CATECHOLBORANE

Product Name: CATECHOLBORANE
CAS No.: 274-07-7
Chemical Name: CATECHOLBORANE
Synonyms: 1,3,2-BENZODIOXABOROLE;Benzo[1,3,2]dioxaborole;Catchelborane;1,3,2;C6H5BO2;O-dioxolane;Ctecholborane;CATECHOLBORANE;Catecholatoborane;Benzcatechinborane
CBNumber: CB2490830
Molecular Formula: C6H5BO2
Formula Weight: 119.91
MOL File: 274-07-7.mol

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CATECHOLBORANE Property

Melting point:: 12 °C(lit.)
Boiling point:: 50 °C50 mm Hg(lit.)
Density: 1.125 g/mL at 25 °C(lit.)
refractive index: n20/D 1.507(lit.)
Flash point:: 36 °F
storage temp.: 2-8°C
solubility: Miscible with diethyl ether, tetrahydrofuran, dichloromethane, chloroform, carbon tetrachloride, toluene, and benzene.
form: liquid
color: Hazy Colourless
Water Solubility: Reacts with water.
Sensitive: Moisture Sensitive
BRN: 972072
Stability:: Hygroscopic
InChIKey: CENMEJUYOOMFFZ-UHFFFAOYSA-N
CAS DataBase Reference: 274-07-7(CAS DataBase Reference)
EPA Substance Registry System: 1,3,2-Benzodioxaborole (274-07-7)

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Safety

Hazard Codes: F,C
Risk Statements: 11-19-34-67-65-63-48/20-14-40-37
Safety Statements: 26-36/37/39-45-62-16-43
RIDADR: UN 2924 3/PG 2
WGK Germany: 3
F: 1-10
TSCA: Yes
HazardClass: 3
PackingGroup: II
HS Code: 29209090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H225Highly Flammable liquid and vapour

H314Causes severe skin burns and eye damage

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 188913
Product name: Catecholborane
Purity: 98%
Packaging: 25g
Price: $296
Updated: 2024/03/01

Sigma-Aldrich

Product number: 188913
Product name: Catecholborane
Purity: 98%
Packaging: 100g
Price: $604
Updated: 2024/03/01

Alfa Aesar

Product number: H30234
Product name: Catecholborane, 50% w/w in toluene (98% dry wt.)
Packaging: 100g
Price: $1008
Updated: 2021/12/16

Alfa Aesar

Product number: H30234
Product name: Catecholborane, 50% w/w in toluene (98% dry wt.)
Packaging: 25g
Price: $306
Updated: 2021/12/16

Sigma-Aldrich

Product number: 225762
Product name: Catecholborane solution
Purity: 1.0 M in THF
Packaging: 100ml
Price: $106
Updated: 2024/03/01

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CATECHOLBORANE Chemical Properties,Usage,Production

Chemical Properties

CATECHOLBORANE is clear colorless solution

Uses

Catecholborane is used to prepare B-alkylcatecholboranes. It finds application for the preparation of amides and macrocyclic lactams from carboxylic acids. It is used as a stereoselective reducing agent to convert beta-hydroxy ketones to syn 1,3-diols. Further, it reacts with alkyne through hydroboration to form trans vinyl borane, which is a precursor to Suzuki reaction.

Uses

CATECHOLBORANE is used in the transition metal catalyzed hydroboration of alkenes.1,2,3

Purification Methods

It is a moisture-sensitive flammable liquid which is purified by distillation in a vacuum under a N2 atmosphere and stored under N2 at 0-4o. It liberates H2 when added to H2O or MeOH. A solution in THF, after 25hours at 25o, has residual hydride of 95% (under N2) and 80% (under air) [Brown & Gupta J Am Chem Soc 97 5249 1975].

CATECHOLBORANE Preparation Products And Raw materials

Raw materials

Tetrahydrofuran Catechol Borane-tetrahydrofuran complex

Preparation Products

E-PHENYLETHENYLBORONIC ACID

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CATECHOLBORANE Suppliers

Belgium 1 China 163 Europe 1 France 1 Germany 3 India 10 Russia 1 Slovakia 1 South Korea 2 Switzerland 1 Ukraine 1 United Kingdom 5 United States 13 Global 203

Apollo Scientific Ltd.

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Email: sales@apolloscientific.co.uk
Country: United Kingdom
ProdList: 6084
Advantage: 88

CARBONE SCIENTIFIC CO.,LTD

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Email: sales@carbonesci.com
Country: United Kingdom
ProdList: 6666
Advantage: 30

Eurolabs Limited

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Country: United Kingdom
ProdList: 6309
Advantage: 46

Fluorochem Ltd.

