Potassium tetrachloroplatinate(II)

Product Name: Potassium tetrachloroplatinate(II)
CAS No.: 10025-99-7
Chemical Name: Potassium tetrachloroplatinate(II)
Synonyms: POTASSIUM TETRACHLOROPLATINATE;POTASSIUM CHLOROPLATINITE;POTASSIUM TETRACHLOROPLATINATE(II);potassiumplatinochloride;PLATINOUS POTASSIUM CHLORIDE;POTASSIUM PLATINUM(II) CHLORIDE;PLATINUM(II) DIPOTASSIUM TETRACHLORIDE;oropL;1G;5G;100G;atinate(II)
CBNumber: CB4206811
Molecular Formula: Cl4KPt-
Formula Weight: 375.98
MOL File: 10025-99-7.mol

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Potassium tetrachloroplatinate(II) Property

Melting point:: 250°C
Density: 3.38 g/mL at 25 °C(lit.)
storage temp.: Inert atmosphere,Room Temperature
solubility: soluble in Water
form: Crystals or Crystalline Powder
Specific Gravity: 3.38
color: Red-brown
Water Solubility: 10 g/L (20 ºC)
Sensitive: Hygroscopic
Merck: 14,7682
Exposure limits: ACGIH: TWA 0.002 mg/m3
NIOSH: IDLH 4 mg/m3; TWA 0.002 mg/m3
Stability:: Stable. Incompatible with acids, strong oxidizing agents.
InChIKey: RVRDLMCWUILSAH-UHFFFAOYSA-J
CAS DataBase Reference: 10025-99-7(CAS DataBase Reference)
EPA Substance Registry System: Platinate(2-), tetrachloro-, dipotassium, (SP-4-1)- (10025-99-7)

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Safety

Hazard Codes: T,Xi
Risk Statements: 25-38-41-42/43
Safety Statements: 22-26-36/37/39-45
RIDADR: UN 3288 6.1/PG 3
WGK Germany: 1
RTECS: TP1850000
TSCA: Yes
HazardClass: 6.1
PackingGroup: Ⅲ
HS Code: 28439000

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H301Toxic if swalloed

H315Causes skin irritation

H317May cause an allergic skin reaction

H318Causes serious eye damage

H334May cause allergy or asthma symptoms or breathing difficulties if inhaled

Precautionary statements

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 925098
Product name: Potassium tetrachloroplatinate(II)
Purity: Technipur?, ≥99.9% trace metals basis
Packaging: 50G
Price: $4100
Updated: 2024/03/01

Sigma-Aldrich

Product number: 925098
Product name: Potassium tetrachloroplatinate(II)
Purity: Technipur?, ≥99.9% trace metals basis
Packaging: 100G
Price: $7370
Updated: 2024/03/01

Sigma-Aldrich

Product number: 925098
Product name: Potassium tetrachloroplatinate(II)
Purity: Technipur?, ≥99.9% trace metals basis
Packaging: 250G
Price: $16230
Updated: 2024/03/01

Sigma-Aldrich

Product number: 925098
Product name: Potassium tetrachloroplatinate(II)
Purity: Technipur?, ≥99.9% trace metals basis
Packaging: 500G
Price: $29210
Updated: 2024/03/01

Sigma-Aldrich

Product number: 206075
Product name: Potassium tetrachloroplatinate(II)
Purity: 98%
Packaging: 1g
Price: $135
Updated: 2024/03/01

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Potassium tetrachloroplatinate(II) Chemical Properties,Usage,Production

Chemical Properties

Red/Brown, Tetragonal Crystals

Uses

Potassium tetrachloroplatinate solution is used in the preparation of platinum (Pt) nanoparticles. Ligands like ammonia or triphenyl phosphine can able to replace the chloride ligands to afford various derivatives. The replacement by ammonia results in the preparation of cisplatin, which is used in the cancer treatment. Further, it is used as catalyst in the hydroarylation reaction.

Uses

In photography, in acid toning baths.

General Description

Potassium tetrachloroplatinate(II) is a ruby red crystalline solid and can be prepared by reacting potassium hexachloroplatinate (IV) with cuprous chloride.

Flammability and Explosibility

Non flammable

Safety Profile

Human poison by ingestion. Poison experimentally by intraperitoneal route. Corrosive to human skin by intradermal route. Mutation data reported. Human systemic effects: eosinophha, gastritis, renal function tests depressed. When heated to decomposition it emits toxic fumes of Cland K2O. Used as a catalyst for hydroformulations, photocatalysts, and dissociation of water. See also PLATINUM COMPOUNDS.

