(2R)-(-)-GLYCIDYL 4-NITROBENZOATE

Product Name: (2R)-(-)-GLYCIDYL 4-NITROBENZOATE
CAS No.: 106268-95-5
Chemical Name: (2R)-(-)-GLYCIDYL 4-NITROBENZOATE
Synonyms: GLYCIDYL4-NITROBENZOATE;(R)-(-)-GLYCIDYL-4-NITROBENZOATE;(2R)-(-)-GLYCIDYL 4-NITROBENZOATE;4-nitrobenzoate,(r)-oxiranemethano;(R)-oxiran-2-ylmethyl 4-nitrobenzoate;(R)-(-)-Oxirane-2-methanol 4-nitrobenzoate;2-Oxiranemethanol, 2-(4-nitrobenzoate), (2R)-;(2r)-(-)-(2,3-epoxypropylester)-4-nitrobenzoate;(R)-(-)-Glycidyl 4-nitrobenzoate, (R)-(-)-Oxirane-2-methanol 4-nitrobenzoate
CBNumber: CB2440198
Molecular Formula: C10H9NO5
Formula Weight: 223.18
MOL File: 106268-95-5.mol

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(2R)-(-)-GLYCIDYL 4-NITROBENZOATE Property

Melting point:: 60-62 °C (lit.)
storage temp.: 2-8°C
optical activity: [α]19/D 37°, c = 1.08 in chloroform
BRN: 5278590

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Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-36
WGK Germany: 3
RTECS: RR0511000
F: 10-21

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 300438
Product name: (2R)-(?)-Glycidyl 4-nitrobenzoate
Purity: 98%
Packaging: 1g
Price: $97.5
Updated: 2023/01/07

American Custom Chemicals Corporation

Product number: AAA0003184
Product name: (R)-(-)-GLYCIDYL-4-NITROBENZOATE
Purity: 95.00%
Packaging: 1G
Price: $680.11
Updated: 2021/12/16

AHH

Product number: MT-14277
Product name: (R)-(-)-Glycidyl-4-nitrobenzoate
Purity: 98%
Packaging: 10g
Price: $328
Updated: 2021/12/16

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(2R)-(-)-GLYCIDYL 4-NITROBENZOATE Chemical Properties,Usage,Production

Uses

(2R)-(?)-Glycidyl 4-nitrobenzoate can be used as a starting material in the total synthesis of leukotriene B4.

Purification Methods

Purify glycidol by fractional distillation.The 4-nitrobenzoates have m 56o (±); m 60-62o, [] D20 -37.9o (c 3.38 CHCl3) for R-(-)-isomer [106268-95-5];m 60-62o, [] D20 +38o (c 1 CHCl3) for the S-(+)-isomer [115459-65-9] and are recrystallised from Et2O or Et2O/pet ether (b 40-60o) [S-isomer: Burgos et al. J Org Chem 52 4973 1987, Sowden & Fischer J Am Chem Soc 64 1291 1942.] [Beilstein 17 I 50, 17 III/IV 985, 17/3 V 9.]

(2R)-(-)-GLYCIDYL 4-NITROBENZOATE Preparation Products And Raw materials

Raw materials

Preparation Products

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(2R)-(-)-GLYCIDYL 4-NITROBENZOATE Suppliers

China 9 Germany 1 Switzerland 1 United Kingdom 2 United States 4 Global 17

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106268-95-5, (2R)-(-)-GLYCIDYL 4-NITROBENZOATERelated Search:

2-Benzyloxyethanol 4-Nitrobenzoic acid N-PROPYL 4-AMINOBENZOATE GLYCIDYL METHYL ETHER Ethyl p-nitrobenzoate 4-Nitrobenzyl alcohol (S)-Oxiranemethanol BENZYL GLYCIDYL ETHER 3-Benzyloxy-1-propanol 4-(METHOXYMETHYL)ANILINE (S)-(-)-Propylene oxide Methyl 4-nitrobenzoate Methyl 4-aminobenzoate Benzocaine (R)-(-)-Benzyl glycidyl ether (R)-(-)-Methyl glycidyl ether (S)-(+)-GLYCIDYL-4-NITROBENZOATE,(2S)-(+)-GLYCIDYL 4-NITROBENZOATE (R)-(-)-1-BENZYLOXY-2-PROPANOL

(2r)-(-)-(2,3-epoxypropylester)-4-nitrobenzoate

4-nitrobenzoate,(r)-oxiranemethano

(R)-(-)-GLYCIDYL-4-NITROBENZOATE

(2R)-(-)-GLYCIDYL 4-NITROBENZOATE

GLYCIDYL4-NITROBENZOATE

(R)-(-)-Oxirane-2-methanol 4-nitrobenzoate

(R)-(-)-Glycidyl 4-nitrobenzoate, (R)-(-)-Oxirane-2-methanol 4-nitrobenzoate

2-Oxiranemethanol, 2-(4-nitrobenzoate), (2R)-

(R)-oxiran-2-ylmethyl 4-nitrobenzoate

106268-95-5

C10H9NO5

Chiral Building Blocks

Asymmetric Synthesis

Organic Building Blocks

Epoxides