Bismuth trichloride

Product Name: Bismuth trichloride
CAS No.: 7787-60-2
Chemical Name: Bismuth trichloride
Synonyms: BiCl3;BISMUTH(III) CHLORIDE;BISMUTH CHLORIDE;Trichlorobismuthane;Trichlorobismuth;Bismuth(III) chL;BISMUTH(+3)CHLORIDE;BISMUTH TRICHLORIDE;Bismuth(Ⅲ) chloride;trichloro-bismuthin
CBNumber: CB3205675
Molecular Formula: BiCl3
Formula Weight: 315.34
MOL File: 7787-60-2.mol

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Bismuth trichloride Property

Melting point:: 230-232 °C(lit.)
Boiling point:: 447 °C(lit.)
Density: 4.75
Flash point:: 430°C
storage temp.: no restrictions.
solubility: Soluble in hydrochloric acid, nitric acid, diethyl ether, ethyl acetate and acetone. Insoluble in alcohol.
form: powder
color: White to beige or gray
Specific Gravity: 4.75
Odor: Hydrochloric acid odor
Water Solubility: decomposes
Sensitive: Hygroscopic
Sublimation: 430 ºC
Merck: 14,1262
Stability:: Stable, but reacts with water, moisture.
InChIKey: JHXKRIRFYBPWGE-UHFFFAOYSA-K
CAS DataBase Reference: 7787-60-2(CAS DataBase Reference)
NIST Chemistry Reference: Bismuth trichloride(7787-60-2)
EPA Substance Registry System: Bismuthine, trichloro- (7787-60-2)

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Safety

Hazard Codes: Xi
Risk Statements: 36/38-36/37/38
Safety Statements: 26-36-37/39
RIDADR: 3260
WGK Germany: 2
RTECS: EB2690000
TSCA: Yes
HS Code: 2827 39 85
HazardClass: 8
PackingGroup: III
Toxicity: LD50 orally in Rabbit: 3334 mg/kg

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P337+P313IF eye irritation persists: Get medical advice/attention.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 224839
Product name: Bismuth(III) chloride
Purity: reagent grade, ≥98%
Packaging: 25g
Price: $118
Updated: 2024/03/01

Sigma-Aldrich

Product number: 224839
Product name: Bismuth(III) chloride
Purity: reagent grade, ≥98%
Packaging: 100g
Price: $340
Updated: 2024/03/01

Sigma-Aldrich

Product number: 1.12403
Product name: Bismuth(III) chloride
Purity: 98+
Packaging: 100g
Price: $329
Updated: 2024/03/01

TCI Chemical

Product number: B3546
Product name: Bismuth(III) Chloride Anhydrous
Purity: >97.0%(T)
Packaging: 25g
Price: $50
Updated: 2024/03/01

TCI Chemical

Product number: B3546
Product name: Bismuth(III) Chloride Anhydrous
Purity: >97.0%(T)
Packaging: 250g
Price: $194
Updated: 2024/03/01

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Bismuth trichloride Chemical Properties,Usage,Production

Chemical Properties

Bismuth trichloride is white crystal and crystalline powder

Physical properties

Yellowish-white crystalline solid; cubic crystals; hygroscopic; density 4.75g/cm³; melts at 230°C; vaporizes at 447°C; vapor pressure 5 torr at 242°C; reacts with water; soluble in acids, alcohol and acetone.

Uses

Bismuth chloride (Bi³⁺ + 3Cl^1- → BiCl3) reacts with water to produce what is known as “bismuth white” pigment.

Uses

In the manufacture of other bismuth salts; as catalyst for organic reactions.

Uses

Bismuth trichloride used as catalyst for organic reactions.

Definition

Bismuth trichloride is a white deliquescent solid. It can be prepared by direct combination of bismuth and chlorine. Bismuth(III) chloride dissolves in excess dilute hydrochloric acid to form a clear liquid, but if diluted it produces a white precipitate of bismuth(III) chloride oxide (bismuthyl chloride, BiOCl): BiCl₃+ H₂O = BiOCl + 2HCl This reaction is often used as an exam ple of a reversible reaction and as a confirmatory test for bismuth during quantitative analysis. Bismuth(V) chloride does not form.

Preparation

Bismuth chloride may be synthesized directly by passing chlorine over bismuth. Alternatively, the chloride salt may be prepared by adding hydrochloric acid to basic bismuth chloride and evaporating the solution:
Bi(OH)₂Cl + 2HCl → BiCl₃ + 2H₂O
Also, the compound can be prepared by dissolving bismuth in concentrated nitric acid and then adding solid sodium chloride into this solution. Another method of preparation is treating the metal with concentrated hydrochloric acid:
2Bi + 6HCl → 2BiCl₃ + 3H₂.

General Description

Bismuth(III) chloride is an inorganic salt that can be prepared by the reaction of bismuth with chlorine.

Purification Methods

Sublime the trichloride under high vacuum, or dry it under a current of HCl gas, followed by fractional distillation, once under HCl and once under argon. It is deliquescent. [Schenk in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol I p 621 1963.]

