METIRAM

ChemicalBook > CAS DataBase List > METIRAM

Product Name: METIRAM
CAS No.: 9006-42-2
Chemical Name: METIRAM
Synonyms: amarex;POLYRAM;FMC9102;METIRAM;THIUMET;Metriam;nia9102;polymat;Methiram;MetriraM
CBNumber: CB3220555
Molecular Formula: C12H12N6S16Zn
Formula Weight: 818.69388
MOL File: 9006-42-2.mol

Less

METIRAM Property

Melting point:: 156℃ (approx, Decomposition)
storage temp.: 0-6°C
solubility: DMSO (Slightly, Heated)
form: Solid
color: Off-White
EPA Substance Registry System: Metiram (9006-42-2)

Less

Safety

RIDADR: UN 1282 3 / PGII
RTECS: TR6250000
Hazardous Substances Data: 9006-42-2(Hazardous Substances Data)

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H317May cause an allergic skin reaction

H410Very toxic to aquatic life with long lasting effects

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P272Contaminated work clothing should not be allowed out of the workplace.

P273Avoid release to the environment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P321Specific treatment (see … on this label).

P333+P313IF SKIN irritation or rash occurs: Get medical advice/attention.

P363Wash contaminated clothing before reuse.

P391Collect spillage. Hazardous to the aquatic environment

P501Dispose of contents/container to..…

Less

N-Bromosuccinimide Price

TRC

Product number: M338630
Product name: Metriram(>90%)
Packaging: 10g
Price: $1070
Updated: 2021/12/16

Less

METIRAM Chemical Properties,Usage,Production

Chemical Properties

Light yellow solid or powder at room temperature. Characteristic dithiocarbamate odor.

Uses

Metriram is a polymeric dithiocarbamic fungicide used in agriculture. Metiram is present as a mixture rather than a complex and is not assigned an ISO name. Metiram is used commonly in the protection of grapevines, apples, tomatoes, potatoes as well as other crops.

Definition

ChEBI: Zineb is a polymeric complex of zinc with the ethylene bis(dithiocarbamate) anionic ligand. Formerly used as an agricultural fungicide for the control of downy mildews and rusts, its use is no longer permitted in the US or the EU. It has a role as an antifungal agrochemical. It is a macromolecule, a zinc coordination entity and a dithiocarbamate salt. It contains an ethylenebis(dithiocarbamate).

General Description

Yellow powder. Non corrosive. Insoluble in water. Used as an fungicide.

Air & Water Reactions

Thio and dithiocarbamates slowly decompose in aqueous solution to form carbon disulfide and methylamine or other amines. Such decompositions are accelerated by acids and bases. Insoluble in water.

Reactivity Profile

METIRAM is a dithiocarbamate. Flammable gases are generated by the combination of thiocarbamates and dithiocarbamates with aldehydes, nitrides, and hydrides. Thiocarbamates and dithiocarbamates are incompatible with acids, peroxides, and acid halides.

Hazard

Toxic by ingestion and inhalation.

Agricultural Uses

Fungicide: Metiram is used to protect fruits, vegetables, field crops and other crops and ornamentals against many types of fungi and other foliar diseases.

Trade name

ATLAS® BRAND[C]; AMAREX®; NIA 9102®[C]; NIAGARA[C]; POLYCARBACIN®; POLYCARBACINE®; POLYCARBAZIN®; POLYCARBAZINE®; POLYMARCIN®; POLYMARCINE®; POLYMARSIN®; POLYMARZIN®; POLYMARZINE®; POLYRAM®

Potential Exposure

Metiram is a dithiocarbamate fungicide used on fruits, vegetables, field crops and other crops and on ornamentals to protect against many types of fungi and other foliar diseases.

Shipping

UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required.

