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Bismuth trichloride

Product Name
Bismuth trichloride
CAS No.
7787-60-2
Chemical Name
Bismuth trichloride
Synonyms
BiCl3;BISMUTH(III) CHLORIDE;BISMUTH CHLORIDE;Trichlorobismuthane;Trichlorobismuth;Bismuth(III) chL;BISMUTH(+3)CHLORIDE;BISMUTH TRICHLORIDE;Bismuth(Ⅲ) chloride;trichloro-bismuthin
CBNumber
CB3205675
Molecular Formula
BiCl3
Formula Weight
315.34
MOL File
7787-60-2.mol
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Bismuth trichloride Property

Melting point:
230-232 °C(lit.)
Boiling point:
447 °C(lit.)
Density 
4.75
Flash point:
430°C
storage temp. 
no restrictions.
solubility 
Soluble in hydrochloric acid, nitric acid, diethyl ether, ethyl acetate and acetone. Insoluble in alcohol.
form 
powder
color 
White to beige or gray
Specific Gravity
4.75
Odor
Hydrochloric acid odor
Water Solubility 
decomposes
Sensitive 
Hygroscopic
Sublimation 
430 ºC
Merck 
14,1262
Stability:
Stable, but reacts with water, moisture.
InChIKey
JHXKRIRFYBPWGE-UHFFFAOYSA-K
CAS DataBase Reference
7787-60-2(CAS DataBase Reference)
NIST Chemistry Reference
Bismuth trichloride(7787-60-2)
EPA Substance Registry System
Bismuthine, trichloro- (7787-60-2)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/38-36/37/38
Safety Statements 
26-36-37/39
RIDADR 
3260
WGK Germany 
2
RTECS 
EB2690000
TSCA 
Yes
HS Code 
2827 39 85
HazardClass 
8
PackingGroup 
III
Toxicity
LD50 orally in Rabbit: 3334 mg/kg
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
224839
Product name
Bismuth(III) chloride
Purity
reagent grade, ≥98%
Packaging
25g
Price
$118
Updated
2024/03/01
Sigma-Aldrich
Product number
224839
Product name
Bismuth(III) chloride
Purity
reagent grade, ≥98%
Packaging
100g
Price
$340
Updated
2024/03/01
Sigma-Aldrich
Product number
1.12403
Product name
Bismuth(III) chloride
Purity
98+
Packaging
100g
Price
$329
Updated
2024/03/01
TCI Chemical
Product number
B3546
Product name
Bismuth(III) Chloride Anhydrous
Purity
>97.0%(T)
Packaging
25g
Price
$50
Updated
2024/03/01
TCI Chemical
Product number
B3546
Product name
Bismuth(III) Chloride Anhydrous
Purity
>97.0%(T)
Packaging
250g
Price
$194
Updated
2024/03/01
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Bismuth trichloride Chemical Properties,Usage,Production

Chemical Properties

Bismuth trichloride is white crystal and crystalline powder

Physical properties

Yellowish-white crystalline solid; cubic crystals; hygroscopic; density 4.75g/cm3; melts at 230°C; vaporizes at 447°C; vapor pressure 5 torr at 242°C; reacts with water; soluble in acids, alcohol and acetone.

Uses

Bismuth chloride (Bi3+ + 3Cl1- → BiCl3) reacts with water to produce what is known as “bismuth white” pigment.

Uses

In the manufacture of other bismuth salts; as catalyst for organic reactions.

Uses

Bismuth trichloride used as catalyst for organic reactions.

Definition

Bismuth trichloride is a white deliquescent solid. It can be prepared by direct combination of bismuth and chlorine. Bismuth(III) chloride dissolves in excess dilute hydrochloric acid to form a clear liquid, but if diluted it produces a white precipitate of bismuth(III) chloride oxide (bismuthyl chloride, BiOCl): BiCl3 + H2O = BiOCl + 2HCl This reaction is often used as an exam ple of a reversible reaction and as a confirmatory test for bismuth during quantitative analysis. Bismuth(V) chloride does not form.

Preparation

Bismuth chloride may be synthesized directly by passing chlorine over bismuth. Alternatively, the chloride salt may be prepared by adding hydrochloric acid to basic bismuth chloride and evaporating the solution:
Bi(OH)2Cl + 2HCl → BiCl3 + 2H2O
Also, the compound can be prepared by dissolving bismuth in concentrated nitric acid and then adding solid sodium chloride into this solution. Another method of preparation is treating the metal with concentrated hydrochloric acid:
2Bi + 6HCl → 2BiCl3 + 3H2.

General Description

Bismuth(III) chloride is an inorganic salt that can be prepared by the reaction of bismuth with chlorine.

Purification Methods

Sublime the trichloride under high vacuum, or dry it under a current of HCl gas, followed by fractional distillation, once under HCl and once under argon. It is deliquescent. [Schenk in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol I p 621 1963.]