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Email: enquiries@fluorochem.co.uk
Country: United Kingdom
ProdList: 6401
Advantage: 74

VWR International

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Email: solutions@vwr.com
Country: United Kingdom
ProdList: 6548
Advantage: 82

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View Lastest Price from CATECHOLBORANE manufacturers

Hebei Chuanghai Biotechnology Co,.LTD

Product: CATECHOLBORANE 274-07-7
Price: US $1.90/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10 ton
Release date: 2024-08-20

Henan Fengda Chemical Co., Ltd

Product: CATECHOLBORANE 274-07-7
Price: US $34.00-1.20/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: g-kg-tons, free sample is available
Release date: 2024-04-08

Henan Aochuang Chemical Co.,Ltd.

Product: CATECHOLBORANE 274-07-7
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: 1Ton
Release date: 2022-09-26

274-07-7, CATECHOLBORANERelated Search:

Phenylacetylene Sodium Methoxide Acetophenone Iodoform 9-Borabicyclo[3.3.1]nonane Boron 2-BROMO-1,3,2-BENZODIOXABOROLE CATECHOLBORANE 2,2'-Bis-1,3,2-benzodioxaborole (R)-2-hydroxy-alpha-[(methylamino)methyl]-1,3,2-benzodioxaborole-5-methanol 2-CHLORO-1,3,2-BENZODIOXABOROLE 2-PROPYL-1,3,2-BENZODIOXABOROLE 2-PHENYL-1,3,2-BENZODIOXABOROLE 4-CHLOROPHENYLBORONIC ACID, CATECHOL CYCLIC ESTER 2-(CIS-1-ETHYL-1-BUTENYL)-1 3 2-BENZODI& 2-(4-BROMOBUTYL)-1 3 2-BENZODIOXABOROLE& O-PHENYLENE BORATE DI-O-TOLYLGUANIDINE SALT OF DICATECHOLBORATE

Benzo[d][1,3,2]dioxaborole(1.0M)

CATECHOLBORANE

1,3,2-BENZODIOXABOROLE

RARECHEM AK VD 0002

Catecholborane, 1.0 M solution in THF

Catecholborane, Benzo[d][1,3,2]dioxaborole

Catecholborane, 1.0 M solution in THF, J&KSeal

Benzcatechinborane

Benzo[1,3,2]dioxaborole

C6H5BO2

Catecholatoborane

Pyrocatecholborane

Catecholborane, 50% w/w in toluene (98% dry wt.)

Catecholborane 98%

Catecholborane solution 1.0 M in THF

Catecholborane, 1.0 M solution in THF, SpcSeal

Catchelborane

1,3,2-BENZODIOXABOROLE SOLUTION, ~1 M IN TOLUENE

1,3,2-BENZODIOXABOROL

CATECHOLBORANE, 1.0M SOLUTION IN TETRAHY DROFURAN

1,3,2-BENZODIOXABOROLE ( 1M SOLUTION INTHF)

Catecholborane, 1M solution in tetrahydrofuran

Catecholborane, 98+%

1,3,2-benzodioxaborole solution

catecholborane solution

7,9-dioxa-8$l^{2}-borabicyclo[4.3.0]nona-1,3,5-triene

Catecholborane1M solution in tetrahydrofuranAcroSeal§3

1,3-Dioxa-2-boraindan

Boronic acid 1,2-phenylene ester

Catecholborane1,3,2-Benzodioxaborole

Catecholborane, 50% w/w in tol

Catecholborane, 1M solution in tetrahydrofuran, AcroSeal 100ML

Catecholborane, 1M solution in tetrahydrofuran, AcroSeal 800ML

Catecholborane, 50% w/w in toluene (99+% dry wt.)

Catecholborane, 1M solution in tetrahydrofuran, AcroSeal

Ctecholborane

1,3,2-Benzodioxaborole, 50% w/w in toluene (98% dry wt.)

1,3,2λsup2sup-benzodioxaborole

1,3,2

1,3,2λ2-benzodioxaborole

O-dioxolane

benzo[d][1,3,2]dioxaborole

Catecholborane 1. M in THF

Catechol borane 1.0 M in THF

Catecholborane - sol 1M in THF

274-07-7

247-07-7

C6H4BO2

Boronic Acids and Derivatives

Borylation Reagents

Organometallic Reagents

Boranes

Boronic Acids and Derivatives

Borylation Reagents

Chemical Synthesis

Organometallic Reagents

Synthetic Reagents

BoranesOrganometallic Reagents