Bromoquinoline Application and synthesis method Uses
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3-Bromoquinoline

Bromoquinoline Application and synthesis method Uses
Product Name
3-Bromoquinoline
CAS No.
5332-24-1
Chemical Name
3-Bromoquinoline
Synonyms
Quinoline, 3-bromo-;NSC 3995;CETH-016;3-BromoquinoL;Bromoquinoline;3-BROMOQUINOLINE;3-BROMOQUINLIINE;3-bromo-quinolin;3-Bromoquuinoline;1-3-Bromoquinoline
CBNumber
CB4220082
Molecular Formula
C9H6BrN
Formula Weight
208.05
MOL File
5332-24-1.mol
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3-Bromoquinoline Property

Melting point:
13-15 °C (lit.)
Boiling point:
274-276 °C (lit.)
Density 
1.533 g/mL at 25 °C (lit.)
vapor pressure 
0.196Pa at 25℃
refractive index 
n20/D 1.664(lit.)
Flash point:
>230 °F
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
pka
2.69(at 25℃)
form 
Liquid
color 
Clear colorless to yellow
Water Solubility 
103mg/L at 25℃
BRN 
112939
InChIKey
ZGIKWINFUGEQEO-UHFFFAOYSA-N
LogP
3.03
CAS DataBase Reference
5332-24-1(CAS DataBase Reference)
NIST Chemistry Reference
Quinoline, 3-bromo-(5332-24-1)
EPA Substance Registry System
Quinoline, 3-bromo- (5332-24-1)
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Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36-37/39
RIDADR 
UN2810
WGK Germany 
3
TSCA 
Yes
HS Code 
29334900
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
124133
Product name
3-Bromoquinoline
Purity
98%
Packaging
25g
Price
$119
Updated
2024/03/01
Sigma-Aldrich
Product number
124133
Product name
3-Bromoquinoline
Purity
98%
Packaging
100g
Price
$319
Updated
2024/03/01
TCI Chemical
Product number
B1013
Product name
3-Bromoquinoline
Purity
>98.0%(GC)(T)
Packaging
25g
Price
$94
Updated
2024/03/01
Alfa Aesar
Product number
A14573
Product name
3-Bromoquinoline, 98%
Packaging
10g
Price
$30.65
Updated
2024/03/01
Alfa Aesar
Product number
A14573
Product name
3-Bromoquinoline, 98%
Packaging
50g
Price
$113.65
Updated
2024/03/01
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3-Bromoquinoline Chemical Properties,Usage,Production

Bromoquinoline

There are seven position isomers with the main properties are as follows:

Name
Melting point(℃)
Boiling point(℃)
Solubility
2-bromoquinoline
48～49
It is soluble in diethyl ether, chloroform and benzene
3-bromoquinoline
12～15
274～276, 95(66.66Pa)
4-bromoquinoline
29～30
270(decomposition)
Easily soluble in dilute acid
5-bromoquinoline
52 (needle crystal)
280
6-bromoquinoline
24
278
7-bromoquinoline
52 (needle crystal)
290
8-bromoquinoline
80
165～166
(2399.79Pa)

Application and synthesis method

3-Bromoquinoline can have action with mixed acid to generate 3-bromo-5-nitroquinoline, followed by heating with potassium permanganate to be oxidized to 5-bromo-2, 3-pyridine dicarboxylic acid.
6-bromo-quinoline can be heated together nitric acid to generate 6-bromo-8-nitro-quinoline, followed by reaction with potassium permanganate to be oxidized into 2, 3-pyridinedicarboxylic acid.
2-bromo-quinoline can be manufactured through the reaction between 2-hydroxyquinoline and phosphorus pentabromide
3-bromo-quinoline can be obtained through heating the quinoline perbromide at 180 ° C.
4-bromoquinoline can be obtained through either the heating reaction between 4-hydroxyquinoline and phosphorus pentabromide or by the diazotization reaction of 4-aminoquinoline.
5-bromo-quinoline can be obtained from the heating reaction between m-bromo aniline, glycerol, m-bromonitrobenzene and concentrated sulfuric acid, or through the diazotization reaction of 5-amino-quinoline.
6-bromo-quinoline can be obtained through the heating reaction between p-bromoaniline, glycerol, concentrated sulfuric acid and p-bromo-nitrobenzene.
7-bromoquinoline can be obtained through the diazotization of 7-aminoquinoline.
8-bromo-quinoline can be obtained through the heating of o-bromo aniline, glycerol, concentrated sulfuric acid and o-bromo-nitrobenzene in the heating system.
Purposes: as organic synthesis reagents.

