ChemicalBook > CAS DataBase List > 2'-Hydroxy-4'-methylacetophenone

2'-Hydroxy-4'-methylacetophenone

Product Name
2'-Hydroxy-4'-methylacetophenone
CAS No.
6921-64-8
Chemical Name
2'-Hydroxy-4'-methylacetophenone
Synonyms
ASISCHEM D38758;2'-Hydroxyacetopenone;4-Methyl-2-Hydroxyacetophenone;Mercaptobenzimidazole zinc salt;2'-HYDROXY-4'-METHYLACETOPHENONE;2'-Hydroxy-4'-methylacetophenone;1-(2-hydroxy-4-methylphenyl)-ethanon;1-(2-HYDROXY-4-METHYLPHENYL)ETHANONE;2'-Hydroxy-4'-Methylacetophenone 97%;Ethanone,1-(2-hydroxy-4-Methylphenyl)-
CBNumber
CB3253409
Molecular Formula
C9H10O2
Formula Weight
150.17
MOL File
6921-64-8.mol
More
Less

2'-Hydroxy-4'-methylacetophenone Property

Melting point:
21°C
Boiling point:
245 °C(lit.)
Density 
1.08 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.565(lit.)
Flash point:
>230 °F
storage temp. 
2-8°C
form 
clear liquid
pka
10.27±0.10(Predicted)
color 
Colorless to Light orange to Yellow
λmax
325nm(MeOH)(lit.)
InChIKey
LYKDOWJROLHYOT-UHFFFAOYSA-N
CAS DataBase Reference
6921-64-8(CAS DataBase Reference)
EPA Substance Registry System
Ethanone, 1-(2-hydroxy-4-methylphenyl)- (6921-64-8)
More
Less

Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36-37/39
WGK Germany 
3
HS Code 
2914500090
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
531669
Product name
2′-Hydroxy-4′-methylacetophenone
Purity
97%
Packaging
10g
Price
$132
Updated
2022/05/15
TCI Chemical
Product number
H1530
Product name
2'-Hydroxy-4'-methylacetophenone
Purity
>95.0%(GC)
Packaging
5g
Price
$76
Updated
2024/03/01
TCI Chemical
Product number
H1530
Product name
2'-Hydroxy-4'-methylacetophenone
Purity
>95.0%(GC)
Packaging
25g
Price
$264
Updated
2024/03/01
TRC
Product number
H939865
Product name
2′-Hydroxy-4′-methylacetophenone
Packaging
5g
Price
$110
Updated
2021/12/16
TRC
Product number
H939865
Product name
2′-Hydroxy-4′-methylacetophenone
Packaging
10g
Price
$175
Updated
2021/12/16
More
Less

2'-Hydroxy-4'-methylacetophenone Chemical Properties,Usage,Production

Uses

2′-Hydroxy-4′-methylacetophenone is found in Angelica koreana roots and a study was done in which it could be useful for natural acaricides against three mite species.

Preparation

Preparation by treatment of methyl 4-hydroxy-7- methyl-coumarin-3-carboxylate with potassium hydroxide at 200° (87%).

Synthesis Reference(s)

Tetrahedron Letters, 37, p. 4183, 1996 DOI: 10.1016/0040-4039(96)00790-3

General Description

2′-Hydroxy-4′-methylacetophenone, also known as 1-(2-hydroxy-4-methylphenyl)ethanone can be synthesized by the Fries rearrangement of m-tolyl acetate in the presence of zirconium tetrachloride. The results from the toxicity studies on mite species suggest that 2′-hydroxy-4′-methylacetophenone possesses acaricidal property.

2'-Hydroxy-4'-methylacetophenone Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

2'-Hydroxy-4'-methylacetophenone Suppliers

Americas 1 Belgium 1 Canada 1 China 120 Europe 3 France 1 Germany 3 India 19 Japan 1 South Korea 1 Switzerland 2 Ukraine 1 United Kingdom 12 United States 25 Global 191
Attix Pharmaceuticals/Darmerica
Tel
--
Fax
--
Email
sales@darmerica.com
Country
Canada
ProdList
964
Advantage
58
More
Less

View Lastest Price from 2'-Hydroxy-4'-methylacetophenone manufacturers

Shaanxi Dideu New Materials Co. Ltd
Product
2'-Hydroxy-4'-methylacetophenone 6921-64-8
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98.0%
Supply Ability
10000KGS
Release date
2024-11-19
Zhuozhou Wenxi import and Export Co., Ltd
Product
2"-Hydroxy-4"-methylacetophenone 6921-64-8
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-06-27
Career Henan Chemical Co
Product
2'-Hydroxy-4'-methylacetophenone 6921-64-8
Price
US $1.00/KG
Min. Order
1KG
Purity
98% HPLC
Supply Ability
10tons
Release date
2020-02-18

6921-64-8, 2'-Hydroxy-4'-methylacetophenoneRelated Search:

2'-Methylacetophenone 4-Nitroacetophenone 4'-(Trifluoromethyl)acetophenone 4'-Hydroxyacetophenone CHLOROPHOSPHONAZO III PIPERACETAZINE (250 MG) 3'-Methylacetophenone 3-Nitroacetophenone 4'-Methylacetophenone 2'-Hydroxyacetophenone 3'-(Trifluoromethyl)acetophenone Acetophenone 4'-Methoxyacetophenone 2',4'-Dichloroacetophenone FRANGULIN B Chrysophanic acid 5-CHLORO-2-HYDROXY-4-METHYLBENZOPHENONE Emodin

  • 2'-HYDROXY-4'-METHYLACETOPHENONE
  • 1-(2-HYDROXY-4-METHYLPHENYL)ETHAN-1-ONE
  • 1-(2-HYDROXY-4-METHYLPHENYL)ETHANONE
  • ASISCHEM D38758
  • 1-(2-hydroxy-4-methylphenyl)-ethanon
  • 4-Methyl-2-Hydroxyacetophenone
  • 1-(2-HYDROXY-4-METHYLPHENYL)ETHAN-1-ON
  • Ethanone,1-(2-hydroxy-4-Methylphenyl)-
  • 2'-Hydroxy-4'-Methylacetophenone 97%
  • 2'-Hydroxyacetopenone
  • Mercaptobenzimidazole zinc salt
  • 2'-Hydroxy-4'-methylacetophenone
  • 6921-64-8
  • Building Blocks
  • Carbonyl Compounds
  • C9
  • Organic Building Blocks
  • Ketones
  • Aromatic Acetophenones & Derivatives (substituted)
  • Phenyls & Phenyl-Het
  • Phenyls & Phenyl-Het
  • C9
  • Carbonyl Compounds
  • Ketones