Bismuth trichloride Preparation Products And Raw materials

Raw materials

Preparation Products

4-METHYL-2-OXO-2 H-CHROMENE-7-CARBALDEHYDE CHLOROETHANE 7-BROMOMETHYL-4-METHYL-CHROMEN-2-ONE 4,7-DIMETHYLCOUMARIN

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Bismuth trichloride Suppliers

Americas 1 Belgium 3 China 277 Europe 3 France 2 Germany 9 India 42 Japan 8 Russia 1 Slovakia 1 Switzerland 2 United Kingdom 18 United States 58 Global 425

INTATRADE GmbH

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Fox-Chemicals Gmbh

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Intatrade Chemicals Gmbh

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ABCR GmbH & CO. KG

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Service Chemical Inc.

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Merck Schuchardt OHG

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View Lastest Price from Bismuth trichloride manufacturers

Hebei Yanxi Chemical Co., Ltd.

Product: Bismuth chloride 7787-60-2
Price: US $1.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 20tons
Release date: 2023-09-06

Hebei Weibang Biotechnology Co., Ltd

Product: Bismuth trichloride 7787-60-2
Price: US $30.00-10.00/KG
Min. Order: 50KG
Purity: 99%
Supply Ability: 500000kg
Release date: 2024-10-24

Hebei Kingfiner Technology Development Co.Ltd

Product: Bismuth trichloride 7787-60-2
Price: US $0.00-0.00/kg
Min. Order: 1kg
Purity: 0.99
Supply Ability: 50000kg
Release date: 2024-07-02

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BisuMuth trichloride

BisuMuth(Ⅲ) chloride

Bismuth(III) chloride anhydrous, powder, 99.999% trace metals basis

Bismuth(III) chloride reagent grade, >=98%

Bismuth(III) chloride Vetec(TM) reagent grade

BisMuth(III) chloride, 99.999% (Metals basis)

Bismuth(III) chloride, 98% dry weight, may contain up to 3% water

Bismuth(III) chloride, anhydrous, 99.9% trace metals basis

Bismuth(III) chloride, anhydrous, 99.999% trace metals basis

BISMUTH CHLORIDE

BISMUTH(III) CHLORIDE

BISMUTH(+3)CHLORIDE

BISMUTH TRICHLORIDE

Bismuth(III) chloride≥ 99.95% (Metal basis)

BiCl3

Bismuthine, trichloro-

Trichlorobismuth

Trichlorobismuthane

Bismuth(iii) chloride, 98+%, anhydrous

Trichlorobismuth(III)

BisMuth(III) chloride, anhydrous, 98+% 25GR

Bismuth trichloride , 99.999%

Bismuth(III) Chloride Anhydrous [for General Organic Chemistry]

Bismuth(III) chloride, 98% (dry wt.), may cont. up to 3% water

Bismuth(III) chloride, anhydrous (metals basis)

Bismuth(III) chloride, (trace metal basis), 99.999%

Bismuth(Ⅲ) chloride

BisMuth(III) chloride, 99.999%, (trace Metal basis)

BISMUTH(III) CHLORIDE 98+ 100 G

BISMUTH CHLORIDE, REAGENT (ACS)BISMUTH CHLORIDE, REAGENT (ACS)BISMUTH CHLORIDE, REAGENT (ACS)

Bismuth(III) chL

trichloro-bismuthin

Trichlorobismuthine

trichloro-Bismuthine

BISMUTH(III) CHLORIDE, ANHYDROUS, POWDER , 99.999%

BISMUTH(III) CHLORIDE, 98+%

BISMUTH(III) CHLORIDE, 99.99%

BISMUTH(III) CHLORIDE REAGENT GRADE >&

BISMUTH(III) CHLORIDE, ANHYDROUS, BEADS, -10 MESH, 99.999%

Bismuth(III) chloride anhydrous, 99.999%

Bismuth(III)chloride,anhydrous,99+%(metalsbasis)

Bismuth(III)chloride,anhydrous,99.999%(metalsbasis)

Bismuth(III) chloride, 99.999%

Bismuth(III) chloride, anhydrous, 98+%

BISMUTH CHLORIDE REAGENT (ACS)

Bismuth(III)chloride,anhydrous(99.999%-Bi)PURATREM

Bismuth(III)chloride,anhydrous,99+%(99.9+%-Bi)

bismuth(iii) chloride, anhydrous

bismuth(iii) chloride, ultra dry

BISMUTHCHLORIDE,REAGENT

BISMUTH(III) CHLORIDE, ANHYDROUS (99.9%-BI)

BISMUTH CHLORIDE: 99.999%, AMPOULED UNDER ARGON

BISMUTH(LLL) CHLORIDE

Bismuth(III) chloride, anhydrous, 99.9% (metals basis)

Bismuth(III) chloride, ultra dry, 99.997+% (metals basis)

Bismuth(III) Chloride Anhydrous[for General Organic Chemistry]&gt

Bismuth(III) chloride, 98%, for synthesis

Bismuth(III) chloride, for analysis