1,1'-Bis(diphenylphosphino)ferrocene

ChemicalBook > CAS DataBase List > 1,1'-Bis(diphenylphosphino)ferrocene

1,1'-Bis(diphenylphosphino)ferrocene

Reaction

Product Name: 1,1'-Bis(diphenylphosphino)ferrocene
CAS No.: 12150-46-8
Chemical Name: 1,1'-Bis(diphenylphosphino)ferrocene
Synonyms: DPPF;Bis(diphenylphosphino)ferrocene;1,1'-FERROCENEDIYL-BIS(DIPHENYLPHOSPHINE);98% DPPF;1,1'-Bis(diphenylpho;Terazolamide Impurity 83;Zirconium ionophore I ;phosphino)ferrocene (DPPF);1,1-(twophenylphosphine)Er Maotie;Cyclopentadienyldiphenylphosphine
CBNumber: CB2746748
Molecular Formula: C34H28FeP210*
Formula Weight: 554.38
MOL File: 12150-46-8.mol

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1,1'-Bis(diphenylphosphino)ferrocene Property

Melting point:: 181-182 °C (dec.)(lit.)
storage temp.: 2-8°C
solubility: Chloroform, Ethyl Acetate
form: crystal
color: yellow to orange
Water Solubility: Soluble in chloroform, dichloromethane, alcohol and pentane. Insoluble in water.
Sensitive: Air Sensitive
Hydrolytic Sensitivity: 7: reacts slowly with moisture/water
Stability:: Stable. Incompatible with strong oxidizing agents.
CAS DataBase Reference: 12150-46-8(CAS DataBase Reference)
NIST Chemistry Reference: 1,1'-Bis(diphenylphosphino)ferrocene(12150-46-8)

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Safety

Hazard Codes: T,Xi,Xn
Risk Statements: 25-36/37/38-20/21/22
Safety Statements: 22-24/25-45-28A-36-26-36/37/39
RIDADR: 3467
WGK Germany: 3
F: 10-23
TSCA: No
HazardClass: IRRITANT
HS Code: 29319090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 177261
Product name: 1,1′-Bis(diphenylphosphino)ferrocene
Purity: 97%
Packaging: 1g
Price: $37.5
Updated: 2024/03/01

Sigma-Aldrich

Product number: 177261
Product name: 1,1′-Bis(diphenylphosphino)ferrocene
Purity: 97%
Packaging: 10g
Price: $212
Updated: 2024/03/01

TCI Chemical

Product number: B2027
Product name: 1,1'-Bis(diphenylphosphino)ferrocene
Purity: >96.0%(T)
Packaging: 1g
Price: $26
Updated: 2024/03/01

TCI Chemical

Product number: B2027
Product name: 1,1'-Bis(diphenylphosphino)ferrocene
Purity: >96.0%(T)
Packaging: 5g
Price: $46
Updated: 2024/03/01

Alfa Aesar

Product number: B21166
Product name: 1,1'-Bis(diphenylphosphino)ferrocene, 97%
Packaging: 1g
Price: $49.3
Updated: 2023/06/20

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1,1'-Bis(diphenylphosphino)ferrocene Chemical Properties,Usage,Production

Reaction

Ligand for Pd-catalyzed cross-coupling.
Useful ligand for Pd-catalyzed carbon-nitrogen and carbon-oxygen bond forming procedures.
Ligand for Ni-catalyzed amination of aryl chlorides.
Ligand for Pd-catalyzed conversion of aryl halides to aryl nitriles.
Ligand for Ni-catalyzed Suzuki reactions.
Ni-catalyzed hydroamination of 1,3-dienes.
Pd-catalyzed hydrocarbonation and hydroamination of 3,3-dihexylcyclopropene.
Pd-catalyzed γ-arylation of β,γ-unsaturated ketones.
Ligand for Ru-catalyzed reduction of nitriles to primary amines.
Ligand for Rh-catalyzed alkyne head-to-tail dimerization.
Ligand for Rh-catalyzed cross-coupling
Ligand for Rh-catalyzed olefin isomerization
Ligand for Ni or Rh-catalyzed borylation
Ligand for regioselective Pd-catalyzed hydrophosphinylation of terminal alkynes to form branched alkenes.

