ChemicalBook > CAS DataBase List > 2'-Hydroxy-4'-methylacetophenone

2'-Hydroxy-4'-methylacetophenone

Product Name
2'-Hydroxy-4'-methylacetophenone
CAS No.
6921-64-8
Chemical Name
2'-Hydroxy-4'-methylacetophenone
Synonyms
ASISCHEM D38758;2'-Hydroxyacetopenone;4-Methyl-2-Hydroxyacetophenone;Mercaptobenzimidazole zinc salt;2'-HYDROXY-4'-METHYLACETOPHENONE;2'-Hydroxy-4'-methylacetophenone;1-(2-hydroxy-4-methylphenyl)-ethanon;1-(2-HYDROXY-4-METHYLPHENYL)ETHANONE;2'-Hydroxy-4'-Methylacetophenone 97%;Ethanone,1-(2-hydroxy-4-Methylphenyl)-
CBNumber
CB3253409
Molecular Formula
C9H10O2
Formula Weight
150.17
MOL File
6921-64-8.mol
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2'-Hydroxy-4'-methylacetophenone Property

Melting point:
21°C
Boiling point:
245 °C(lit.)
Density 
1.08 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.565(lit.)
Flash point:
>230 °F
storage temp. 
2-8°C
form 
clear liquid
pka
10.27±0.10(Predicted)
color 
Colorless to Light orange to Yellow
λmax
325nm(MeOH)(lit.)
InChIKey
LYKDOWJROLHYOT-UHFFFAOYSA-N
CAS DataBase Reference
6921-64-8(CAS DataBase Reference)
EPA Substance Registry System
Ethanone, 1-(2-hydroxy-4-methylphenyl)- (6921-64-8)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36-37/39
WGK Germany 
3
HS Code 
2914500090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
531669
Product name
2′-Hydroxy-4′-methylacetophenone
Purity
97%
Packaging
10g
Price
$132
Updated
2022/05/15
TCI Chemical
Product number
H1530
Product name
2'-Hydroxy-4'-methylacetophenone
Purity
>95.0%(GC)
Packaging
5g
Price
$76
Updated
2024/03/01
TCI Chemical
Product number
H1530
Product name
2'-Hydroxy-4'-methylacetophenone
Purity
>95.0%(GC)
Packaging
25g
Price
$264
Updated
2024/03/01
TRC
Product number
H939865
Product name
2′-Hydroxy-4′-methylacetophenone
Packaging
5g
Price
$110
Updated
2021/12/16
TRC
Product number
H939865
Product name
2′-Hydroxy-4′-methylacetophenone
Packaging
10g
Price
$175
Updated
2021/12/16
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2'-Hydroxy-4'-methylacetophenone Chemical Properties,Usage,Production

Uses

2′-Hydroxy-4′-methylacetophenone is found in Angelica koreana roots and a study was done in which it could be useful for natural acaricides against three mite species.

Preparation

Preparation by treatment of methyl 4-hydroxy-7- methyl-coumarin-3-carboxylate with potassium hydroxide at 200° (87%).

Synthesis Reference(s)

Tetrahedron Letters, 37, p. 4183, 1996 DOI: 10.1016/0040-4039(96)00790-3

General Description

2′-Hydroxy-4′-methylacetophenone, also known as 1-(2-hydroxy-4-methylphenyl)ethanone can be synthesized by the Fries rearrangement of m-tolyl acetate in the presence of zirconium tetrachloride. The results from the toxicity studies on mite species suggest that 2′-hydroxy-4′-methylacetophenone possesses acaricidal property.

2'-Hydroxy-4'-methylacetophenone Preparation Products And Raw materials

Raw materials

Preparation Products

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2'-Hydroxy-4'-methylacetophenone Suppliers

Americas 1 Belgium 1 Canada 1 China 116 Europe 3 France 1 Germany 3 India 19 Japan 1 South Korea 1 Switzerland 2 Ukraine 1 United Kingdom 12 United States 22 Global 184
TCI Europe
Tel
320-37350700
Fax
+32 (0)37350701
Email
sales@tcieurope.eu
Country
Europe
ProdList
23680
Advantage
75
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View Lastest Price from 2'-Hydroxy-4'-methylacetophenone manufacturers

Hebei Duling International Trade Co. LTD
Product
1-(2-HYDROXY-4-METHYLPHENYL)ETHAN-1-ONE 6921-64-8
Price
US $30.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
100 tons
Release date
2022-10-25
Zhuozhou Wenxi import and Export Co., Ltd
Product
2"-Hydroxy-4"-methylacetophenone 6921-64-8
Price
US $15.00-10.00/KG
Min. Order
1KG
Purity
99%+ HPLC
Supply Ability
Monthly supply of 1 ton
Release date
2021-06-27
Career Henan Chemical Co
Product
2'-Hydroxy-4'-methylacetophenone 6921-64-8
Price
US $1.00/KG
Min. Order
1KG
Purity
98% HPLC
Supply Ability
10tons
Release date
2020-02-18

6921-64-8, 2'-Hydroxy-4'-methylacetophenoneRelated Search:

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  • 2'-HYDROXY-4'-METHYLACETOPHENONE
  • 1-(2-HYDROXY-4-METHYLPHENYL)ETHAN-1-ONE
  • 1-(2-HYDROXY-4-METHYLPHENYL)ETHANONE
  • ASISCHEM D38758
  • 1-(2-hydroxy-4-methylphenyl)-ethanon
  • 4-Methyl-2-Hydroxyacetophenone
  • 1-(2-HYDROXY-4-METHYLPHENYL)ETHAN-1-ON
  • Ethanone,1-(2-hydroxy-4-Methylphenyl)-
  • 2'-Hydroxy-4'-Methylacetophenone 97%
  • 2'-Hydroxyacetopenone
  • Mercaptobenzimidazole zinc salt
  • 2'-Hydroxy-4'-methylacetophenone
  • 6921-64-8
  • Building Blocks
  • Carbonyl Compounds
  • C9
  • Organic Building Blocks
  • Ketones
  • Aromatic Acetophenones & Derivatives (substituted)
  • Phenyls & Phenyl-Het
  • Phenyls & Phenyl-Het
  • C9
  • Carbonyl Compounds
  • Ketones