t-BuBrettPhos Palladacycle Gen. 3

ChemicalBook > CAS DataBase List > t-BuBrettPhos Palladacycle Gen. 3

t-BuBrettPhos Palladacycle Gen. 3

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Product Name: t-BuBrettPhos Palladacycle Gen. 3
CAS No.: 1536473-72-9
Chemical Name: t-BuBrettPhos Palladacycle Gen. 3
Synonyms: P](methane;N)[1,1’-(Amino-κtbuttphos Pd G3;-biphenyl]-2-yl-κC][[3,6-dimethoxy-2’-tris(1-methylethyl)[1,1’t-BuBrettPhos Palladacycle Gen. 3;t-butylBrettPhos Palladacycle Gen. 3;t-BuBrettPhos Palladacycle Gen. 3 ISO 9001：2015 REACH
CBNumber: CB33052898
Molecular Formula: C44H63NO5PPdS-
Formula Weight: 855.433481
MOL File: 1536473-72-9.mol

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t-BuBrettPhos Palladacycle Gen. 3 Property

Melting point:: 119-131°C
storage temp.: under inert gas (nitrogen or Argon) at 2-8°C
form: solid
color: brown-green
InChI: InChI=1S/C31H49O2P.C12H10N.CH4O3S.Pd/c1-19(2)22-17-23(20(3)4)27(24(18-22)21(5)6)28-25(32-13)15-16-26(33-14)29(28)34(30(7,8)9)31(10,11)12;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h15-21H,1-14H3;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;-1;;
InChIKey: VKLHIPFGYVFUGT-UHFFFAOYSA-N
SMILES: [Pd].S(C([H])([H])[H])(=O)(=O)O[H].P(C1=C(C([H])=C([H])C(=C1C1C(=C([H])C(C([H])(C([H])([H])[H])C([H])([H])[H])=C([H])C=1C([H])(C([H])([H])[H])C([H])([H])[H])C([H])(C([H])([H])[H])C([H])([H])[H])OC([H])([H])[H])OC([H])([H])[H])(C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H].N([H])([H])C1=C([H])C([H])=C([H])C([H])=C1C1=C([H])C([H])=C([H])C([H])=[C-]1
CAS DataBase Reference: 1536473-72-9

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Safety

WGK Germany: 3

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Precautionary statements

P201Obtain special instructions before use.

P202Do not handle until all safety precautions have been read and understood.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P308+P313IF exposed or concerned: Get medical advice/attention.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 745979
Product name: tBuBrettPhos Pd G3
Purity: 96%
Packaging: 100MG
Price: $81.6
Updated: 2024/03/01

Sigma-Aldrich

Product number: 745979
Product name: tBuBrettPhos Pd G3
Purity: 96%
Packaging: 500MG
Price: $147
Updated: 2024/03/01

Sigma-Aldrich

Product number: 745979
Product name: tBuBrettPhos Pd G3
Purity: 96%
Packaging: 1G
Price: $341
Updated: 2024/03/01

Sigma-Aldrich

Product number: 928313
Product name: tBuBrettPhos Pd G3 ChemBeads
Packaging: 1G
Price: $287
Updated: 2024/03/01

Sigma-Aldrich

Product number: 745979
Product name: tBuBrettPhos Pd G3
Purity: 96%
Packaging: 2G
Price: $666
Updated: 2024/03/01

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t-BuBrettPhos Palladacycle Gen. 3 Chemical Properties,Usage,Production

Reaction

Palladium catalyst used for the arylation of primary amides.
Palladium catalyst used for the synthesis of N-aryl carbamates.
Palladium catalyst used for the N-monoarylation of amidines.
Palladium catalyst used for the cross-coupling of aryl chlorides and triflates with sodium cyanate – a practical synthesis of unsymmetrical ureas.
Palladium catalyst used in the synthesis of imidazo[4,5-b]pyridines and imidazo[4,5]pyrazines through amidation of 2-chloro-3-amino-heterocycles.
Palladium catalyst used in the N-arylation of 2-aminothiazoles
Palladium catalyst used in the synthesis of diarylethers under mild conditions.
Palladium catalyst used in the hydroxylation of aryl and heteroaryl halides.

Uses

tBuBrettPhos Pd G3 has been used as a precatalyst for the N-arylation of amino acid esters with aryl triflates under mild reaction conditions and minimal racemization of the amino acid ester. It may also be used to catalyze the conversion of aryl halides to phenols in the presence of benzaldoxime as a hydroxide surrogate.