Bismuth trichloride Preparation Products And Raw materials

Raw materials

Preparation Products

4-METHYL-2-OXO-2 H-CHROMENE-7-CARBALDEHYDE CHLOROETHANE 7-BROMOMETHYL-4-METHYL-CHROMEN-2-ONE 4,7-DIMETHYLCOUMARIN
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View Lastest Price from Bismuth trichloride manufacturers

Hebei Yanxi Chemical Co., Ltd.
Product
Bismuth chloride 7787-60-2
Price
US $1.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20tons
Release date
2023-09-06
Hebei Weibang Biotechnology Co., Ltd
Product
Bismuth trichloride 7787-60-2
Price
US $30.00-10.00/KG
Min. Order
50KG
Purity
99%
Supply Ability
500000kg
Release date
2024-10-24
Hebei Kingfiner Technology Development Co.Ltd
Product
Bismuth trichloride 7787-60-2
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
0.99
Supply Ability
50000kg
Release date
2024-07-02

7787-60-2, Bismuth trichloride Related Search:

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  • BisuMuth trichloride
  • BisuMuth(Ⅲ) chloride
  • Bismuth(III) chloride anhydrous, powder, 99.999% trace metals basis
  • Bismuth(III) chloride reagent grade, >=98%
  • Bismuth(III) chloride Vetec(TM) reagent grade
  • BisMuth(III) chloride, 99.999% (Metals basis)
  • Bismuth(III) chloride, 98% dry weight, may contain up to 3% water
  • Bismuth(III) chloride, anhydrous, 99.9% trace metals basis
  • Bismuth(III) chloride, anhydrous, 99.999% trace metals basis
  • BISMUTH CHLORIDE
  • BISMUTH(III) CHLORIDE
  • BISMUTH(+3)CHLORIDE
  • BISMUTH TRICHLORIDE
  • Bismuth(III) chloride≥ 99.95% (Metal basis)
  • BiCl3
  • Bismuthine, trichloro-
  • Trichlorobismuth
  • Trichlorobismuthane
  • Bismuth(iii) chloride, 98+%, anhydrous
  • Trichlorobismuth(III)
  • BisMuth(III) chloride, anhydrous, 98+% 25GR
  • Bismuth trichloride , 99.999%
  • Bismuth(III) Chloride Anhydrous [for General Organic Chemistry]
  • Bismuth(III) chloride, 98% (dry wt.), may cont. up to 3% water
  • Bismuth(III) chloride, anhydrous (metals basis)
  • Bismuth(III) chloride, (trace metal basis), 99.999%
  • Bismuth(Ⅲ) chloride
  • BisMuth(III) chloride, 99.999%, (trace Metal basis)
  • BISMUTH(III) CHLORIDE 98+ 100 G
  • BISMUTH CHLORIDE, REAGENT (ACS)BISMUTH CHLORIDE, REAGENT (ACS)BISMUTH CHLORIDE, REAGENT (ACS)
  • Bismuth(III) chL
  • trichloro-bismuthin
  • Trichlorobismuthine
  • trichloro-Bismuthine
  • BISMUTH(III) CHLORIDE, ANHYDROUS, POWDER , 99.999%
  • BISMUTH(III) CHLORIDE, 98+%
  • BISMUTH(III) CHLORIDE, 99.99%
  • BISMUTH(III) CHLORIDE REAGENT GRADE >&
  • BISMUTH(III) CHLORIDE, ANHYDROUS, BEADS, -10 MESH, 99.999%
  • Bismuth(III) chloride anhydrous, 99.999%
  • Bismuth(III)chloride,anhydrous,99+%(metalsbasis)
  • Bismuth(III)chloride,anhydrous,99.999%(metalsbasis)
  • Bismuth(III) chloride, 99.999%
  • Bismuth(III) chloride, anhydrous, 98+%
  • BISMUTH CHLORIDE REAGENT (ACS)
  • Bismuth(III)chloride,anhydrous(99.999%-Bi)PURATREM
  • Bismuth(III)chloride,anhydrous,99+%(99.9+%-Bi)
  • bismuth(iii) chloride, anhydrous
  • bismuth(iii) chloride, ultra dry
  • BISMUTHCHLORIDE,REAGENT
  • BISMUTH(III) CHLORIDE, ANHYDROUS (99.9%-BI)
  • BISMUTH CHLORIDE: 99.999%, AMPOULED UNDER ARGON
  • BISMUTH(LLL) CHLORIDE
  • Bismuth(III) chloride, anhydrous, 99.9% (metals basis)
  • Bismuth(III) chloride, ultra dry, 99.997+% (metals basis)
  • Bismuth(III) Chloride Anhydrous[for General Organic Chemistry]&gt
  • Bismuth(III) chloride, 98%, for synthesis
  • Bismuth(III) chloride, for analysis