ChemicalBook > CAS DataBase List > Ethyl 3-(4-fluorophenyl)-3-oxopropanoate

Ethyl 3-(4-fluorophenyl)-3-oxopropanoate

Product Name
Ethyl 3-(4-fluorophenyl)-3-oxopropanoate
CAS No.
1999-00-4
Chemical Name
Ethyl 3-(4-fluorophenyl)-3-oxopropanoate
Synonyms
ETHYL 4-FLUOROBENZOYLACETATE;Ethyl-4-FluorobenzoyalAcetate;ETHYL (P-FLUOROBENZOYL)ACETATE;Ethyl(4-Fluorobenzoyl)acetate>3-(4'-Fluorophenyl)-3-oxopropanoate;Ethyl (4-Fluorobenzoyl)acetate, 96%+;Ethyl (4-Fluorobenzoyl)acetate, >=97%;Ethyl 4-fluoro-β-oxobenzenepropanoate;p-Fluorobenzoylacetic acid ethyl ester;2-[(4-fluorophenyl)-oxomethyl]butanoate
CBNumber
CB2480433
Molecular Formula
C11H11FO3
Formula Weight
210.2
MOL File
1999-00-4.mol
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Ethyl 3-(4-fluorophenyl)-3-oxopropanoate Property

Melting point:
117-120℃
Boiling point:
117-120 °C(lit.)
Density 
1.174 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.5040(lit.)
Flash point:
>230 °F
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
form 
clear liquid
pka
9.82±0.25(Predicted)
Specific Gravity
1.19
color 
Colorless to Almost colorless
InChIKey
SJUXLKYJKQBZLM-UHFFFAOYSA-N
CAS DataBase Reference
1999-00-4(CAS DataBase Reference)
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Safety

Hazard Codes 
Xi
Safety Statements 
24/25
WGK Germany 
3
Hazard Note 
Irritant
HS Code 
29183000
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P312Call a POISON CENTER or doctor/physician if you feel unwell.

P321Specific treatment (see … on this label).

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
146293
Product name
Ethyl (4-fluorobenzoyl)acetate
Packaging
5g
Price
$116
Updated
2024/03/01
Sigma-Aldrich
Product number
146293
Product name
Ethyl (4-fluorobenzoyl)acetate
Packaging
1g
Price
$63.4
Updated
2023/06/20
TCI Chemical
Product number
F0435
Product name
Ethyl (4-Fluorobenzoyl)acetate
Purity
>98.0%(GC)(T)
Packaging
1g
Price
$80
Updated
2024/03/01
TCI Chemical
Product number
F0435
Product name
Ethyl (4-Fluorobenzoyl)acetate
Purity
>98.0%(GC)(T)
Packaging
5g
Price
$239
Updated
2024/03/01
Alfa Aesar
Product number
H61813
Product name
Ethyl (4-fluorobenzoyl)acetate, 95%
Packaging
5g
Price
$232
Updated
2021/12/16
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Ethyl 3-(4-fluorophenyl)-3-oxopropanoate Chemical Properties,Usage,Production

Chemical Properties

Colorless liquid

Uses

Reactant used as a precursor in:

  • Condensation reactions with diamines via C-C bond cleavage for synthesis of benzimidazoles and perimidines for possible use as antimalarial treatments
  • Base-promoted domino Michael addition / cyclization / elimination reactions for synthesis of hydroxybenzophenones
  • Oxidative cross-coupling with indoles via dioxygen activation
  • Cyclization of keto esters for synthesis of pyrones
  • Lewis base catalyzed hydrosilylation for synthesis of α-acetoxy β-amino acid derivatives
  • Conia-ene reactions for synthesis of methylenecyclopentane derivatives

General Description

Ethyl (4-fluorobenzoyl)acetate on condensation with benzofurazan oxide yields 2-(carboethoxy)-3-(4′-fluoro)phenylquinoxaline1,4-dioxide.

Ethyl 3-(4-fluorophenyl)-3-oxopropanoate Preparation Products And Raw materials

Raw materials

Preparation Products

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Ethyl 3-(4-fluorophenyl)-3-oxopropanoate Suppliers

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View Lastest Price from Ethyl 3-(4-fluorophenyl)-3-oxopropanoate manufacturers

Hebei Guanlang Biotechnology Co., Ltd.
Product
Ethyl 3-(4-fluorophenyl)-3-oxopropanoate 1999-00-4
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20 mt
Release date
2023-03-02
Career Henan Chemical Co
Product
Ethyl 3-(4-fluorophenyl)-3-oxopropanoate 1999-00-4
Price
US $500.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1ton
Release date
2018-08-04

1999-00-4, Ethyl 3-(4-fluorophenyl)-3-oxopropanoateRelated Search:

Ethyl acetate Ethyl formate Calcium folinate Ethylparaben ISOXADIFEN-ETHYL Ethyl benzoylacetate Ethyl pyruvate Ethyl cyanoacetate Ethyl oleate Ethyl propionylacetate Tris(trimethylsilyl)phosphate Ethyl malonyl chloride Dibenzoylmethane Ethanol Ethyl acrylate Benzoyl peroxide PHENOXYACETIC ACID Ethyl 1-ethyl-6,7,8-trifluoro-1,4-dihydro-4-oxoquinoline-3-carboxylate

  • (4-FLUOROBENZOYL)ACETIC ACID ETHYL ESTER
  • 3-(4'-Fluorophenyl)-3-oxopropanoate
  • ETHYL 3-(4'-FLUOROPHENYL)-3-OXOPROPNOATE
  • ETHYL 4-FLUOROBENZOYLACETATE
  • ETHYL (P-FLUOROBENZOYL)ACETATE
  • 3-(4-FLUORO-PHENYL)-3-OXO-PROPIONIC ACID ETHYL ESTER
  • 3-Oxo-3-(4-fluorophenyl)propanoic acid ethyl ester
  • p-Fluorobenzoylacetic acid ethyl ester
  • β-Oxo-4-fluorobenzenepropionic acid ethyl ester
  • Ethyl-4-FluorobenzoyalAcetate
  • Benzenepropanoic acid, 4-fluoro-b-oxo-, ethyl ester
  • Benzenepropanoic acid, 4-fluoro-β-oxo-, ethyl ester
  • Benzenepropanoic acid, 4-fluoro-beta-oxo-, ethyl ester
  • 4-Fluoro--oxobenzenepropanoic acid ethyl ester
  • Ethyl 3-(4-fluorophenyl)-3-oxopropionate
  • Ethyl (4-Fluorobenzoyl)acetate, >=97%
  • Ethyl 3-(4-Fluorophenyl)-3-Oxopropanoate Min 96%
  • ETHYL 3-(4-FLUOROPHENYL)-3-OXOPROPANOATE
  • 2-[(4-fluorophenyl)-oxomethyl]butanoate
  • Ethyl(4-Fluorobenzoyl)acetate&gt
  • ? Benzenepropanoic acid, 4-fluoro-β-oxo-, ethyl ester
  • Ethyl (4-Fluorobenzoyl)acetate, 96%+
  • Ethyl 4-fluoro-β-oxobenzenepropanoate
  • 1999-00-4
  • Building Blocks
  • C10 to C11
  • Carbonyl Compounds
  • Organic Building Blocks
  • Esters
  • Benzene series
  • Benzoic acid
  • Acids & Esters
  • Fluorine Compounds