ChemicalBook > CAS DataBase List > 4-Methylcyclohexanecarboxylic acid

4-Methylcyclohexanecarboxylic acid

Product Name: 4-Methylcyclohexanecarboxylic acid
CAS No.: 4331-54-8
Chemical Name: 4-Methylcyclohexanecarboxylic acid
Synonyms: 4-METHYL-CYCLOHEXANECARBOXYLIC ACID;Cyclohexanecarboxylic acid,4-methyl-;4-METHYL-1-CYCLOHEXANECARBOXYLIC ACID;4-Methylcyclohexanecarboxylic Acid 4-Methyl-1-cyclohexanecarboxylic acid 99%;4-Methyl-1-cyclohexanecarboxylic acid 95+%;trans-4-Methyl-1-cyclohexanecarboxylic acid;4-METHYL-1-CYCLOHEXANECARBOXYLICACID(CIS+TRANS);4-MethylcyclohexanecarboxylicAcid(cis-andtrans-mixture)>4-Methylcyclohexanecarboxylic acid,mixture of cis and trans
CBNumber: CB3288195
Molecular Formula: C8H14O2
Formula Weight: 142.2
MOL File: 4331-54-8.mol

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4-Methylcyclohexanecarboxylic acid Property

Melting point:: 110 °C
Boiling point:: 134-136 °C/15 mmHg (lit.)
Density: 1.005 g/mL at 25 °C (lit.)
refractive index: n20/D 1.4598(lit.)
Flash point:: >230 °F
storage temp.: Sealed in dry,Room Temperature
solubility: Chloroform, DMSO, Methanol
pka: 4.92±0.10(Predicted)
form: Oil
color: Clear Colorless
InChI: InChI=1S/C8H14O2/c1-6-2-4-7(5-3-6)8(9)10/h6-7H,2-5H2,1H3,(H,9,10)
InChIKey: QTDXSEZXAPHVBI-UHFFFAOYSA-N
SMILES: C1(C(O)=O)CCC(C)CC1

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Safety

Hazard Codes: Xn
Risk Statements: 22-36
Safety Statements: 26
WGK Germany: 2
HS Code: 29162090

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H319Causes serious eye irritation

Precautionary statements

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 330620
Product name: 4-Methyl-1-cyclohexanecarboxylic acid
Purity: 99%
Packaging: 5g
Price: $76.7
Updated: 2023/01/07

TCI Chemical

Product number: M1621
Product name: 4-Methylcyclohexanecarboxylic Acid (cis- and trans- mixture)
Purity: >98.0%(GC)(T)
Packaging: 5g
Price: $109
Updated: 2025/07/31

TCI Chemical

Product number: M1621
Product name: 4-Methylcyclohexanecarboxylic Acid (cis- and trans- mixture)
Purity: >98.0%(GC)(T)
Packaging: 25g
Price: $326
Updated: 2025/07/31

TRC

Product number: M299530
Product name: 4-MethylcyclohexanecarboxylicAcid
Packaging: 10g
Price: $110
Updated: 2021/12/16

Matrix Scientific

Product number: 113906
Product name: 4-Methyl-1-cyclohexanecarboxylic acid
Purity: 97%
Packaging: 1g
Price: $134
Updated: 2021/12/16

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4-Methylcyclohexanecarboxylic acid Chemical Properties,Usage,Production

Chemical Properties

Relative density 1.005, melting point 108-111°C, boiling point 134-136°C (15mmHg), refractive index 1.4598.

Uses

4-Methyl-1-cyclohexanecarboxylic acid was used to investigate the palladium core-porous silica shell-nanoparticles catalyzed hydrogenation of 4-carboxybenzaldehyde (4-CBA) to p-toluic acid. It was also used in the synthesis of substituted cyclohexyl carbonyl chlorides.