General Description

tBuBrettPhos Pd G3 is a third generation (G3) Buchwald precatalyst that can be used in cross-coupling reactions for the formation of C-C, C–N, C–O, C–F, C–CF3, and C–S bonds. It is air-, moisture-, and thermally-stable and is highly soluble in a wide range of common organic solvents. Some of its unique features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species and accurate control of ligand: palladium ratio.

t-BuBrettPhos Palladacycle Gen. 3 Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from t-BuBrettPhos Palladacycle Gen. 3 manufacturers

Wuhan LPBchem Technology Co.,Ltd

Product: Methanesulfonato(2-di-t-butylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) / t-BuBrettPhos Pd G3 1536473-72-9
Price: US $0.00-0.00/g
Min. Order: 1g
Purity: 0.98
Supply Ability: 50KG
Release date: 2020-11-26

Career Henan Chemical Co

Product: t-BuBrettPhos Palladacycle Gen. 3 1536473-72-9
Price: US $1.00/g
Min. Order: 1g
Purity: Min98%HPLC
Supply Ability: g/kg/ton
Release date: 2020-01-09

1536473-72-9, t-BuBrettPhos Palladacycle Gen. 3Related Search:

cataCXium A Pd G3 XPhos Pd G3 SPhos Palladacycle Gen. 4 XPhos Pd G4 Xantphos Pd G3 BrettPhos Pd G3 XPhos Pd G2 RuPhos Pd G1 Methyl t--Butyl Ether Adduct SPhos Pd G2 BrettPhosPalladacycle Palladacycle Gen. 3 t-BuXphos Palladacycle Gen. 4 RuPhos Palladacycle Gen. 4 SPhos Pd G3 SPhos Pd G1, Methyl t-Butyl Ether Adduct RuPhos Pd G2 tBuXPhos Pd G1 XPhos Pd G1

Methanesulfonato 2-Di-t-butylphosphino-3,6-dimethoxy-2'-4' -6'-tri-i-propyl-1,1'-bipheny)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)

Methanesulfonato(2-(di-t-butylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), min. 98%

METHANESULFONATO(2-(DI-T-BUTYLPHOSPHINO)-3,6-DIMETHOXY-2',4',6'-TRI-I-PROPYL-1,1'-BIPHENYL)(2'-AMINO-1,1'-BIPHENYL-2-YL)PALLADIUM(II),DICHLOROMETHANEADDUCT,MIN.98%[T-BUBRETTPHOSPALLADACYCLEGEN.3]

t-BuBrettPhos Palladacycle Gen. 3

Methanesulfonato(2-(di-t-butylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II),[t-BuBrettPhos Palladacycle Gen. 3]

Methanesulfonato(2-(di-t-butylphosphino)-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), dichloromethane adduct, min. 98%[t-BuBrettPhos Palladacycle Gen.

Methanesulfonato[2-(di-t-butylphosphino)-3,6-dimethoxy-2’,4’,6’-tri-i-propyl-1,1’-biphenyl](2’-amino-1,1’-biphenyl-2-yl)palladium(II)

[2'-(amino-κN)[1,1'-biphenyl]-2-yl-κC][[3,6-dimethoxy-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]bis(1,1-dimethyle

t-butylBrettPhos Palladacycle Gen. 3

Methanesulfonate[(2-Di-tert-butylphosphino-3,6-dimethoxy-2',4',6'-triisopropyl-1,1'-biphenyl)-2-(2'-amino-1,1'-biphenyl)]palladium(II) tBuBrettPhos Pd G3

Methanesulfonato(2-di-t-butylphosphino-3,6-dimethoxy-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) / t-BuBrettPhos Pd G3

2'-(Amino-κN)[1,1'-biphenyl]-2-yl-κC][[3,6-dimethoxy-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]bis(1,1-dimethylethyl)phosphine-κP](methanesulfonato-κO)palladium

-(Amino-&kappa

-biphenyl]-2-yl-&kappa

-biphenyl]-2-yl]bis(1,1-dimethylethyl)phosphine-&kappa

C][[3,6-dimethoxy-2&rsquo

N)[1,1&rsquo

P](methane

-tris(1-methylethyl)[1,1&rsquo

t-BuBrettPhos Palladacycle Gen. 3 ISO 9001：2015 REACH

2'-(Amino-κN)[1,1'-biphenyl]-2-yl-κC][[3,6-dimethoxy-2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]bis(1,1-dimethylethyl)phosphine-κP](methanesulfonato-κO)palladium (tBuBrettPhos Pd G3)

Methanesulfonato(2-Di-t-butylphosphino-3,6-dimethoxy-2'-4' -6'-tri-i-propyl-1,1'-bipheny)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) (tBuBrettPhos Pd G3)

t-ButylXPhos Pd G4 / Methanesulfonato(2-di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl)(2'-methylamino-1,1'-biphenyl-2-yl)palladium(II)

tbuttphos Pd G3

methanesulfonato 2-di-t-butylphosphino-3,6-dimethoxy-2'-4' -6'-tri-i-propyl-1,1'-bipheny)(2'-amino-1,1'-biphenyl-2-yl)palladium(ii)

(2-Di-tert-butylphosphino-3,6-dimethoxy-2',4',6'-triisopropyl-1,1'-biphenyl)-2-(2'-amino-1,1'-biphenyl)]palladium(II) methanesulfonate

ditert-butyl-[3,6-dimethoxy-2-(2,4,6-triisopropylphenyl)phenyl]phosphane methylsulfonyloxy-(2-phenylanilino)palladium

1536473-72-9

C44H62NO5PPdS

C31H49O2PC13H13NO3PdS

Buchwald Ligands&Precatalysts

Buchwald Precatalysts Series