Synthesis

To a suspension of 9.72g (0.02mol) of potassium hexachloroplatinate(IV) in 100cm3 of water, in a 250cm3 beaker, is added in small portions 1.0g (0.01mol) of hydrazine dihydrochloride. Excess hydrazine dihydrochloride must be avoided to prevent the formation of hydrazine complexes and the reduction of potassium hexachloroplatinate(IV) to platinum when the solution is made basic with ammonia during cisplatin synthesis. The mixture is stirred mechanically while the temperature is raised to 50-65°C over 5-10 minutes. This temperature is maintained for about 2 hours until only a small amount of yellow potassium hexachloroplatinate(IV) remains in the deep red solution. The temperature is then raised to 80-90°C to ensure completion of the reaction, and the mixture is cooled in an ice bath and filtered. The latter is washed with several 10cm3 portions of ice water until the washings are colourless. The washings and deep red filtrate contain pure potassium tetrachloroplatinate(II) and HCl(aq). Half of this solution is used to make the cisplatin.

Purification Methods

It forms crystals from aqueous 0.75M HCl (20mL/g) between 100o and 0o. Wash them with ice-cold water and dry.

Potassium tetrachloroplatinate(II) Preparation Products And Raw materials

Raw materials

Preparation Products

ZENIPLATIN acrylate ternary copolymer bound disulfide platinum complex catalyst ENLOPLATIN Dichloro(1,5-cyclooctadiene)platinum(II)

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Potassium tetrachloroplatinate(II) Suppliers

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View Lastest Price from Potassium tetrachloroplatinate(II) manufacturers

HebeiShuoshengImportandExportco.,Ltd

Product: dipotassium tetrachloroplatinate 10025-99-7
Price: US $6.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 2000KG/Month
Release date: 2024-08-09

Hebei Longbang Technology Co., Ltd

Product: dipotassium tetrachloroplatinate 10025-99-7
Price: US $5.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 20TONS
Release date: 2024-05-13

Hebei Zhuanglai Chemical Trading Co.,Ltd

Product: Dipotassium Tetrachloroplatinate 10025-99-7
Price: US $200.00-95.00/kg
Min. Order: 1kg
Purity: 99%
Supply Ability: 20ton
Release date: 2024-04-24

10025-99-7, Potassium tetrachloroplatinate(II)Related Search:

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POTASSIUM TETRACHLOROPLATINATE(+2)

POTASSIUM TETRACHLOROPLATINATE(II)

dipotassium,(sp-4-1)-platinate(2-tetrachloro-

Platinate(2-),tetrachloro-,dipotassium,(SP-4-1)-

Potasiumtetrachloroplatinate(I)

Potasium tetrachloroplatinate

POTASSIUM TETRACHLOROPLATINATE(II): 99.9%

POTASSIUM TETRACHLOROPLATINATE(II): 99.9% (46%PT)

Potassium tetrachloroplatinate(II), Premion(R), 99.99% (metals basis), Pt 46.4% min

Potassium tetrachloroplatinate(II), 99.9% (metals basis), Pt 46.0% min

Potassium tetrachloroplatinate(II), Premion, 99.99% (metals basis), Pt 46.4% min

Dipotassium tetrachloroplatinum

Potassium tetrachloroplatinate(II) ,99.95%

Potassium tetrachloroplatinate(II),Potassium platinum(II) chloride

dipotassium tetrachl

PotassiuM tetrachloroplatinate, (trace Metal basis)

PotassiuM tetrachloroplatinate(II), 46-47% Pt

dipotassium tetrachloroplatinate

1G;5G;100G

PotassiuM tetrachloroplatinate, 99.99%, (trace Metal basis)

POTASSIUM TETRACHLOROPLATINATE(II) 98+

PotassiuM tetrachloroplatinuM

PotassiuM tetrachloroplatinate(Ⅱ), 99.95%

atinate(II)

oropL

Potassium tetrachL

Dipotassium tetrachloroplatinate(II)

Pt46.4%Potassium tetrachloroplatinate(II II)

POTASSIUM TETRACHLOROPLATINATE (II), 99.99%POTASSIUM TETRACHLOROPLATINATE (II), 99.99%POTASSIUM TETRACHLOROPLATINATE (II), 99.99%POTASSIUM TETRACHLOROPLATINATE (II), 99.99%

POTASSIUM TETRACHLOROPLATINATE (II)POTASSIUM TETRACHLOROPLATINATE (II)POTASSIUM TETRACHLOROPLATINATE (II)

potassiumplatinochloride

potassiumplatinum(ii)tetrachloride

potassiumtetrachlorplatinate(ii)

tetrachloro-,dipotassium,(SP-4-1)-Platinate(2-)

tetrachloro-platinate(2-dipotassium

Potassium tetrachloroplatinate(II), 99.9+% metals basis

POTASSIUM TETRACHLOROPLATINATE(II), 99.9 9%

Potassium Tetrachloroplatin (II)-AT

Potassium tetrachloroplatinate(II), 98+% (46% Pt)

POTASSIUM CHLOROPLATINATE GR

Potassium tetrachloroplatinate(Ⅱ)

Potassiumtetrachloroplatinate(II)(99.9%-Pt)

potassium tetrachloroplatinate(ii), premion

POTASSIUM TETRACHLOROPLATINITE (II)

Potassium tetrachloroplatinite

Potassium tetrachloroplatinate(II), 46.5-47.0% Pt