Incompatibilities

Combustible material. Dust may form explosive mixture in air. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Dithiocarbamate esters are combustible. They react violently with powerful oxidizers such as calcium hypochlorite. Poisonous gases are generated by the thermal decomposition of dithiocarbamate compounds, including carbon disulfide, oxides of sulfur, oxides of nitrogen, hydrogen sulfide, ammonia, and methylamine. Thio and dithiocarbamates slowly decompose in aqueous solution to form carbon disulfide and methylamine or other amines. Such decompositions are accelerated by acids. Flammable gases are generated by the combination of dithiocarbamate with aldehydes, nitrides, and hydrides. Dithiocarbamate are incompatible with acids, peroxides, and acid halides. Thermal decomposition products in fire includes oxides of nitrogen and sulfur. Corrosive to iron, copper brass and zinc metals, especially in the presence of moisture. Heat alkalies (lime), moisture can cause decomposition. Decomposes on prolonged storage. Degradation produces ethylene thiourea.

Waste Disposal

Do not discharge into drains or sewers. Dispose of waste material as hazardous waste using a licensed disposal contractor to an approved landfill. Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform to EPA regulations governing storage, transportation, treatment, and waste disposal. A potential candidate for liquid injection incineration at a temperature range of 650 to 1600℃ and a residence time 0.1 to 2 seconds. Also, a potential candidate for rotary kiln incineration at a temperature range of 820 to 1600℃ and residence times of seconds for liquids and gases, and hours for solids.

METIRAM Preparation Products And Raw materials

Raw materials

Preparation Products

Less

METIRAM Suppliers

Canada 2 China 49 France 1 Germany 2 India 3 Japan 2 South Korea 1 Switzerland 1 United States 9 Global 70

J & K SCIENTIFIC LTD.

Tel: 010-82848833 400-666-7788
Fax: 86-10-82849933
Email: jkinfo@jkchemical.com
Country: China
ProdList: 96815
Advantage: 76

Chemsky (shanghai) International Co.,Ltd

Tel: 021-50135380
Email: shchemsky@sina.com
Country: China
ProdList: 15421
Advantage: 60

Shanghai Aladdin Bio-Chem Technology Co.,LTD

Tel: 18521735133 18521732826;
Fax: 021-50323701
Email: market@aladdin-e.com
Country: China
ProdList: 25015
Advantage: 65

Alta Scientific Co., Ltd.

Tel: 022-6537-8550 15522853686
Fax: 022-2532-9655
Email: sales@altasci.com.cn
Country: China
ProdList: 4515
Advantage: 55

Shanghai YuanYe Biotechnology Co., Ltd.

Tel: 021-61312847; 18021002903
Fax: QQ:3008007432
Email: 3008007409@qq.com
Country: China
ProdList: 27322
Advantage: 60

Shandong Xiya Chemical Co., Ltd.

Tel: 4009903999 13395398332
Fax: 0539-6365991
Email: sales@xiyashiji.com
Country: China
ProdList: 20810
Advantage: 60

Chengdu Dianchun Technology Co., Ltd

Tel: 400-1166-196 18502815961
Fax: QQ：800101999
Email: cdhxsj@163.com
Country: China
ProdList: 14623
Advantage: 60

Shenzhen Regent Biochemical Technology Co., Ltd.

Tel: 0755-0755-85201366 18938635012
Fax: 0755-85201366
Email: sales@regentsciences.com
Country: China
ProdList: 9293
Advantage: 58

Wuhan FengyaoTonghui Chemical Products Co., Ltd.

Tel: 027-87466105 15377573527
Email: 2678564200@qq.com
Country: China
ProdList: 17997
Advantage: 58

Shanghai Jizhi Biochemical Technology Co. Ltd.

Tel: 400-400-400-9004166 18616739031
Email: 3007523370@qq.com
Country: China
ProdList: 52712
Advantage: 58

Shenzhen Polymeri Biochemical Technology Co., Ltd.

Tel: +86-400-002-6226 13028896684
Email: sales@rrkchem.com
Country: China
ProdList: 55827
Advantage: 58

SIMAGCHEM CORP

Tel: +86-13806087780
Email: sale@simagchem.com
Country: China
ProdList: 17367
Advantage: 58

Hubei xin bonus chemical co. LTD

Tel: 86-13657291602
Fax: 027-59338440
Email: linda@hubeijusheng.com
Country: CHINA
ProdList: 22968
Advantage: 58

Shandong chuangyingchemical Co., Ltd.