Uses

For pharmaceuticals
Medicine, pesticide intermediates

Chemical Properties

colorless to light yellow liquid

Synthesis Reference(s)

The Journal of Organic Chemistry, 27, p. 1318, 1962 DOI: 10.1021/jo01051a047

General Description

3-Bromoquinoline undergoes bromine-magnesium exchange reaction with lithium tributylmagnesate in toluene at -10°C, which is quenched by various electrophiles to yield functionalized quinolines.

Flammability and Explosibility

Not classified

3-Bromoquinoline Preparation Products And Raw materials

Raw materials

Preparation Products

5-Aminonicotinic acid 3-Quinolinecarboxaldehyde 3-BROMOQUINOLINE-8-SULFONIC ACID 3-Quinolineboronic acid 3-Aminoquinoline
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Americas 1 Austria 1 Belgium 2 Canada 1 China 292 Europe 3 Germany 8 India 42 Japan 7 Poland 1 Slovakia 1 Switzerland 3 Ukraine 1 United Kingdom 16 United States 47 USA 1 Global 427
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View Lastest Price from 3-Bromoquinoline manufacturers

Shanghai UCHEM Inc.
Product
3-Bromoquinoline 5332-24-1
Price
US $11.00-119.00/g
Min. Order
25g
Purity
0.98
Supply Ability
25kg
Release date
2023-12-14
Henan Aochuang Chemical Co.,Ltd.
Product
3-Bromoquinoline 5332-24-1
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1Ton
Release date
2022-10-12
Hebei Zhanyao Biotechnology Co. Ltd
Product
3-Bromoquinoline 5332-24-1
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
20 Tons
Release date
2021-10-13

5332-24-1, 3-BromoquinolineRelated Search:

6-Hydroxy-2(1H)-3,4-dihydroquinolinone Quinclorac Ethoxyquin Quinhydrone quinolinium hydrogen sulphate Isoquinoline 8-Hydroxyquinoline 3,4-DIBROMOQUINOLINE 2,3-DIBROMOQUINOLINE 4-Amino-3-bromoquinoline 8-BROMOQUINOLINE 2-BROMOQUINOLINE 98% 4-Chloro-7-bromoquinoline 6-BROMO-2(1H)-QUINOLONE 2,4-DIBROMOQUINOLINE 2-BROMOQUINOLINE-3-BORONIC ACID 4-AMINO-7-BROMOQUINOLINE 4-BROMOQUINOLINE,97%

  • 3-bromo-quinolin
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  • 3-Bromoquinoline98%Or99%
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  • 3-BroMoquinoline, 98.0%(GC&T
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  • 3-BromoquinoL
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  • 3-Bromoquinoline ISO 9001：2015 REACH
  • 1-3-Bromoquinoline
  • 3-Bromoquuinoline
  • 5332-24-1
  • C9H6NBr
  • Haloquinolines
  • Quinolines
  • Building Blocks
  • Halogenated Heterocycles
  • Heterocyclic Building Blocks
  • Aromatics Compounds
  • Haloquinolines
  • Aromatics
  • Quinoline&Isoquinoline
  • Quinoline Derivertives
  • Building Blocks
  • Halogenated Heterocycles
  • Heterocyclic Building Blocks
  • QuinolinesHeterocyclic Building Blocks
  • Quinolines, Quinazolines and derivatives
  • Halides
  • Heterocycles
  • blocks
  • Bromides
  • Quinolines