ChemicalBook > CAS DataBase List > (S)-(-)-1-(1-Naphthyl)ethylamine

(S)-(-)-1-(1-Naphthyl)ethylamine

Product Name
(S)-(-)-1-(1-Naphthyl)ethylamine
CAS No.
10420-89-0
Chemical Name
(S)-(-)-1-(1-Naphthyl)ethylamine
Synonyms
(S)-1-(1-NAPHTHYL)ETHYLAMINE;(S)-1-(NAPHTHALEN-1-YL)ETHANAMINE;Cinacalcet-22;Cinacalcet Impurity 35;Cinacalcet Impurity 73;1-(1-Naphthyl)ethanamine;L-A-(1-NAPHTHYL)ETHYLAMINE;(S) 1-(1-NAPTHYL)ETHYLAMINE;(s)-1-naphthalenemethanamin;(1S)-1-(1-Naphthyl)ethanamine
CBNumber
CB4323198
Molecular Formula
C12H13N
Formula Weight
171.24
MOL File
10420-89-0.mol
More
Less

(S)-(-)-1-(1-Naphthyl)ethylamine Property

Boiling point:
153 °C/11 mmHg (lit.)
alpha 
-60 º (C=2, MEOH)
Density 
1.067 g/mL at 20 °C (lit.)
refractive index 
n20/D 1.623(lit.)
Flash point:
>230 °F
storage temp. 
Keep in dark place,Sealed in dry,Room Temperature
solubility 
Soluble in chloroform, ethanol.
form 
Liquid
pka
9.26±0.40(Predicted)
color 
brown
optical activity
[α]20/D 59°, c = 5 in methanol
Sensitive 
Air Sensitive
BRN 
2208024
InChIKey
RTCUCQWIICFPOD-VIFPVBQESA-N
CAS DataBase Reference
10420-89-0(CAS DataBase Reference)
NIST Chemistry Reference
(S)-(-)-«alpha»-(1-naphthyl)ethylamine(10420-89-0)
EPA Substance Registry System
1-Naphthalenemethanamine, .alpha.-methyl-, (.alpha.S)- (10420-89-0)
More
Less

Safety

Hazard Codes 
Xi
Risk Statements 
36/37/38
Safety Statements 
26-36-37/39
RIDADR 
2735
WGK Germany 
3
RTECS 
QJ6963000
F 
10-34
Hazard Note 
Irritant
TSCA 
Yes
HazardClass 
8
PackingGroup 
II
HS Code 
29214990
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
237450
Product name
(S)-(?)-1-(1-Naphthyl)ethylamine
Purity
≥99%
Packaging
1g
Price
$61
Updated
2024/03/01
Sigma-Aldrich
Product number
237450
Product name
(S)-(?)-1-(1-Naphthyl)ethylamine
Purity
≥99%
Packaging
5g
Price
$122
Updated
2024/03/01
TCI Chemical
Product number
N0481
Product name
(S)-(-)-1-(1-Naphthyl)ethylamine
Purity
>99.0%(GC)
Packaging
1g
Price
$40
Updated
2024/03/01
TCI Chemical
Product number
N0481
Product name
(S)-(-)-1-(1-Naphthyl)ethylamine
Purity
>99.0%(GC)
Packaging
5g
Price
$113
Updated
2024/03/01
Alfa Aesar
Product number
A17176
Product name
(S)-(-)-1-(1-Naphthyl)ethylamine, 99%
Packaging
1g
Price
$26.65
Updated
2024/03/01
More
Less

(S)-(-)-1-(1-Naphthyl)ethylamine Chemical Properties,Usage,Production

Description

(S)-(-)-1-(1-Naphthyl)ethylamine is an organic compound used as a raw material for organic synthesis. Chiral moieties were connected to the heteroatom-bridged calix-triazin scaffold by reactions of (S)- or (R)-(+)-1-(1-Naphthyl)ethylamine with tetraazacalix[4]arene[2]triazine.

Chemical Properties

(S)-(-)-1-(1-Naphthyl)ethylamine Appearance is colourless to light orange to yellow transparent liquid, hygroscopicity, thermal sensitivity. Density: 1.067 g/mL (lit.) at 20 °C; Boiling Point: 125 °C/3 mmHg; Specific Gravity (20/20): 1.07; Refractive Index: 1.62. Store under inert gas.

