Thiomorpholine

Product Name: Thiomorpholine
CAS No.: 123-90-0
Chemical Name: Thiomorpholine
Synonyms: thiazinane;1,4-Thiazane;TETRAHYDRO-2H-1,4-THIAZINE;ThiomorphoL;1,4-Thiazan;Parathiazan;hiomorpholine;THIAMORPHOLINE;THIOMORPHOLINE;thiazolidinane
CBNumber: CB3266519
Molecular Formula: C4H9NS
Formula Weight: 103.19
MOL File: 123-90-0.mol

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Thiomorpholine Property

Melting point:: 166-168
Boiling point:: 169 °C (lit.)
Density: 1.026 g/mL at 25 °C (lit.)
refractive index: n20/D 1.538(lit.)
Flash point:: 140 °F
storage temp.: under inert gas (nitrogen or Argon) at 2–8 °C
solubility: organic solvents: miscible(lit.)
form: clear liquid
pka: 9.14±0.20(Predicted)
color: Colorless to Light yellow to Light orange
Water Solubility: Miscible with waterMiscible with water and organic solvents.
Sensitive: Air Sensitive
Merck: 14,9300
BRN: 102550
InChIKey: BRNULMACUQOKMR-UHFFFAOYSA-N
CAS DataBase Reference: 123-90-0(CAS DataBase Reference)
NIST Chemistry Reference: Thiomorpholine(123-90-0)

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Safety

Hazard Codes: C,Xi
Risk Statements: 34-37-36/37/38-R37-R34
Safety Statements: 26-36/37/39-45-36-S45-S36/37/39-S26
RIDADR: UN 3267 8/PG 3
WGK Germany: 3
F: 10-13-23
Hazard Note: Irritant
HazardClass: 8
PackingGroup: III
HS Code: 29349990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H314Causes severe skin burns and eye damage

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 196274
Product name: Thiomorpholine
Purity: 98%
Packaging: 5g
Price: $74.6
Updated: 2024/03/01

Sigma-Aldrich

Product number: 196274
Product name: Thiomorpholine
Purity: 98%
Packaging: 25g
Price: $347
Updated: 2024/03/01

TCI Chemical

Product number: T1007
Product name: Thiomorpholine
Purity: >98.0%(GC)
Packaging: 5mL
Price: $53
Updated: 2024/03/01

TCI Chemical

Product number: T1007
Product name: Thiomorpholine
Purity: >98.0%(GC)
Packaging: 25mL
Price: $169
Updated: 2024/03/01

Alfa Aesar

Product number: A15958
Product name: Thiomorpholine
Purity: 98%
Packaging: 5g
Price: $56.65
Updated: 2024/03/01

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Thiomorpholine Chemical Properties,Usage,Production

Chemical Properties

Clear colorless to yellow liquid

Uses

Organic synthesis.

Uses

Thiomorpholine is used as an intermediate for blonanserin. It is used in the preparation of pyrrole derivatives, which acts as a antimycobacterial agent. It is further involved in the hypocholesterolemic activity.

Definition

ChEBI: A saturated organic heteromonocyclic parent that is an analogue of morpholine where the oxygen atom is replaced by sulfur.

General Description

Thiomorpholine forms complexes with Cu(II), Pt(II) and Ni(II) salts and their catalytic activity has been investigated.

Purification Methods

Purify it by vacuum distillation. The hydrochloride has m 179o (from isoPrOH or EtOH/Et2O/HCl). [Davies J Chem Soc 306 1920, Beilstein 27 II 4, 2 III/IV 636.]

Thiomorpholine Preparation Products And Raw materials

Raw materials

Sodium sulfide nonahydrate Ethanol Potassium carbonate Ethyl acetate Sodium bicarbonate Bis(2-chloroethyl)amine hydrochloride Dichloromethane Methanol

Preparation Products

N-Morpholinothio Phthaldamide Thiomorpholine-1,1-dioxide

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Thiomorpholine Suppliers

Belgium 2 Canada 1 China 188 Europe 2 Germany 3 India 6 Japan 3 Slovakia 1 South Korea 1 Switzerland 4 Ukraine 1 United Kingdom 17 United States 43 Global 272

TOKYO CHEMICAL INDUSTRY CO., LTD.

