ChemicalBook > CAS DataBase List > Cyclopropanecarboxaldehyde
Cyclopropanecarboxaldehyde
- Product Name
- Cyclopropanecarboxaldehyde
- CAS No.
- 1489-69-6
- Chemical Name
- Cyclopropanecarboxaldehyde
- Synonyms
- Cyclopropanecarbaldehyde;Formylcyclopropane;Cyclopropylmethanal;Cyclopropylcarboxaldehyde;1-Cyclopropanecarbaldehyde;Cyclopropane-1-carbaldehyde;Cyclopropanecarboxyaldehyde;opropanecarbaL;RARECHEM AK ML 0578;Cyclopropanecarboxal
- CBNumber
- CB4132338
- Molecular Formula
- C4H6O
- Formula Weight
- 70.09
- MOL File
- 1489-69-6.mol
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Cyclopropanecarboxaldehyde Property
- Boiling point:
- 98-101 °C (lit.)
- Density
- 0.938 g/mL at 25 °C (lit.)
- refractive index
- n20/D 1.4298(lit.)
- Flash point:
- 45 °F
- storage temp.
- 2-8°C
- solubility
- soluble in Chloroform
- form
- clear liquid
- color
- Colorless to Light orange to Yellow
- Water Solubility
- Soluble in water.
- Sensitive
- Air Sensitive
- BRN
- 906781
- Stability:
- Volatile
- InChIKey
- JMYVMOUINOAAPA-UHFFFAOYSA-N
- CAS DataBase Reference
- 1489-69-6(CAS DataBase Reference)
- NIST Chemistry Reference
- Cyclopropanecarboxaldehyde(1489-69-6)
- EPA Substance Registry System
- Cyclopropanecarboxaldehyde (1489-69-6)
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Safety
- Hazard Codes
- F,C
- Risk Statements
- 11-34
- Safety Statements
- 16-26-36/37/39-45
- RIDADR
- UN 2924 3/PG 2
- WGK Germany
- 3
- RTECS
- GZ1005000
- TSCA
- Yes
- HazardClass
- 3
- PackingGroup
- II
- HS Code
- 29122990
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H225Highly Flammable liquid and vapour
H314Causes severe skin burns and eye damage
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233Keep container tightly closed.
P240Ground/bond container and receiving equipment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- 272213
- Product name
- Cyclopropanecarboxaldehyde
- Purity
- 98%
- Packaging
- 1g
- Price
- $47.9
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- 272213
- Product name
- Cyclopropanecarboxaldehyde
- Purity
- 98%
- Packaging
- 5g
- Price
- $126
- Updated
- 2024/03/01
TCI Chemical
- Product number
- C1707
- Product name
- Cyclopropanecarboxaldehyde
- Purity
- >97.0%(GC)
- Packaging
- 1g
- Price
- $38
- Updated
- 2024/03/01
TCI Chemical
- Product number
- C1707
- Product name
- Cyclopropanecarboxaldehyde
- Purity
- >97.0%(GC)
- Packaging
- 5g
- Price
- $109
- Updated
- 2024/03/01
Alfa Aesar
- Product number
- L14931
- Product name
- Cyclopropanecarboxaldehyde, 98%
- Packaging
- 1g
- Price
- $36.65
- Updated
- 2024/03/01
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Cyclopropanecarboxaldehyde Chemical Properties,Usage,Production
Chemical Properties
clear colorless liquid
Uses
Cyclopropanecarboxaldehyde reacts with Grignard or organolithium reagents to give the expected secondary alcohols. These are susceptible to ring opening in the presence of HBr, providing stereoselective access to homoallylic bromides. It is also used in the synthesis of eta(2)-enonenickel complexes by reacting with [Ni(cod)(2)] (cod = 1,5-cyclooctadiene) and PBu(3) and to prepare a cyclopropylidene tetralone which underwent an enantioselective palladium-catalyzed [3+2] TMM cycloaddition providing a chiral spiro-fused cyclopentene.
Application
Cyclopropanecarboxaldehyde is a reagent in the preparation of N-alkylphenylalaninamides of pyridinylphenyland oxobipyridinylamines as human GPR 142 agonists for potential use as anti-diabetic agents and the cytochrome P 450 inhibition.
Preparation
Cyclopropanecarboxaldehyde is prepared by reaction of cyclopropylmethanol. The reaction needs reagent pyridinium chlorochromate and solvent CH2Cl2 with other condition of ambient temperature for 3 hours. The yield is about 60%.
Definition
ChEBI: Cyclopropanecarbaldehyde is an organooxygen compound.
Cyclopropanecarboxaldehyde Preparation Products And Raw materials
Raw materials
Cyclopropyl carbinol
Sodium hypochlorite
Potassium bromide
Pyridinium chlorochromate
Triethylamine
Potassium Phosphate Monobasic
2,2,6,6-Tetramethylpiperidinooxy
Dichloromethane
Oxalyl chloride
Cyclopropyl bromide
Magnesium sulfate
Preparation Products
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View Lastest Price from Cyclopropanecarboxaldehyde manufacturers
Ouhuang Engineering Materials (Hubei) Co., Ltd
- Product
- Cyclopropanecarboxyldehyde 1489-69-6
- Price
- US $100.00-30.00/kg
- Min. Order
- 1kg
- Purity
- 99.93%
- Supply Ability
- 1000kg per week
- Release date
- 2024-04-24
Hebei Mojin Biotechnology Co., Ltd
- Product
- Cyclopropanecarboxaldehyde 1489-69-6
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 50000KG/month
- Release date
- 2023-07-24
Hebei Mojin Biotechnology Co., Ltd
- Product
- Cyclopropanecarboxaldehyde 1489-69-6
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 50000KG/month
- Release date
- 2023-07-03
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