Uses

(S)-(-)-1-(1-Naphthyl)ethylamine is used in the asymmetric synthesis of α-cyanocarboxylates. Also used in the synthesis of chiral imadazolin-2-ylidene ligands used in organometallic catalysis. Chiral/Asymmetric synthesis.

Uses

Employed in a preparation of a chiral thiourea solvating agent useful for enantiodiscrimination of α-hydroxy and α-amino acids by 1H NMR.

Purification Methods

Purify the amine by distillation in a good vacuum. [Mori et al. Tetrahedron 37 1343 1981, cf Wilson in Topics Stereochem (Allinger and Eliel eds) v o l 6 135 1971, Fredga et al. Acta Chem Scand 11 1609 1957.] The hydrochlorides crystallise from H2O [] D 18 ±3.9o (c 3, H2O), and the sulfates recrystallise from H2O as tetrahydrates m 230-232o. The RS-amine has b 153o/11mm, 156o/15mm, 183.5o/41mm [Blicke & Maxwell J Am Chem Soc 6 1 1780 1939]. [Beilstein 12 III 3111.]

(S)-(-)-1-(1-Naphthyl)ethylamine Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

(S)-(-)-1-(1-Naphthyl)ethylamine Suppliers

Americas 1 Belgium 4 Canada 1 China 228 Europe 2 France 3 Germany 13 India 26 Ireland 1 Italy 1 Japan 8 Norway 1 Singapore 1 Switzerland 3 The Netherlands 1 Ukraine 1 United Kingdom 14 United States 44 Global 353
Accela ChemBio Inc.
Tel
+1(858) 699-3322
Fax
+1(858) 876-1948
Email
marketing@accelachem.com
Country
United States
ProdList
6024
Advantage
65
AbaChemScene
Tel
732-484-9848
Fax
888-484-5008
Email
sales@chemscene.com
Country
United States
ProdList
3982
Advantage
60
Standardpharm Co. Ltd.
Tel
86-714-3992388
Email
overseasales1@yongstandards.com
Country
United States
ProdList
14332
Advantage
58
Alchem Pharmtech,Inc.
Tel
8485655694
Email
sales@alchempharmtech.com
Country
United States
ProdList
63687
Advantage
58
Aladdin Scientific
Tel
+1-+1(833)-552-7181
Email
sales@aladdinsci.com
Country
United States
ProdList
57505
Advantage
58
United States Biological
Tel
--
Fax
--
Email
sales@advtechind.com
Country
United States
ProdList
6075
Advantage
58
CarboMer, Inc.
Tel
--
Fax
--
Email
sales@carbomer.com
Country
United States
ProdList
4026
Advantage
67
Alichem Inc.
Tel
--
Fax
--
Email
sales@alichem.com
Country
United States
ProdList
6167
Advantage
58
Synectic Corporation
Tel
--
Fax
--
Email
sales@synectic-corp.com
Country
United States
ProdList
42
Advantage
58
BASF Corporation (Pharmaceutical)
Tel
--
Fax
--
Country
United States
ProdList
62
Advantage
58
BASF SE
Tel
--
Fax
--
Email
jennifer.moore-braun@basf.com
Country
United States
ProdList
285
Advantage
58
Redox Scientific
Tel
--
Fax
--
Email
info@redoxsci.com
Country
United States
ProdList
2380
Advantage
58
MilliporeSigma (Sigma-Aldrich Corp.)
Tel
--
Fax
--
Email
@sial.com
Country
United States
ProdList
5414
Advantage
58
Oakwood Products, Inc.
Tel
--
Fax
--
Email
sales@oakwoodchemical.com
Country
United States
ProdList
6193
Advantage
74
VWR International, LLC.
Tel
--
Fax
--
Email
@sargentwelch.com
Country
United States
ProdList
6262
Advantage
58
OChem Incorporation
Tel
--
Fax
--
Email
sales@ocheminc.com
Country
United States
ProdList
6501
Advantage
60
