3-Methyl-4-nitroaniline
- Product Name
- 3-Methyl-4-nitroaniline
- CAS No.
- 611-05-2
- Chemical Name
- 3-Methyl-4-nitroaniline
- Synonyms
- NSC 17041;4-NITRO-M-TOLUIDINE;5-AMINO-2-NITROTOLUENE;3-Amino-6-nitrotoluene;6-Nitro-3-aMinotoluene;4-nitro-3-methylaniline;3-METHYL-4-NITROANILINE;3-Mehtyl-4-nitroaniline;3-Methyl-4-nitroaniline>3-METHYL-4-NITROANILINE 99%
- CBNumber
- CB2665283
- Molecular Formula
- C7H8N2O2
- Formula Weight
- 152.15
- MOL File
- 611-05-2.mol
3-Methyl-4-nitroaniline Property
- Melting point:
- 136-137°C
- Boiling point:
- 330.0±22.0 °C(Predicted)
- Density
- 1.269±0.06 g/cm3(Predicted)
- storage temp.
- Keep in dark place,Inert atmosphere,Room temperature
- solubility
- Methanol
- form
- Solid
- pka
- 1.12±0.10(Predicted)
- color
- Brown Crystalline
- BRN
- 2209112
- CAS DataBase Reference
- 611-05-2(CAS DataBase Reference)
Safety
- Hazard Codes
- T
- Risk Statements
- 23/24/25-33-51/53
- Safety Statements
- 28-36/37-45-61
- RIDADR
- 2660
- HazardClass
- 6.1
- PackingGroup
- III
- HS Code
- 2921420090
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H301Toxic if swalloed
H311Toxic in contact with skin
H331Toxic if inhaled
H373May cause damage to organs through prolonged or repeated exposure
H401Toxic to aquatic life
H411Toxic to aquatic life with long lasting effects
- Precautionary statements
-
P273Avoid release to the environment.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P309IF exposed or if you feel unwell:
P310Immediately call a POISON CENTER or doctor/physician.
N-Bromosuccinimide Price
- Product number
- M1677
- Product name
- 3-Methyl-4-nitroaniline
- Purity
- >97.0%(GC)
- Packaging
- 5g
- Price
- $37
- Updated
- 2025/07/31
- Product number
- M1677
- Product name
- 3-Methyl-4-nitroaniline
- Purity
- >97.0%(GC)
- Packaging
- 25g
- Price
- $186
- Updated
- 2025/07/31
- Product number
- M323580
- Product name
- 3-Methyl-4-nitrobenzeneamine
- Packaging
- 250mg
- Price
- $105
- Updated
- 2021/12/16
- Product number
- 9147AB
- Product name
- 3-Methyl-4-nitroaniline
- Packaging
- 1g
- Price
- $68
- Updated
- 2021/12/16
- Product number
- CHM0023780
- Product name
- 3-METHYL-4-NITRO ANILINE
- Purity
- 95.00%
- Packaging
- 1G
- Price
- $597.87
- Updated
- 2021/12/16
3-Methyl-4-nitroaniline Chemical Properties,Usage,Production
Chemical Properties
Brown Crystalline Solid
Uses
3-Methyl-4-nitrobenzeneamine (cas# 611-05-2) is a compound useful in organic synthesis.
Synthesis Reference(s)
Synthetic Communications, 18, p. 2161, 1988 DOI: 10.1080/00397918808068287
Synthesis
99584-85-7
611-05-2
General procedure for the synthesis of 3-methyl-4-nitroaniline (20-2) from 3-methyl-4-nitrobenzamide (20-1, 40 g, 222 mmol): 20-1 was dissolved in 400 mL of methanol/water (v/v=1/1) mixed solvent and cooled to 0 °C. Subsequently, sodium hydroxide (35.6 g, 888 mmol) was added to the solution and stirred for 0.5 hours. Sodium hypochlorite solution (380 g, 556 mmol) was added slowly and dropwise at 0°C. The reaction mixture was gradually warmed up to room temperature (20°C) and stirring was continued for 18 hours. After that, the mixture was further warmed up to 35°C and stirred for 1 hour, then warmed up to 75°C and stirred for 0.5 hours. After completion of the reaction, the mixture was cooled to room temperature. The pH was adjusted to 6.0 with hydrochloric acid, at which time a brown precipitate was produced. The precipitate was collected by filtration and washed twice with 200 mL of water to give the final 20-2 (29 g, 86% yield) as a tan powder.
References
[1] Patent: US9138427, 2015, B2. Location in patent: Page/Page column 297
3-Methyl-4-nitroaniline Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 3-Methyl-4-nitroaniline manufacturers
- Product
- 3-Methyl-4-nitroaniline 611-05-2
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 99.0%
- Supply Ability
- 100 tons
- Release date
- 2022-02-21
- Product
- 3-Methyl-4-nitroaniline 611-05-2
- Price
- US $1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 100kg
- Release date
- 2019-07-12