Tel: 18853181302
Email: sale@chuangyingchem.com
Country: CHINA
ProdList: 5909
Advantage: 58

Chongqing Chemdad Co., Ltd

Tel: +86-023-61398051 +8613650506873
Email: sales@chemdad.com
Country: China
ProdList: 39916
Advantage: 58

career henan chemical co

Tel: +86-0371-86658258 15093356674;
Fax: 0086-371-86658258
Email: factory@coreychem.com
Country: China
ProdList: 29826
Advantage: 58

ShangHai Anpel Co, Ltd.

Tel: 18501792038; 18501792038
Email: shanpel@anpel.com.cn
Country: China
ProdList: 9614
Advantage: 58

Shaanxi Dideu Medichem Co. Ltd

Tel: 029-61856359 18690052321
Fax: 029-88380327
Email: 1027@dideu.com
Country: China
ProdList: 10010
Advantage: 58

Manhag Testing Technology Co., Ltd

Tel: 020-020-3846236 17688849268
Email: 2443244976@qq.com
Country: China
ProdList: 7775
Advantage: 58

TCI (Shanghai) Chemical Trading Co., Ltd.

Tel: 021-61109150
Fax: 021-61105897
Email: sales@tcisct.com
Country: China
ProdList: 31163
Advantage: 58

Hebei Dueling International Trade Co. LTD

Tel: 18032116176
Email: 399549586@qq.com
Country: China
ProdList: 1181
Advantage: 58

LGC Science (Shanghai) Ltd.

Tel: 17717235263
Email: cindy.yang@lgcgroup.com
Country: China
ProdList: 11437
Advantage: 58

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 18621169109
Email: market03@meryer.com
Country: China
ProdList: 27996
Advantage: 58

Wuhan Fengyao Tonghui Chemical Products Co. LTD

Tel: 027-87466205 15377579727
Email: 1228964013@qq.com
Country: China
ProdList: 8561
Advantage: 58

Jiangsu Aikon Biopharmaceutical R&D co.,Ltd.

Tel: 025-66113011 18112977050
Email: cb5@aikonchem.com
Country: China
ProdList: 10529
Advantage: 58

Nantong Zhonghe Chemical New Materials Co., Ltd

Tel: 13003551299 13003551299
Email: 2369399482@qq.com
Country: China
ProdList: 7568
Advantage: 58

Shanghai Acmec Biochemical Technology Co., Ltd.

Tel: +undefined18621343501
Email: product@acmec-e.com
Country: China
ProdList: 33349
Advantage: 58

LEAPCHEM CO., LTD.

Tel: +86-852-30606658
Email: market18@leapchem.com
Country: China
ProdList: 43348
Advantage: 58

Hebei Duling International Trade Co. LTD

Tel: +8618032673083
Fax: 0311-87836622
Email: sales05@hbduling.cn
Country: China
ProdList: 15744
Advantage: 58

Shanghai Hao Zhun Biological Technology Co., Ltd.

Tel: --
Fax: --
Email: info@zzsrm.com
Country: CHINA
ProdList: 6846
Advantage: 58

Dongguan Biaobiao Experimental Equipment Technology Co., Ltd.

Tel: --
Fax: --
Country: CHINA
ProdList: 6673
Advantage: 58

Shanghai Hao Biological Technology Co., Ltd.

Tel: --
Fax: --
Email: shxiyuanbio@163.com
Country: CHINA
ProdList: 6921
Advantage: 58

Shanghai Zhenyu Biological Technology Co., Ltd.

Tel: --
Fax: --
Email: 2836767067@qq.com
Country: CHINA
ProdList: 6970
Advantage: 58

Shanghai Lianshuobao is Biotechnology Co., Ltd.

Tel: --
Fax: --
Email: lianshuobio@163.com
Country: CHINA
ProdList: 6985
Advantage: 58

Shanghai Sanhao Biological Technology Co., Ltd.

Tel: --
Fax: --
Country: CHINA
ProdList: 6411
Advantage: 58

Shanghai Yubo Biotechnology Co., Ltd.

Tel: --
Fax: --
Email: 344843571@qq.com
Country: CHINA
ProdList: 6322
Advantage: 58

Xiamen Research Biotechnology Co., Ltd.

Tel: --
Fax: --
Email: 1562893815@qq.com
Country: CHINA
ProdList: 6942
Advantage: 58

Beijing Bai Ao Si Biotechnology Co., Ltd.

