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ChemicalBook > CAS DataBase List > (OXYDI-2,1-PHENYLENE)BIS(DIPHENYLPHOSPHINE)

(OXYDI-2,1-PHENYLENE)BIS(DIPHENYLPHOSPHINE)

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Product Name
(OXYDI-2,1-PHENYLENE)BIS(DIPHENYLPHOSPHINE)
CAS No.
166330-10-5
Chemical Name
(OXYDI-2,1-PHENYLENE)BIS(DIPHENYLPHOSPHINE)
Synonyms
DPEPHOS;BIS(2-DIPHENYLPHOSPHINOPHENYL)ETHER;1-(diphenylphosphino)-2-(2-(diphenylphosphino)phenoxy)benzene;DK994;Bis(2-diphenyphosphinophenyl)ether;{2-[2-(di;ene)bis(diphenyL;(Oxydi-2,1-phenyL;(OXYDI-2,1-PHENYLENE)BIS(DIPHE;Bisdiphenylphosphinophenylether
CBNumber
CB3685781
Molecular Formula
C36H28OP2
Formula Weight
538.55
MOL File
166330-10-5.mol
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(OXYDI-2,1-PHENYLENE)BIS(DIPHENYLPHOSPHINE) Property

Melting point:
184-187 °C (lit.)
Boiling point:
608.2±40.0 °C(Predicted)
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
solubility 
Chloroform (Slightly), Methanol (Slightly)
form 
Crystalline Powder or Crystals
color 
White to off-white
BRN 
7729718
InChIKey
RYXZOQOZERSHHQ-UHFFFAOYSA-N
CAS DataBase Reference
166330-10-5(CAS DataBase Reference)
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Safety

Hazard Codes 
Xn
Risk Statements 
36/37/38-22
Safety Statements 
37/39-26
WGK Germany 
3
TSCA 
No
HS Code 
29319090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
510017
Product name
(Oxydi-2,1-phenylene)bis(diphenylphosphine)
Purity
98%
Packaging
25g
Price
$140
Updated
2024/03/01
TCI Chemical
Product number
B2867
Product name
Bis[2-(diphenylphosphino)phenyl] Ether
Purity
>98.0%(GC)
Packaging
5g
Price
$51
Updated
2024/03/01
TCI Chemical
Product number
B2867
Product name
Bis[2-(diphenylphosphino)phenyl] Ether
Purity
>98.0%(GC)
Packaging
25g
Price
$148
Updated
2024/03/01
Alfa Aesar
Product number
L18481
Product name
Bis[(2-diphenylphosphino)phenyl] ether, 98%
Packaging
1g
Price
$48.65
Updated
2024/03/01
Alfa Aesar
Product number
L18481
Product name
Bis[(2-diphenylphosphino)phenyl] ether, 98%
Packaging
5g
Price
$144
Updated
2024/03/01
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(OXYDI-2,1-PHENYLENE)BIS(DIPHENYLPHOSPHINE) Chemical Properties,Usage,Production

Reaction

  1. Useful as a ligand in the Pd-catalyzed formation of diaryl amines.
  2. Has been recently applied to the C3 benzylation of indoles.
  3. Has been recently applied to the monoallylation of ammonia.
  4. Ligand used in the palladium-catalyzed, aerobic oxidation coupling of acyl chlorides with arylboronic acids.
  5. Ligand used in carbonylation of aryl iodides.
  6. Ligand used in the direct C-H arylation of benzothiodiazoles.
  7. Ligand used in stereo-retentive azacyclization of propargylic carbonates.
  8. Ligand used in palladium catalyzed benzyne trimerization.

Chemical Properties

White to off-white crystalline powder or crystals

Uses

suzuki reaction

Uses

Ligand for ruthenium-catalyzed greener amine synthesis from amines and alcohols by hydrogen-borrowing.

Ruthenium-Catalyzed N-Alkylation of Amines and Sulfonamides Using Borrowing Hydrogen Methodology

General Description

This product has been enhanced for catalytic efficiency.

(OXYDI-2,1-PHENYLENE)BIS(DIPHENYLPHOSPHINE) Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from (OXYDI-2,1-PHENYLENE)BIS(DIPHENYLPHOSPHINE) manufacturers

XINXIANG RUNYU MATERIAL CO., LTD.
Product
(OXYDI-2,1-PHENYLENE)BIS(DIPHENYLPHOSPHINE) 166330-10-5
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
99.5%
Supply Ability
2T
Release date
2023-12-07
Hebei Mojin Biotechnology Co., Ltd
Product
(OXYDI-2,1-PHENYLENE)BIS(DIPHENYLPHOSPHINE) 166330-10-5
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-09-05
Hebei Guanlang Biotechnology Co,.LTD
Product
DPEPhos 166330-10-5
Price
US $5.00-2.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10000kg
Release date
2023-06-09

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  • Phosphorus Compounds
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