Tel: 03-36680489
Fax: 03-3668-0520
Email: Sales-JP@TCIchemicals.com
Country: Japan
ProdList: 28387
Advantage: 80

FUJIFILM Wako Pure Chemical Corporation

Tel: --
Fax: --
Email: ffwk-cservice@fujifilm.com
Country: Japan
ProdList: 6222
Advantage: 58

Junsei Chemical Co., Ltd.

Tel: --
Fax: --
Email: shiyaku@junsei.co.jp
Country: Japan
ProdList: 3096
Advantage: 46

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View Lastest Price from Thiomorpholine manufacturers

Xinxiang Hongqi District Houyuan Trading Co.,Ltd

Product: Thiomorpholine 123-90-0
Price: US $30.00-28.00/Kg
Min. Order: 1Kg
Purity: 99.0% up
Supply Ability: 50 tons per month
Release date: 2022-09-26

Longyan Tianhua Biological Technology Co., Ltd

Product: Thiomorpholine 123-90-0
Price: US $800.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10000KG
Release date: 2020-10-24

Career Henan Chemical Co

Product: Thiomorpholine 123-90-0
Price: US $1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10000KGS
Release date: 2019-12-30

123-90-0, ThiomorpholineRelated Search:

Tridemorph Dimethomorph Moroxydine Moroxydine hydrochloride 1,1-DIOXIDE-4-THIOMORPHOLINE,THIOMORPHOLINE DIOXIDE ThioMorpholine-1-oxide HCl thiomorpholin-3-one THIOMORPHOLINE 1,1-DIOXIDE HYDROCHLORIDE Thiomorpholine, 4-methyl-, 1,1-dioxide,thiomorpholine,4-methyl-,1,1-dioxid 4-(Prop-2-yn-1-yl)thiomorpholine 1,1-dioxide 1,1-DIOXIDE-4-(PHENYLMETHYL) THIOMORPHOLINE THIOMORPHOLINE-3-CARBOXYLIC ACID ETHYL ESTER N-(3-DYDROXYPROPYL)THIOMORPHOLINE 1,1-DIXOXIDE THIOMORPHOLINE-3-CARBOXYLIC ACID THIOMORPHOLINE, 4-(3-AMINOROPYL)-1,1-DIOXIDE,THIOMORPHOLINE, 4-(3-AMINOPROPYL)-1,1-DIOXIDE 1-(2-Aminoethyl)thiomorpholine 4-(2-HYDROXYETHYL)THIOMORPHOLINE 1,1-DIOXIDE 4-ALLYL-1LAMBDA6,4-THIAZINANE-1,1-DIONE

ThiomorphoL

Tetrahydro-2H-1,4-thiazine, Thiamorpholine

Thiomorpholine,97%

ThioMorpholine, 97% 5GR

Thiomorpholine ,98%

1,4-Thiazinane, Tetrahydro-2H-1,4-thiazine

ThioMorpholine 98.0%Min

ThioMorpholine 98%

4-THIOMORPHOLINE

THIOMORPHOLINE

THIAMORPHOLINE

TETRAHYDRO-1,4-THIAZINE

TETRAHYDRO-2H-1,4-THIAZINE

TETRAHYDRO-4H-1,4-THIAZINE

1,4-Thiazan

1,4-Thiazane

1,4-Thiazine, tetrahydro-

1-Thia-4-azacyclohexane

Parathiazan

thiazinane

thiazolidinane

Thiomorpholine, 98%, for synthesis

hiomorpholine

sulfanylMorpholine

Thiomorpholine, ≥ 98.0%

123-90-0

C4H9NS

C4H10NS

Morpholines

Others

S-Containing

Building Blocks

Heterocyclic Building Blocks

AMINE

Pyrimidines

Building Blocks

Chemical Synthesis

Heterocyclic Building Blocks

Others

S-Containing

Morpholines & Thiomorpholines

Ring Systems