TCI America, Inc. (part of Tokyo Chemical Industry)
Tel
--
Fax
--
Email
Angelina.Crew@tcichemicals.com
Country
United States
ProdList
2053
Advantage
58
BroadPharm. Inc.
Tel
--
Fax
--
Email
sales@broadpharm.com
Country
United States
ProdList
891
Advantage
50
SynQuest Laboratories, Inc.
Tel
--
Fax
--
Email
info@synquestlabs.com
Country
United States
ProdList
6871
Advantage
62
Riedel-de Haen AG
Tel
--
Fax
--
Country
United States
ProdList
6773
Advantage
87
TCI America
Tel
--
Fax
--
Email
sales@tciamerica.com
Country
United States
ProdList
6909
Advantage
75
Frontier Scientific, Inc.
Tel
--
Fax
--
Email
sales@frontiersci.com
Country
United States
ProdList
6222
Advantage
86
Matrix Scientific
Tel
--
Fax
--
Email
sales@matrixscientific.com
Country
United States
ProdList
6632
Advantage
80
Cambrex Pharma & Biopharmaceuticals
Tel
--
Fax
--
Email
pharma@cambrex.com
Country
United States
ProdList
261
Advantage
75
Arran Chemical Company
Tel
--
Fax
--
Email
info@arranchemical.ie
Country
United States
ProdList
72
Advantage
0
Anvia Chemicals, LLC
Tel
--
Fax
--
Email
sales@anviachem.com
Country
United States
ProdList
3933
Advantage
0
3B Scientific Corporation
Tel
--
Fax
--
Email
sales@3bsc.com
Country
United States
ProdList
6962
Advantage
56
Waterstone Technology, LLC
Tel
--
Fax
--
Email
sales@waterstonetech.com
Country
United States
ProdList
6786
Advantage
30
Pfaltz & Bauer, Inc.
Tel
--
Fax
--
Email
sales@pfaltzandbauer.com
Country
United States
ProdList
6828
Advantage
72
BASF Corporation
Tel
--
Fax
--
Country
United States
ProdList
573
Advantage
86
The K-Genix Group
Tel
--
Fax
--
Email
export@k-genix.com
Country
United States
ProdList
31
Advantage
64
HONEST JOY HOLDINGS LIMITED
Tel
--
Fax
--
Email
sales@honestjoy.cn
Country
United States
ProdList
6675
Advantage
54
City Chemical LLC
Tel
--
Fax
--
Email
sales@citychemical.com
Country
United States
ProdList
6708
Advantage
72
3B Scientific Corporation
Tel
--
Fax
--
Email
sales@3bsc.com
Country
United States
ProdList
6718
Advantage
47
Chemiplus Corporation
Tel
--
Fax
--
Email
okazaki@chemiplus.com
Country
United States
ProdList
3198
Advantage
38
Norse Laboratories, Inc.
Tel
--
Fax
--
Email
sylvia@norselabs.com
Country
United States
ProdList
105
Advantage
30
Charkit Chemical Corporation
Tel
--
Fax
--
Email
sales@charkit.com
Country
United States
ProdList
2993
Advantage
65
MP Biomedicals, Inc.
Tel
--
Fax
--
Country
United States
ProdList
6561
Advantage
81
Advanced Asymmetrics, Inc.
Tel
--
Fax
--
Email
sales@advancedasymmetrics.com
Country
United States
ProdList
521
Advantage
42
NetChem, Inc.
Tel
--
Fax
--
Email
sales@netchem.com
Country
United States
ProdList
6960
Advantage
51
ASDI Incorporated
Tel
--
Fax
--
Email
customerservice@asdi.net
Country
United States
ProdList
6922
Advantage
67
City Chemicals Corporation
Tel
--
Fax
--
Country
United States
ProdList
6460
Advantage
72
Alfa Aesar
Tel
--
Fax
--
Email
tech@alfa.com
Country
United States
ProdList
6814
Advantage
81
Fisher Scientific
Tel
--
Fax
--
Email
sales@fishersci.com
Country
United States
ProdList
2337
Advantage
86
More
Less

