHENOXYMETHYL)OXIRANE;PHENYL GLYCIDYL ETHER;1,2-EPOXY-3-PHENOXYPROPANE;ageflexpge;heloxywc-63;Ageflex pge;PHENYLGYCIDYLETHER;PHENYL GLYCID ETHER;PHENYLGLYCIDOLETHER
CBNumber
CB2429443
Molecular Formula
C9H10O2
Formula Weight
150.17
MOL File
122-60-1.mol
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Glycidyl phenyl ether Property

Melting point:
3.5 °C(lit.)
Boiling point:
245-247 °C(lit.)
Density 
1.109 g/mL at 25 °C(lit.)
vapor density 
5.2 (vs air)
vapor pressure 
0.03 mm Hg ( 20 °C)
refractive index 
n20/D 1.531
Flash point:
>230 °F
storage temp. 
Store below +30°C.
solubility 
2.4g/l
form 
Liquid
color 
Clear colorless to yellow
Water Solubility 
2.4 g/L (20 ºC)
BRN 
2744
Exposure limits
TLV-TWA 6 mg/m3 (1 ppm) (ACGIH); 1 ppm (15 min) (NIOSH).
Stability:
Stable. Incompatible with strong oxidizing agents.
InChIKey
FQYUMYWMJTYZTK-UHFFFAOYSA-N
LogP
1.61 at 25℃
CAS DataBase Reference
122-60-1(CAS DataBase Reference)
NIST Chemistry Reference
Oxirane, (phenoxymethyl)-(122-60-1)
IARC
2B (Vol. 47, 71) 1999
EPA Substance Registry System
Phenyl glycidyl ether (122-60-1)
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Safety

Hazard Codes 
T
Risk Statements 
45-20-37/38-43-52/53-68
Safety Statements 
53-45-61
RIDADR 
2810
WGK Germany 
3
RTECS 
TZ3675000
Autoignition Temperature
430 °C
TSCA 
Yes
HazardClass 
IRRITANT
HS Code 
29109000
Hazardous Substances Data
122-60-1(Hazardous Substances Data)
Toxicity
LD50 orally in Rabbit: 2150 mg/kg LD50 dermal Rabbit 1500 mg/kg
IDLA
100 ppm
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H315Causes skin irritation

H317May cause an allergic skin reaction

H332Harmful if inhaled

H335May cause respiratory irritation

H341Suspected of causing genetic defects

H350May cause cancer

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P202Do not handle until all safety precautions have been read and understood.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P308+P313IF exposed or concerned: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
8.20553
Product name
2,3-Epoxypropyl phenyl ether
Purity
for synthesis
Packaging
250ML
Price
$49.8
Updated
2024/03/01
Sigma-Aldrich
Product number
8.20553
Product name
2,3-Epoxypropyl phenyl ether
Purity
for synthesis
Packaging
20kg
Price
$895
Updated
2024/03/01
Sigma-Aldrich
Product number
248487
Product name
1,2-Epoxy-3-phenoxypropane
Purity
99%
Packaging
50g
Price
$55.9
Updated
2024/03/01
Sigma-Aldrich
Product number
248487
Product name
1,2-Epoxy-3-phenoxypropane
Purity
99%
Packaging
250g
Price
$161
Updated
2024/03/01
TCI Chemical
Product number
G0098
Product name
Glycidyl Phenyl Ether
Purity
>99.0%(GC)
Packaging
25g
Price
$22
Updated
2024/03/01
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Glycidyl phenyl ether Chemical Properties,Usage,Production

Chemical Properties

Phenyl glycidyl ether, also known as glycidyl phenyl ether or PGE, is a clear liquid with a sweet odor that is considered unpleasant. It is soluble in ether and benzene, but insoluble in water. It has the ability to volatilize with water vapor. It is used in the production of epoxy resins, as a chemical intermediate, and as a stabilizer.

Uses

Phenyl glycidyl ether (PGE) is utilized in organic syntheses as an intermediate. As a reactive diluent, PGE is incorporated into uncured epoxy resins to lower viscosity, thereby facilitating casting, adhesives, and laminating applications.

