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(2R)-(-)-GLYCIDYL 4-NITROBENZOATE

Product Name
(2R)-(-)-GLYCIDYL 4-NITROBENZOATE
CAS No.
106268-95-5
Chemical Name
(2R)-(-)-GLYCIDYL 4-NITROBENZOATE
Synonyms
GLYCIDYL4-NITROBENZOATE;(R)-(-)-GLYCIDYL-4-NITROBENZOATE;(2R)-(-)-GLYCIDYL 4-NITROBENZOATE;4-nitrobenzoate,(r)-oxiranemethano;(R)-oxiran-2-ylmethyl 4-nitrobenzoate;(R)-(-)-Oxirane-2-methanol 4-nitrobenzoate;2-Oxiranemethanol, 2-(4-nitrobenzoate), (2R)-;(2r)-(-)-(2,3-epoxypropylester)-4-nitrobenzoate;(R)-(-)-Glycidyl 4-nitrobenzoate, (R)-(-)-Oxirane-2-methanol 4-nitrobenzoate
CBNumber
CB2440198
Molecular Formula
C10H9NO5
Formula Weight
223.18
MOL File
106268-95-5.mol
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(2R)-(-)-GLYCIDYL 4-NITROBENZOATE Property

Melting point:
60-62 °C (lit.)
storage temp. 
2-8°C
optical activity
[α]19/D 37°, c = 1.08 in chloroform
BRN 
5278590
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36
WGK Germany 
3
RTECS 
RR0511000
F 
10-21
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
300438
Product name
(2R)-(?)-Glycidyl 4-nitrobenzoate
Purity
98%
Packaging
1g
Price
$97.5
Updated
2023/01/07
American Custom Chemicals Corporation
Product number
AAA0003184
Product name
(R)-(-)-GLYCIDYL-4-NITROBENZOATE
Purity
95.00%
Packaging
1G
Price
$680.11
Updated
2021/12/16
AHH
Product number
MT-14277
Product name
(R)-(-)-Glycidyl-4-nitrobenzoate
Purity
98%
Packaging
10g
Price
$328
Updated
2021/12/16
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(2R)-(-)-GLYCIDYL 4-NITROBENZOATE Chemical Properties,Usage,Production

Uses

(2R)-(?)-Glycidyl 4-nitrobenzoate can be used as a starting material in the total synthesis of leukotriene B4.

Purification Methods

Purify glycidol by fractional distillation.The 4-nitrobenzoates have m 56o (±); m 60-62o, [] D20 -37.9o (c 3.38 CHCl3) for R-(-)-isomer [106268-95-5];m 60-62o, [] D20 +38o (c 1 CHCl3) for the S-(+)-isomer [115459-65-9] and are recrystallised from Et2O or Et2O/pet ether (b 40-60o) [S-isomer: Burgos et al. J Org Chem 52 4973 1987, Sowden & Fischer J Am Chem Soc 64 1291 1942.] [Beilstein 17 I 50, 17 III/IV 985, 17/3 V 9.]

(2R)-(-)-GLYCIDYL 4-NITROBENZOATE Preparation Products And Raw materials

Raw materials

Preparation Products

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(2R)-(-)-GLYCIDYL 4-NITROBENZOATE Suppliers

China 9 Germany 1 Switzerland 1 United Kingdom 2 United States 4 Global 17
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Advantage
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106268-95-5, (2R)-(-)-GLYCIDYL 4-NITROBENZOATERelated Search:

2-Benzyloxyethanol 4-Nitrobenzoic acid N-PROPYL 4-AMINOBENZOATE GLYCIDYL METHYL ETHER Ethyl p-nitrobenzoate 4-Nitrobenzyl alcohol (S)-Oxiranemethanol BENZYL GLYCIDYL ETHER 3-Benzyloxy-1-propanol 4-(METHOXYMETHYL)ANILINE (S)-(-)-Propylene oxide Methyl 4-nitrobenzoate Methyl 4-aminobenzoate Benzocaine (R)-(-)-Benzyl glycidyl ether (R)-(-)-Methyl glycidyl ether (S)-(+)-GLYCIDYL-4-NITROBENZOATE,(2S)-(+)-GLYCIDYL 4-NITROBENZOATE (R)-(-)-1-BENZYLOXY-2-PROPANOL

  • (2r)-(-)-(2,3-epoxypropylester)-4-nitrobenzoate
  • 4-nitrobenzoate,(r)-oxiranemethano
  • (R)-(-)-GLYCIDYL-4-NITROBENZOATE
  • (2R)-(-)-GLYCIDYL 4-NITROBENZOATE
  • GLYCIDYL4-NITROBENZOATE
  • (R)-(-)-Oxirane-2-methanol 4-nitrobenzoate
  • (R)-(-)-Glycidyl 4-nitrobenzoate, (R)-(-)-Oxirane-2-methanol 4-nitrobenzoate
  • 2-Oxiranemethanol, 2-(4-nitrobenzoate), (2R)-
  • (R)-oxiran-2-ylmethyl 4-nitrobenzoate
  • 106268-95-5
  • C10H9NO5
  • Chiral Building Blocks
  • Asymmetric Synthesis
  • Organic Building Blocks
  • Epoxides