Chemical Properties

1,1'-Bis(diphenylphosphino)ferrocene is deep yellow crystalline powder

Uses

1,1'-Bis(diphenylphosphino)ferrocene acts as a ligand in homogeneous catalysis. It is used as a ligand for ruthenium-catalyzed greener amine synthesis from amines and alcohols by hydrogen-borrowing. It is also employed as a ligand for Buchwald-Hartwig cross coupling. Further, it is used in the synthesis of coordination compound as well as the formation of complexes with various metals such as palladium chloride. In addition to this, it serves as a reagent for palladium-catalyzed coupling reactions and also plays an important role in Suzuki reaction.

Uses

1,1'-Bis(diphenylphosphino)ferrocene used coordination compound in synthesis, readily forms complexes with various metals, i.e. when reacting with the acetonitrile or benzonitrile complexes of PdCl2 it forms (dppf)PdCl2, which i s a popular reagent for palladium-catalyzed coupling reactions.

General Description

Novel functionalized furan derivatives were prepared via Pd-phosphine sequential C-C and C-O bond formation.

Purification Methods

Wash it with distilled H2O and dry it in a vacuum. Dissolve it in ca 5 parts of hot dioxane and cool to give orange crystals m 181-183o. Recrystallisation from *C6H6/heptane (1:2) gives a product with m 183-184o. [Bishop et al. J Organomet Chem 27 241 1971.]

1,1'-Bis(diphenylphosphino)ferrocene Preparation Products And Raw materials

Raw materials

Ferrocene N,N,N',N'-Tetramethylethylenediamine Dicyclopentadiene Ferrous chloride Chlorodiphenylphosphine Tetrahydrofuran Ethyl acetate Dichloromethane Sodium hydroxide n-Butyllithium

Preparation Products

N,N'-Bis- (1-naphthalenyl)-N,N'-bis-phenyl-(1,1'-biphenyl)-4,4'-diamine 1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex [1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II) [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)

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View Lastest Price from 1,1'-Bis(diphenylphosphino)ferrocene manufacturers

Henan Fengda Chemical Co., Ltd

Product: 1,1'-Bis(diphenylphosphino)ferrocene 12150-46-8
Price: US $5.00-2.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: g-kg-tons, free sample is available
Release date: 2024-04-16

Shanghai UCHEM Inc.

Product: 1,1'-Bis(diphenylphosphino)ferrocene 12150-46-8
Price: US $35.00-286.00/g
Min. Order: 100g
Purity: 0.98
Supply Ability: 100kg
Release date: 2023-10-20

Hebei Yanxi Chemical Co., Ltd.

Product: 1,1'-Bis(diphenylphosphino)ferrocene 12150-46-8
Price: US $20.00-1.00/kg
Min. Order: 1kg
Purity: 0.99
Supply Ability: 10 tons
Release date: 2023-10-31

12150-46-8, 1,1'-Bis(diphenylphosphino)ferroceneRelated Search:

Ferrocene Diphenylphosphine oxide Diphenylphosphine Chlorodiphenylphosphine N-(Carboxymethyl)-N-(phosphonomethyl)-glycine 1,3-Bis(diphenylphosphino)propane 1,2-Bis(diphenylphosphino)ethane nickel(II) chloride 1,2-Bis(diphenylphosphino)ethane (1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE)TETRACARBONYLCHROMIUM (S)-N,N-DIMETHYL-1-[(R)-1',2-BIS(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE (R)-CTH-JAFAPHOS Dichloro(1,1-bis(diphenylphosphino)ferrocene)palladium(II) acetone adduct [1,1'-Bis(diphenylphosphino)ferrocene]dichloronickel(II) [1,1'-Bis(diphenylphosphino)ferrocene]dichlorocobalt(II) [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS(DIPHENYLPHOSPHINO)FERROCENE (ALPHAR,ALPHAR)-1,1'-BIS[ALPHA-(DIMETHYLAMINO)BENZYL]-(S,S)-2,2'-BIS[BIS(4-METHOXY-3,5-DIMETHYLPHENYL)PHOSPHINO]FERROCENE 1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex

DPPF

1,1''-BIS(DIPHENYLPHOSPHINO)ERROCENE

1,1''-BIS(DIPHENYLPHOSPHINO)FERROCENE (DPPF)

DPPF/1,1''-BIS(DIPHENYLPHOSPHINO) FERROCENE

1,1'-Bis(diphenylphosphiNA)ferrocene

DPPF, (Ferrocene-1,1'-diyl)bis(diphenylphosphine)

1,1-(twophenylphosphine)Er Maotie

1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE

1,1'-FERROCENEDIYL-BIS(DIPHENYLPHOSPHINE)

1,1'-FERROCENEBIS(DIPHENYLPHOSPHINE)

1,1'-bis(diphenyphosphino)ferrocene

1,1'-bis(diphenyphosphino)ferrocene(dppf)

1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE, 97 %

1,1'-Bis(diphenylphosphino)ferrocene,99%DPPF

1,1'- double(twophenylphosphine)Er Maotie

1,1'-Bis(diphenylphosphino)ferrocene 97%

1,1'-Bis(diphenylphosphino)ferrocene (DPPF), 95+%

Bis(diphenylphosphino)ferrocene

1,1'-Bis(diphenylphosphino)ferrocene 1,1'-Ferrocenebis(diphenylphosphine)

1,1'-Bis(diphenylphosphino)ferrocene,98% DPPF

bis(2-(diphenylphosphino)cyclopenta-2,4-dien-1-yl)iron

dppf 1,1'-Ferrocenebis(diphenylphosphine) 1,1'-Ferrocenediyl-bis(diphenylphosphine)

Zirconium ionophore I

Ferrocene,1,1'-bis(diphenylphosphino)-

1,1'-Bis(diphenylphosphino) ferrocene, Catalyst Grade

1,1'-Bis(diphenylphosphino)ferrocene, C 73.4%, H 5.2%

1,1μ-Ferrocenebis(diphenylphosphine), 1,1μ-Ferrocenediyl-bis(diphenylphosphine)

1,1''-BIS-(DIPHENYLPHOSPHINO)-FEROCENE

1,1'-Bis(diphenylphosphino)ferrocene,98%

1,1'-Bis(diphenylphosphino)ferrocene,99%

1,1'-Bis(diphenylpho

1'-Bis(diphenylphosphino)ferrocene

1,1'-bis(diphenylphosphine) Ferrocene

98% DPPF

1,1'-Ferrocendiylbis(diphenylphosphine)

Cyclopentadienyldiphenylphosphine

1,1'-Ferrocenebis(diphenylphosphine) dppf

phosphino)ferrocene (DPPF)

1,1'-Bis(diphenylphosphino)ferrocene&gt

1,1'-Bis(diphenylphosphino)ferrocene ISO 9001：2015 REACH

cyclopenta-2,4-dien-1-yl(diphenyl)phosphane(1:2)

DPPF (1,1-Bis(Diphenylphosphino)Ferrocene) extrapure, 98%

1,1'-Bis(diphenylphosphino)ferrocene, 94%

1,1'-Bis(diphenylphosphino)ferrocene

Terazolamide Impurity 83

1,1'-bis(diphenyphosphino)ferrocene

12150-46-8

C34H28FeP2

C35H30Cl2FeP2

C6H52PC5H4FeC5H4PC6H52

Polydentate Phosphine Ligands

Phosphorus Compounds

Fe (Iron) Compounds

Ferrocenes

Metallocenes

Transition Metal Compounds

Classes of Metal Compounds

Phosphine Ligands