Uses

2-Phenylglycidyl ether is an organic synthesis; chemical intermediate with high solvency for halogenated materials; reactive diluent of epoxy-resin systems; forms chemical bonds with the resin during cure and accelerates the curing process.

Definition

ChEBI: Phenyl glycidyl ether is an aromatic ether.

Production Methods

PGE is synthesized by condensation of phenol with epichlorohydrin, with subsequent dehydrochlorination with caustic to form the epoxy ring.

Synthesis Reference(s)

The Journal of Organic Chemistry, 50, p. 1784, 1985 DOI: 10.1021/jo00210a053

General Description

Colorless liquid.

Air & Water Reactions

Ethers tend to form unstable peroxides when exposed to oxygen. Ethyl, isobutyl, ethyl tert-butyl, and ethyl tert-pentyl ether are particularly hazardous in this respect. Ether peroxides can sometimes be observed as clear crystals deposited on containers or along the surface of the liquid. Slightly soluble in water.

Reactivity Profile

Glycidyl phenyl ether, an ether, can act as a base. They form salts with strong acids and addition complexes with Lewis acids. The complex between diethyl ether and boron trifluoride is an example. Ethers may react violently with strong oxidizing agents. In other reactions, which typically involve the breaking of the carbon-oxygen bond, ethers are relatively inert.

Health Hazard

PGE is a toxic compound exhibiting moderate irritant action and carcinogenicity inanimals. Application of 0.25 mg resulted insevere eye irritation in rabbits, while 500 mgcaused moderate skin irritation over a periodof 24 hours. Prolonged or repeated contactcan cause moderate irritation and skin sensitization in humans.
The symptoms of its toxicity in animalswere depression of the central nervous system and paralysis of the respiratory tract.Prolonged exposure caused changes in thekidney, liver, thymus, and testes, and lossof hair in rats. The toxicity of this compound in humans is low and the health hazardcan arise primarily from its skin-sensitizationaction.
LD50 value, oral (mice): 1400 mg/kg
DGE showed carcinogenicity in rats, causingnasal cancer.

Fire Hazard

Glycidyl phenyl ether is probably combustible.

Contact allergens

This monoglycidyl derivative is a reactive diluent in epoxy resins Bisphenol A type. It is a component of epoxy paints, epoxy glues, and epoxy resins. Sensitization has been observed in many professions, such as in construction workers, marble workers, ceramic workers, and shoemakers.

Safety Profile

Confirmed carcinogen with experimental carcinogenic data. Moderately toxic by ingestion, skin contact, and subcutaneous routes. A severe eye and skin irritant. Experimental reproductive effects. Mutation data reported. When heated to decomposition it emits acrid smoke and irritating fumes. Used as a chemical intermediate. See also ETHERS

Potential Exposure

PGE is used to increase storage time and stability of halogenated compounds; as a reactive diluent in uncured epoxy resins to reduce the viscosity of the uncured system for ease in casting; adhesive, and laminating applications. NIOSH once estimated that 8000 workers are potentially exposed to PGE.

Carcinogenicity

Chronic exposure of rats to 1 or 12ppm 6 hours/day, 5 days/week for 2 years caused an increased incidence of rhinitis, squamous metaplasia, and epidermal carcinomas of the nasal cavity.4 The IARC has determined that there is sufficient evidence for the carcinogenicity of PGE in animals and that it is possibly carcinogenic to humans.

Shipping

UN2810 Toxic liquids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required.

Incompatibilities

Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides, amines, and curing agents. PGE can presumably form explosive peroxides

Waste Disposal

Concentrated waste containing no peroxides-discharge liquid at a controlled rate near a pilot flame. Concentrated waste containing peroxidesperforation of a container of the waste from a safe distance followed by open burning.

