ChemicalBook > CAS DataBase List > SILVER TRIFLUOROMETHANESULFONATE
SILVER TRIFLUOROMETHANESULFONATE
Reactions- Product Name
- SILVER TRIFLUOROMETHANESULFONATE
- CAS No.
- 2923-28-6
- Chemical Name
- SILVER TRIFLUOROMETHANESULFONATE
- Synonyms
- AGOTF;SILVER TRIFLATE;SILVER TRIFLUOROMETHANESULPHONATE;Silver (trifluoromethyl)sulfonate;TRIFLUOROMETHANESULFONIC ACID SILVER SALT;fonate;ver trifL;uoromethanesuL;Silver(I)triflate;Indiumtrifluorometha
- CBNumber
- CB3157655
- Molecular Formula
- CAgF3O3S
- Formula Weight
- 256.94
- MOL File
- 2923-28-6.mol
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SILVER TRIFLUOROMETHANESULFONATE Property
- Melting point:
- 286 °C (lit.)
- storage temp.
- Store below +30°C.
- solubility
- Methanol (Slightly), Water (Slightly)
- form
- Powder
- color
- White to light beige
- Water Solubility
- Soluble in water and also in most organic solvents.
- Sensitive
- Light Sensitive
- Hydrolytic Sensitivity
- 6: forms irreversible hydrate
- BRN
- 3598402
- Stability:
- Stable, but may be light sensitive. Incompatible with strong acids, strong oxidizing agents.
- InChI
- InChI=1S/CHF3O3S.Ag/c2-1(3,4)8(5,6)7;/h(H,5,6,7);/q;+1/p-1
- InChIKey
- QRUBYZBWAOOHSV-UHFFFAOYSA-M
- SMILES
- C(F)(F)(F)S([O-])(=O)=O.[Ag+]
- CAS DataBase Reference
- 2923-28-6(CAS DataBase Reference)
- EPA Substance Registry System
- Methanesulfonic acid, trifluoro-, silver(1+) salt (2923-28-6)
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Safety
- Hazard Codes
- Xi,C
- Risk Statements
- 36/37/38-50-34
- Safety Statements
- 26-36-61-45-36/37/39
- RIDADR
- 3260
- WGK Germany
- 3
- F
- 8
- Hazard Note
- Corrosive
- TSCA
- Yes
- HazardClass
- 8
- HS Code
- 28432900
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H315Causes skin irritation
H318Causes serious eye damage
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 8.14325
- Product name
- Silver trifluoromethanesulfonate
- Purity
- for synthesis
- Packaging
- 5G
- Price
- $103
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- 8.14325
- Product name
- Silver trifluoromethanesulfonate
- Purity
- for synthesis
- Packaging
- 25g
- Price
- $342
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- 176435
- Product name
- Silver trifluoromethanesulfonate
- Purity
- ≥99%
- Packaging
- 1g
- Price
- $40.4
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- 176435
- Product name
- Silver trifluoromethanesulfonate
- Purity
- ≥99%
- Packaging
- 10g
- Price
- $122
- Updated
- 2024/03/01
TCI Chemical
- Product number
- T1331
- Product name
- Silver Trifluoromethanesulfonate
- Purity
- >98.0%(T)
- Packaging
- 1g
- Price
- $28
- Updated
- 2024/03/01
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SILVER TRIFLUOROMETHANESULFONATE Chemical Properties,Usage,Production
Reactions
- Silver precatalyst for the asymmetric allylation of aldehydes
- Silver catalyst for intramolecular additions of alcohols and carboxylic acids to inert olefins
- Silver catalyst for the fluorination of boronic acids
- Silver catalyst for the fluorination of functionalized aryl stannanes
- Silver catalyst for cyclopropenation of internal alkynes with donor/acceptor substituted diazo compounds
- Silver catalyst for the reaction of 2-alkynylbenzaldehyde with 2-isocyanoacetate
Chemical Properties
light beige crystalline powder
Uses
Silver Trifluoromethanesulfonate is used to generate cationic rhodium catalysts from chlororhodium complexes for the hydrophosphination of acetylenes. It is also employed as a catalyst for the preparation of silyl ethers by hydrosilylation of aldehydes.
General Description
Silver trifluoromethanesulfonate p-complexes of monoenes, dienes, trienes, monoynes and diynes have been prepared. It reacts with 2-fluoro- and 3-fluoro-4-alkoxystilbazoles to afford the mesomorphic complexes. Iodine monochloride/AgOTf constitutes an efficient promoter system for the O-glycoside synthesis.
Purification Methods
Recrystallise it twice from hot CCl4 [Alo et al. J Chem Soc, Perkin Trans 1 805 1986]. Store it in the dark. [Beilstein 3 IV 34.]
SILVER TRIFLUOROMETHANESULFONATE Preparation Products And Raw materials
Raw materials
Preparation Products
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SILVER TRIFLUOROMETHANESULFONATE Suppliers
- Tel
- 03-36680489
- Fax
- 03-3668-0520
- Sales-JP@TCIchemicals.com
- Country
- Japan
- ProdList
- 28398
- Advantage
- 80
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View Lastest Price from SILVER TRIFLUOROMETHANESULFONATE manufacturers
LY Global chemicals co.,ltd .
- Product
- SILVER TRIFLUOROMETHANESULFONATE 2923-28-6
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 99.0%
- Supply Ability
- 1000KG
- Release date
- 2023-03-09
Henan Aochuang Chemical Co.,Ltd.
- Product
- SILVER TRIFLUOROMETHANESULFONATE 2923-28-6
- Price
- US $0.00-0.00/kg
- Min. Order
- 1kg
- Purity
- 98%
- Supply Ability
- 1Ton
- Release date
- 2022-10-09
henan kanbei chemical co.,ltd
- Product
- SILVER TRIFLUOROMETHANESULFONATE 2923-28-6
- Price
- US $0.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 1000kg
- Release date
- 2022-09-22
2923-28-6, SILVER TRIFLUOROMETHANESULFONATERelated Search:
Trifluoromethanesulfonic acid
Scandium trifluoromethanesulfonate
Ethyl trifluoromethanesulfonate
TIN(II) TRIFLUOROMETHANESULFONATE
Fluoranthene-3-boronic acid
2,3-DIHYDRO-1H-INDOLE-6-CARBOXYLIC ACID
Lanthanum trifluoromethanesulfonate
Aluminum trifluoromethanesulfonate
YTTERBIUM(III) TRIFLUOROMETHANESULFONATE HYDRATE
Sodium trifluoromethanesulfonate
Trifluoromethanesulfonic anhydride
Trifluoromethanesulfonyl chloride
Trifluoromethanesulfonimide
Lithium trifluoromethanesulfonate
Zinc trifluoromethanesulfonate
Lithium bis(trifluoromethanesulphonyl)imide
N-Phenyl-bis(trifluoromethanesulfonimide)
Potassium trifluoromethanesulfonate