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Cyclopropanecarboxaldehyde

Product Name
Cyclopropanecarboxaldehyde
CAS No.
1489-69-6
Chemical Name
Cyclopropanecarboxaldehyde
Synonyms
Cyclopropanecarbaldehyde;Formylcyclopropane;Cyclopropylmethanal;Cyclopropylcarboxaldehyde;1-Cyclopropanecarbaldehyde;Cyclopropane-1-carbaldehyde;Cyclopropanecarboxyaldehyde;opropanecarbaL;RARECHEM AK ML 0578;Cyclopropanecarboxal
CBNumber
CB4132338
Molecular Formula
C4H6O
Formula Weight
70.09
MOL File
1489-69-6.mol
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Cyclopropanecarboxaldehyde Property

Boiling point:
98-101 °C (lit.)
Density 
0.938 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.4298(lit.)
Flash point:
45 °F
storage temp. 
2-8°C
solubility 
soluble in Chloroform
form 
clear liquid
color 
Colorless to Light orange to Yellow
Water Solubility 
Soluble in water.
Sensitive 
Air Sensitive
BRN 
906781
Stability:
Volatile
InChIKey
JMYVMOUINOAAPA-UHFFFAOYSA-N
CAS DataBase Reference
1489-69-6(CAS DataBase Reference)
NIST Chemistry Reference
Cyclopropanecarboxaldehyde(1489-69-6)
EPA Substance Registry System
Cyclopropanecarboxaldehyde (1489-69-6)
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Safety

Hazard Codes 
F,C
Risk Statements 
11-34
Safety Statements 
16-26-36/37/39-45
RIDADR 
UN 2924 3/PG 2
WGK Germany 
3
RTECS 
GZ1005000
TSCA 
Yes
HazardClass 
3
PackingGroup 
II
HS Code 
29122990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H314Causes severe skin burns and eye damage

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
272213
Product name
Cyclopropanecarboxaldehyde
Purity
98%
Packaging
1g
Price
$47.9
Updated
2024/03/01
Sigma-Aldrich
Product number
272213
Product name
Cyclopropanecarboxaldehyde
Purity
98%
Packaging
5g
Price
$126
Updated
2024/03/01
TCI Chemical
Product number
C1707
Product name
Cyclopropanecarboxaldehyde
Purity
>97.0%(GC)
Packaging
1g
Price
$38
Updated
2024/03/01
TCI Chemical
Product number
C1707
Product name
Cyclopropanecarboxaldehyde
Purity
>97.0%(GC)
Packaging
5g
Price
$109
Updated
2024/03/01
Alfa Aesar
Product number
L14931
Product name
Cyclopropanecarboxaldehyde, 98%
Packaging
1g
Price
$36.65
Updated
2024/03/01
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Cyclopropanecarboxaldehyde Chemical Properties,Usage,Production

Chemical Properties

clear colorless liquid

Uses

Cyclopropanecarboxaldehyde reacts with Grignard or organolithium reagents to give the expected secondary alcohols. These are susceptible to ring opening in the presence of HBr, providing stereoselective access to homoallylic bromides. It is also used in the synthesis of eta(2)-enonenickel complexes by reacting with [Ni(cod)(2)] (cod = 1,5-cyclooctadiene) and PBu(3) and to prepare a cyclopropylidene tetralone which underwent an enantioselective palladium-catalyzed [3+2] TMM cycloaddition providing a chiral spiro-fused cyclopentene.

Application

Cyclopropanecarboxaldehyde is a reagent in the preparation of N-alkylphenylalaninamides of pyridinylphenyland oxobipyridinylamines as human GPR 142 agonists for potential use as anti-diabetic agents and the cytochrome P 450 inhibition.

Preparation

Cyclopropanecarboxaldehyde is prepared by reaction of cyclopropylmethanol. The reaction needs reagent pyridinium chlorochromate and solvent CH2Cl2 with other condition of ambient temperature for 3 hours. The yield is about 60%.

Definition

ChEBI: Cyclopropanecarbaldehyde is an organooxygen compound.

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View Lastest Price from Cyclopropanecarboxaldehyde manufacturers

Ouhuang Engineering Materials (Hubei) Co., Ltd
Product
Cyclopropanecarboxyldehyde 1489-69-6
Price
US $100.00-30.00/kg
Min. Order
1kg
Purity
99.93%
Supply Ability
1000kg per week
Release date
2024-04-24
Hebei Mojin Biotechnology Co., Ltd
Product
Cyclopropanecarboxaldehyde 1489-69-6
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-07-24
Hebei Mojin Biotechnology Co., Ltd
Product
Cyclopropanecarboxaldehyde 1489-69-6
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-07-03

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