Glycidyl phenyl ether Preparation Products And Raw materials

Raw materials

Potassium carbonate Epichlorohydrin

Preparation Products

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View Lastest Price from Glycidyl phenyl ether manufacturers

Hebei Yanxi Chemical Co., Ltd.
Product
Glycidyl phenyl ether 122-60-1
Price
US $30.00-10.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
10 tons
Release date
2023-10-07
Hebei Guanlang Biotechnology Co., Ltd.
Product
Glycidyl phenyl ether 122-60-1
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500000kg
Release date
2023-01-03
Zhuozhou Wenxi import and Export Co., Ltd
Product
1,2-Epoxy-3-phenoxypropane 99% 122-60-1
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-06-27

122-60-1, Glycidyl phenyl etherRelated Search:

Guaifenesin Phenyl salicylate Propylene oxide DIGLYCIDYL ETHER Ethylene glycol diglycidyl ether Diphenyl ether 1,2,3-PROPANETRIOL GLYCIDYL ETHER Cuminaldehyde Cumene Dimethyl ether BISPHENOL A DIGLYCIDYL ETHER RESIN Diisopropyl ether Butyl glycidyl ether Glycidyl acrylate BENZYL GLYCIDYL ETHER Styrene oxide Resin epoxy PHENYL RESIN

  • GLYCIDYL PHENYL ETHER
  • 2,3-EPOXYPROPYL PHENYL ETHER
  • Phenyl tlycidyl ether
  • PHENYL 2,3-EPOXYPROPYL ETHER
  • PHENYL GLYCID ETHER
  • PHENYL GLYCIDYL ETHER
  • PGE
  • 1-PHENOXY-2,3-PROPYLENE OXIDE
  • 2-(PHENOXYMETHYL)OXIRANE
  • 1,2-EPOXYETHYL PHENYL ETHER
  • 1,2-EPOXY-3-PHENOXYPROPANE
  • PHENYL GLYCIDYL ETHER (1,2-EPOXY-3-PHENOXYPROPANE)
  • PHENYLGYCIDYLETHER
  • PHENYLGLYCIDOLETHER
  • 1,2-EPOXYPHENOXYPROPANE
  • (2,3-epoxypropoxy)-benzen
  • (2,3-epoxypropoxy)benzene
  • (phenoxymethyl)-oxiran
  • (Phenoxymethyl)oxirane
  • (phenoxymethyl)-Oxirane
  • 1,2-epoxy-3-phenoxy-propan
  • 1-Phenoxy-2,3-epoxypropane
  • 2,3-Epoxy-1-phenoxypropane
  • 2,3-Epoxypropoxybenzene
  • 3-(phenyloxy)-1,2-epoxypropane
  • 3-Phenoxy-1,2-epoxypropane
  • 3-Phenoxy-1,2-propylene oxide
  • 3-phenoxy-1,2-propyleneoxide
  • gamma-phenoxypropyleneoxide
  • Glycidol phenyl ether
  • glycidolphenylether
  • heloxywc-63
  • Oxirane, (phenoxymethyl)-phenol-glycidaether
  • oxirane,(phenoxymethyl)-
  • oxydedephenyletdeglycidyle
  • Phenol glycidyl ether
  • Phenol-glycidaether
  • phenolglycidylether
  • Phenoxypropene oxide
  • phenoxypropeneoxide
  • Phenoxypropylene oxide
  • phenyl glycidyl ether 2,3-epoxypropyl phenyl ether 1,2-epoxy-3-phenoxypropane
  • 1,2-Epoxy-3-phenoxypropane, 2,3-Epoxypropyl phenyl ether, Glycidyl phenyl ether
  • 2,3-Epoxypropyl phenyl ether, Glycidyl phenyl ether, Phenyl glycidyl ether
  • 1,2-Epoxy-3-phenoxybenzene
  • N-Cyclohexyl-N-methoxy-2,5-dimethylfuran-3-carboxamide
  • N-Methoxy N-cyclohexyl-2,5-dimethyl-3-furancarboxamide
  • Phenyl(oxiranylmethyl) ether
  • Glycidyl phenyl ether,99%
  • 1,2-EPOXY-3-PHENOXYPROPANE,TECH.
  • Oxirane,2-(phenoxymethyl)-
  • 2,3-Epoxypropyl phenyl ether for synthesis
  • Glycidyl phenyl ether, epoxy value:>=0.5 mol/100 g
  • 3-Phenyloxy-1,2-epoxypropane
  • 3-Phenyloxy-1,2-epoxypropanel-, (+)-
  • Ageflex pge
  • ageflexpge
  • Benzene, (2,3-epoxypropoxy)-