Ethyl benzoylformate
- Product Name
- Ethyl benzoylformate
- CAS No.
- 1603-79-8
- Chemical Name
- Ethyl benzoylformate
- Synonyms
- ETHYL 2-OXO-2-PHENYLACETATE;ETHYL PHENYLGLYOXYLATE;Benzeneacetic acid, .alpha.-oxo-, ethyl ester;Ethyl oxophenyla;RARECHEM AL BI 0384;ETHYL BENZOYLFORMATE;PHENYLETHYLGLYOXYLATE;Ethyloxophenylacetate;Ethyl oxophenylacetate;Ethylα-oxobenzeneacetate
- CBNumber
- CB4299905
- Molecular Formula
- C10H10O3
- Formula Weight
- 178.18
- MOL File
- 1603-79-8.mol
Ethyl benzoylformate Property
- Boiling point:
- 138-139 °C/18 mmHg (lit.)
- Density
- 1.122 g/mL at 25 °C (lit.)
- refractive index
- 1.515-1.517
- Flash point:
- 113 °C
- storage temp.
- Store below +30°C.
- form
- Liquid
- Specific Gravity
- 1.122
- color
- Clear colorless to greenish
- Water Solubility
- Soluble in water 1143 mg/L @ 25°C .
- Sensitive
- Moisture Sensitive
- InChI
- InChI=1S/C10H10O3/c1-2-13-10(12)9(11)8-6-4-3-5-7-8/h3-7H,2H2,1H3
- InChIKey
- QKLCQKPAECHXCQ-UHFFFAOYSA-N
- SMILES
- C1(C=CC=CC=1)C(=O)C(=O)OCC
- LogP
- 1.974 (est)
- CAS DataBase Reference
- 1603-79-8(CAS DataBase Reference)
- NIST Chemistry Reference
- Benzeneacetic acid, «alpha»-oxo-, ethyl ester(1603-79-8)
- EPA Substance Registry System
- Benzeneacetic acid, .alpha.-oxo-, ethyl ester (1603-79-8)
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H227Combustible liquid
H302Harmful if swallowed
H314Causes severe skin burns and eye damage
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P270Do not eat, drink or smoke when using this product.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P363Wash contaminated clothing before reuse.
P370+P378In case of fire: Use … for extinction.
P403+P235Store in a well-ventilated place. Keep cool.
P405Store locked up.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- 258911
- Product name
- Ethyl benzoylformate
- Purity
- 95%
- Packaging
- 5g
- Price
- $31.8
- Updated
- 2024/03/01
- Product number
- 258911
- Product name
- Ethyl benzoylformate
- Purity
- 95%
- Packaging
- 25g
- Price
- $71
- Updated
- 2024/03/01
- Product number
- B0109
- Product name
- Ethyl Benzoylformate
- Purity
- >96.0%(GC)
- Packaging
- 5mL
- Price
- $29
- Updated
- 2024/03/01
- Product number
- B0109
- Product name
- Ethyl Benzoylformate
- Purity
- >96.0%(GC)
- Packaging
- 25mL
- Price
- $76
- Updated
- 2024/03/01
- Product number
- B25292
- Product name
- Ethyl phenylglyoxylate, 98%
- Packaging
- 5g
- Price
- $27.65
- Updated
- 2024/03/01
Ethyl benzoylformate Chemical Properties,Usage,Production
Chemical Properties
clear colorless to greenish liquid
Uses
Ethyl Benzoylformate is a general chemical reagent used in the preparation of diaminoethanediyl bismethylpyridinium salts for designing recyclable organocatalysts.
Application
Ethyl benzoylformate has been used in preparation of 1,5-dihydro-5-deazaflavin derivatives possessing a chiral substituent at N(3) position.
Definition
ChEBI: Ethyl benzoylformate is the ethyl ester of phenylglyoxylic acid. Metabolite observed in cancer metabolism. It has a role as a human metabolite. It derives from a phenylglyoxylic acid.
Synthesis Reference(s)
Journal of the American Chemical Society, 82, p. 918, 1960
The Journal of Organic Chemistry, 50, p. 3573, 1985 DOI: 10.1021/jo00219a025
Tetrahedron Letters, 23, p. 3661, 1982 DOI: 10.1016/S0040-4039(00)88651-7
General Description
Enantioselective hydrogenation of ethyl benzoylformate on Pt/Al2O3 modified with dihydrocinchonidine has been studied.
Ethyl benzoylformate Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from Ethyl benzoylformate manufacturers
- Product
- Ethyl benzoylformate 1603-79-8
- Price
- US $2.00/kg
- Min. Order
- 1kg
- Purity
- 99%
- Supply Ability
- 100kg
- Release date
- 2018-12-24