Synthesis

99-94-5

934-67-8

GENERAL STEPS: The hydrogenation reaction was carried out in a 25 mL stainless steel autoclave with a PTFE liner. In a typical experiment, 20 mg of catalyst and 61 mg (0.5 mmol) of p-toluic acid were dispersed in 5 mL of deionized water. After sealing the autoclave, the air in the autoclave was replaced with hydrogen and pressurized to 2.5 MPa. Subsequently, the reaction mixture was heated to 110 °C under magnetic stirring (1000 rpm). Upon completion of the reaction, it was cooled to room temperature, the reaction mixture was extracted with ethyl acetate and separated by centrifugation to remove the solid catalyst. The recovered solid catalyst was washed sequentially with ethyl acetate, ethanol and deionized water. The filtrate was analyzed by gas chromatography (GC, HP5890, USA) equipped with a 30 m HP-5 capillary column and a flame ionization detector (FID). All products were confirmed structurally by gas chromatography-mass spectrometry (GC-MS, Agilent 6890).

References

[1] Tetrahedron Letters, 2004, vol. 45, # 35, p. 6669 - 6672
[2] Steroids, 1983, vol. 41, # 3, p. 349 - 359
[3] Recueil des Travaux Chimiques des Pays-Bas, 1961, vol. 80, p. 595 - 607
[4] Recueil des Travaux Chimiques des Pays-Bas, 1961, vol. 80, p. 595 - 607
[5] Journal of the Chemical Society, 1937, p. 2003,2007

4-Methylcyclohexanecarboxylic acid Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from 4-Methylcyclohexanecarboxylic acid manufacturers

ZHENGZHOU JIUYI TIME NEW MATERIALS CO,.LTD

Product: 4-Methylcyclohexanecarboxylic acid 4331-54-8
Price: US $3.00-9.00/KG
Min. Order: 0.1KG
Purity: 99%
Supply Ability: g-kg-tons, free sample is available
Release date: 2025-06-24

Shanghai Yongzeng Technology Co.,Ltd

Product: 4-methylcyclohexanecarboxylic acid 4331-54-8
Price: US $0.00/gm
Min. Order: 100gm
Purity: 99%min
Supply Ability: 100kgs
Release date: 2024-09-09

Wuhan Boyuan Import & Export Co., LTD

Product: 4-Methylcyclohexanecarboxylic acid 4331-54-8
Price: US $9.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 50000tons
Release date: 2023-05-31

4331-54-8, 4-Methylcyclohexanecarboxylic acidRelated Search:

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4-METHYL-CYCLOHEXANECARBOXYLIC ACID

4-METHYL-1-CYCLOHEXANECARBOXYLIC ACID

4-Methyl-1-cyclohexanecarboxylic acid,mixture of cis and trans

4-METHYL-1-CYCLOHEXANECARBOXYLIC ACID, 9 9%, MIXTURE OF CIS AND TRANS

4-Methyl-1-cyclohexanecarboxylic acid, 98%, mixture of cis and trans

4-Methylcyclohexanecarboxylic Acid (cis- and trans- mixture)

4-METHYL-1-CYCLOHEXANECARBOXYLICACID(CIS+TRANS)

trans-4-Methyl-1-cyclohexanecarboxylic acid

4-Methyl-1-cyclohexanecarboxylic acid 99%

Cyclohexanecarboxylic acid,4-methyl-

4-Methylcyclohexanecarboxylic Acid&nbsp

4-Methylcyclohexanecarboxylic Acid (<i>cis</i>- and <i>trans</i>- mixture)

4-Methyl-1-cyclohexanecarboxylic acid 95+%

4-MethylcyclohexanecarboxylicAcid(cis-andtrans-mixture)&gt

4-Methylcyclohexanecarboxylic acid,mixture of cis and trans

4331-54-8

Organic Building Blocks

4-Substituted Cyclohexanecarboxylic Acids

4-Alkylcyclohexanecarboxylic Acids (Building Blocks for Liquid Crystals)

Building Blocks for Liquid Crystals

Building Blocks

Carbonyl Compounds

Carboxylic Acids

Building Blocks

Carbonyl Compounds

Carboxylic Acids

Chemical Synthesis

Organic Building Blocks

4-Alkylcyclohexanecarboxylic Acids (Building Blocks for Liquid Crystals)

4-Substituted Cyclohexanecarboxylic Acids

Building Blocks for Liquid Crystals

Functional Materials

Carbonyl Compounds

Carboxylic Acids