METIRAM

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Product Name: METIRAM
CAS No.: 9006-42-2
Chemical Name: METIRAM
Synonyms: amarex;POLYRAM;FMC9102;METIRAM;THIUMET;Metriam;nia9102;polymat;Methiram;MetriraM
CBNumber: CB3220555
Molecular Formula: C12H12N6S16Zn
Formula Weight: 818.69388
MOL File: 9006-42-2.mol

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METIRAM Property

Melting point:: 156℃ (approx, Decomposition)
storage temp.: 0-6°C
solubility: DMSO (Slightly, Heated)
form: Solid
color: Off-White
EPA Substance Registry System: Metiram (9006-42-2)

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Safety

RIDADR: UN 1282 3 / PGII
RTECS: TR6250000
Hazardous Substances Data: 9006-42-2(Hazardous Substances Data)

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H317May cause an allergic skin reaction

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P272Contaminated work clothing should not be allowed out of the workplace.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P321Specific treatment (see … on this label).

P333+P313IF SKIN irritation or rash occurs: Get medical advice/attention.

P363Wash contaminated clothing before reuse.

P391Collect spillage. Hazardous to the aquatic environment

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TRC

Product number: M338630
Product name: Metriram(>90%)
Packaging: 10g
Price: $1070
Updated: 2021/12/16

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METIRAM Chemical Properties,Usage,Production

Chemical Properties

Light yellow solid or powder at room temperature. Characteristic dithiocarbamate odor.

Uses

Metriram is a polymeric dithiocarbamic fungicide used in agriculture. Metiram is present as a mixture rather than a complex and is not assigned an ISO name. Metiram is used commonly in the protection of grapevines, apples, tomatoes, potatoes as well as other crops.

Definition

ChEBI: Zineb is a polymeric complex of zinc with the ethylene bis(dithiocarbamate) anionic ligand. Formerly used as an agricultural fungicide for the control of downy mildews and rusts, its use is no longer permitted in the US or the EU. It has a role as an antifungal agrochemical. It is a macromolecule, a zinc coordination entity and a dithiocarbamate salt. It contains an ethylenebis(dithiocarbamate).

General Description

Yellow powder. Non corrosive. Insoluble in water. Used as an fungicide.

Air & Water Reactions

Thio and dithiocarbamates slowly decompose in aqueous solution to form carbon disulfide and methylamine or other amines. Such decompositions are accelerated by acids and bases. Insoluble in water.

Reactivity Profile

METIRAM is a dithiocarbamate. Flammable gases are generated by the combination of thiocarbamates and dithiocarbamates with aldehydes, nitrides, and hydrides. Thiocarbamates and dithiocarbamates are incompatible with acids, peroxides, and acid halides.

Hazard

Toxic by ingestion and inhalation.

Agricultural Uses

Fungicide: Metiram is used to protect fruits, vegetables, field crops and other crops and ornamentals against many types of fungi and other foliar diseases.

Trade name

ATLAS® BRAND[C]; AMAREX®; NIA 9102®[C]; NIAGARA[C]; POLYCARBACIN®; POLYCARBACINE®; POLYCARBAZIN®; POLYCARBAZINE®; POLYMARCIN®; POLYMARCINE®; POLYMARSIN®; POLYMARZIN®; POLYMARZINE®; POLYRAM®

Potential Exposure

Metiram is a dithiocarbamate fungicide used on fruits, vegetables, field crops and other crops and on ornamentals to protect against many types of fungi and other foliar diseases.

Shipping

UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required.

Incompatibilities

Combustible material. Dust may form explosive mixture in air. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Dithiocarbamate esters are combustible. They react violently with powerful oxidizers such as calcium hypochlorite. Poisonous gases are generated by the thermal decomposition of dithiocarbamate compounds, including carbon disulfide, oxides of sulfur, oxides of nitrogen, hydrogen sulfide, ammonia, and methylamine. Thio and dithiocarbamates slowly decompose in aqueous solution to form carbon disulfide and methylamine or other amines. Such decompositions are accelerated by acids. Flammable gases are generated by the combination of dithiocarbamate with aldehydes, nitrides, and hydrides. Dithiocarbamate are incompatible with acids, peroxides, and acid halides. Thermal decomposition products in fire includes oxides of nitrogen and sulfur. Corrosive to iron, copper brass and zinc metals, especially in the presence of moisture. Heat alkalies (lime), moisture can cause decomposition. Decomposes on prolonged storage. Degradation produces ethylene thiourea.

Waste Disposal

Do not discharge into drains or sewers. Dispose of waste material as hazardous waste using a licensed disposal contractor to an approved landfill. Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform to EPA regulations governing storage, transportation, treatment, and waste disposal. A potential candidate for liquid injection incineration at a temperature range of 650 to 1600℃ and a residence time 0.1 to 2 seconds. Also, a potential candidate for rotary kiln incineration at a temperature range of 820 to 1600℃ and residence times of seconds for liquids and gases, and hours for solids.

METIRAM Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from METIRAM manufacturers

Career Henan Chemical Co

Product: METIRAM 9006-42-2
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99.0%
Supply Ability: 100kg
Release date: 2020-03-11

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METIRAM

FMC9102

POLYRAM

POLYRAM(C)

POLYRAM (TM)

NIA 9102(R)

TRIS[AMMINE[ETHYLENEBIS(DITHIOCARBAMATO) ZINC(2+)]TETRAHYDRO-1,2,4,7-DITHIADIAZOCINE-3,8-DITHIONE, POLYMER

ZINC METIRAM

polycarbazin

polycarbazine

polymarcin

polymarcine

polymarsin

polymarzin

polymarzine

POLYRAM, 1GM, NEAT

Dithiobis(thiocarbonyl) iminoethylene bis(dithiocarbamic acid), zinc salt

THIUMET

Methiram

Polyram (technical grade)

Metiram Standrad

Polyram (TM) 1g [9006-42-2]

POLYRAM, TECHNICAL GRADE, 1000MG NEAT

MetiraM-zinc

MetriraM

Phytox-Super

Polykarbacin

PolyraM 2000

Metriam

Metiram(Technical)

METIRAM TECHNICAL MIXTURE, PESTANAL,250

amarex

carbatene

metiram-complex

metiramezinc

nia9102

polikarbatsin

polycarbacin

polycarbacine

polymat

polyram80

polyram80wp

polyramcombi

polyramdf

zincammoniateethylenebis(dithiocarbamate)-poly(ethylenethiuramdisulfide)

Metriram (&gt

MetiramSolution,100mg/L,1ml

Metiram Standard

Metiram, tech.

Metriam solution, 100μg/mL

Metriram (>90%)

9006-42-2

C16H33N11S16Zn3n

C16H33MN3N11S16X

C8H16N5S8Zn

C12H12N6S16Zn

C16H33N11S16Zn3

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