Tel: --
Fax: --
Email: yangmei@bioneeds.net
Country: CHINA
ProdList: 6999
Advantage: 58

Shanghai Yuda Industrial Co., Ltd.

Tel: --
Fax: --
Email: lucy@runwelltac.com
Country: CHINA
ProdList: 6107
Advantage: 58

Beijing Fubo Biotechnology Co., Ltd.

Tel: --
Fax: --
Email: info@f-biology.com
Country: CHINA
ProdList: 6039
Advantage: 58

Shanghai Jingke Chemical Technology Co., Ltd.

Tel: --
Fax: --
Email: jingkehuaxue@163.com
Country: CHINA
ProdList: 6974
Advantage: 58

Shanghai Ziqi Biological Technology Co., Ltd.

Tel: --
Fax: --
Email: 2453006496@qq.com
Country: CHINA
ProdList: 6192
Advantage: 58

Xiamen Huijia Biological Technology Co., Ltd.

Tel: --
Fax: --
Country: CHINA
ProdList: 6979
Advantage: 58

Shanghai Caiyou Industrial Co., Ltd.

Tel: --
Fax: --
Email: 15821073967@163.com
Country: CHINA
ProdList: 6894
Advantage: 58

Beijing Hassanal Technology Limited Liability Company

Tel: --
Fax: --
Email: service@huadr.com
Country: China
ProdList: 750
Advantage: 43

Less

View Lastest Price from METIRAM manufacturers

Career Henan Chemical Co

Product: METIRAM 9006-42-2
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99.0%
Supply Ability: 100kg
Release date: 2020-03-11

9006-42-2, METIRAMRelated Search:

Ferric acetylacetonate Ethyl isocyanoacetate Aluminum acetylacetonate COBALT(II) ACETYLACETONATE TERT-BUTYL ISOCYANIDE 1,1,3,3-TETRAMETHYLBUTYL ISOCYANIDE TRIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)DYSPROSIUM(III) TRIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATO)EUROPIUM(III) SALCOMINE DICHLORO(ETHYLENEDIAMINE)PLATINUM(II) 2,4-PENTANEDIONE, SILVER DERIVATIVE N-BUTYLISOCYANIDE Tris(2,4-pentanedionato)chroMiuM(III) METHYL ISOCYANOACETATE PHENYLSELENOL Tosylmethyl isocyanide Benzyl isocyanide Cupric acetylacetonate

METIRAM

FMC9102

POLYRAM

POLYRAM(C)

POLYRAM (TM)

NIA 9102(R)

TRIS[AMMINE[ETHYLENEBIS(DITHIOCARBAMATO) ZINC(2+)]TETRAHYDRO-1,2,4,7-DITHIADIAZOCINE-3,8-DITHIONE, POLYMER

ZINC METIRAM

polycarbazin

polycarbazine

polymarcin

polymarcine

polymarsin

polymarzin

polymarzine

POLYRAM, 1GM, NEAT

Dithiobis(thiocarbonyl) iminoethylene bis(dithiocarbamic acid), zinc salt

THIUMET

Methiram

Polyram (technical grade)

Metiram Standrad

Polyram (TM) 1g [9006-42-2]

POLYRAM, TECHNICAL GRADE, 1000MG NEAT

MetiraM-zinc

MetriraM

Phytox-Super

Polykarbacin

PolyraM 2000

Metriam

Metiram(Technical)

METIRAM TECHNICAL MIXTURE, PESTANAL,250

amarex

carbatene

metiram-complex

metiramezinc

nia9102

polikarbatsin

polycarbacin

polycarbacine

polymat

polyram80

polyram80wp

polyramcombi

polyramdf

zincammoniateethylenebis(dithiocarbamate)-poly(ethylenethiuramdisulfide)

Metriram (&gt

MetiramSolution,100mg/L,1ml

Metiram Standard

Metiram, tech.

Metriam solution, 100μg/mL

Metriram (>90%)

9006-42-2

C16H33N11S16Zn3n

C16H33MN3N11S16X

C8H16N5S8Zn

C12H12N6S16Zn

C16H33N11S16Zn3

Agro-Products