View Lastest Price from (S)-(-)-1-(1-Naphthyl)ethylamine manufacturers

Henan Fengda Chemical Co., Ltd
Product
(S)-(-)-1-(1-Naphthyl)ethylamine 10420-89-0
Price
US $100.00-1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
g-kg-tons, free sample is available
Release date
2023-12-23
Henan Aochuang Chemical Co.,Ltd.
Product
(S)-(-)-1-(1-Naphthyl)ethylamine 10420-89-0
Price
US $0.00-0.00/kg
Min. Order
1kg
Purity
98%
Supply Ability
1Ton
Release date
2022-09-19
Career Henan Chemical Co
Product
(S)-(-)-1-(1-Naphthyl)ethylamine 10420-89-0
Price
US $1.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
200KG
Release date
2018-08-06

10420-89-0, (S)-(-)-1-(1-Naphthyl)ethylamineRelated Search:

Ethylamine L-1-Phenylethylamine Triethylamine hydrochloride Ethambutol Etamsylate 1-(1-NAPHTHYL)-2-THIOUREA Diethylstilbestrol Diethylamine Triethylamine (1R,2R)-(-)-1,2-Diaminocyclohexane (1S,2R)-2-Amino-1,2-diphenylethanol (R)-(+)-1-(1-Naphthyl)ethylamine hydrochloride N-benzyl-1-(1-naphthyl)ethylamine hydrochloride,(R)-(-)-N-BENZYL-1-(1-NAPHTHYL)ETHYLAMINE HYDROCHLORIDE,(R)-N-BENZYL 1-(1-NAPHTHYL)ETHYLAMINE HYDROCHLORIDE 4-(TRIFLUOROMETHYL)HYDROCINNAMIC ACID 1-NAPHTHALEN-2-YL-ETHYLAMINE 3-(Trifluoromethyl)benzaldehyde Methanesulfonic acid 3-(3-trifluoroMethylphenyl)propyl ester 1-(7,8-dihydronaphthalen-1-yl)ethan-1-amine hydrochloride

  • (1S)-1-NAPHTHALEN-1-YLETHANAMINE
  • (S)-(-)-1-(1-Naphthyl)ethylamine, ChiPros 99+%, ee 99+%
  • (S)-(-)-Alpha-(1-naphtyl)ethylamine, 99+%,
  • (-)-1-[(S)-1-Aminoethyl]naphthalene
  • (1S)-1-(1-Naphthyl)ethanamine
  • (S)-α-Methylnaphthalene-1-methanamine
  • (αS)-α-Methylnaphthalene-1-methanamine
  • [S,(-)]-α-Methyl-1-naphthalenemethanamine
  • (S)-(-)-1-(1-NAPHTHYL)ETHYLAMINE: CHIPROS 99%, EE 99%
  • (S)-(-)-1-(1-NAPHTYL)ETHYLAMINE
  • (S)-(-)-1-(1-Naphthyl)ethylamine ,98%
  • (1S)-(-)-1-(Naphth-1-yl)ethylamine
  • 1(S)-(-)-1-(1-Naphthyl)ethylaMine
  • (S)-(-)-alpha-(1-Naphthyl)ethylaMine, 99+% 1GR
  • Cinacalcet Impurity 35
  • 1-[(1S)-1-Aminoethyl]naphthalene
  • (1S)-1-(naphthalen-1-yl)ethan-1-aMine
  • [(1S)-1-(1-naphthalenyl)ethyl]ammonium
  • Cinacalcet-22
  • (S)-1-(napthalen-1-yl)ethanmine
  • L-A-(1-NAPHTHYL)ETHYLAMINE
  • L-ALPHA-(ALPHA-NAPHTHYL)ETHYLAMINE
  • (S)-(-)-1-(1-NAPHTHYL)ETHYLAMINE 99%
  • (S)-(-)-alpha-(1-Naphthyl)ethylamine, 99+%
  • (S)(-)-ALPHA-(1-NAPHTHYL)ETHYLAMINE
  • (S)-(-)-ALPHA-(1-AMINOETHYL)NAPHTHALENE
  • (S)-1-(NAPHTHALEN-1-YL)ETHANAMINE
  • (S)-(-)-1-(1-NAPHTHYL)ETHYLAMINE
  • (S)-1-(1-NAPHTHYL)ETHYLAMINE
  • (S) 1-(1-NAPTHYL)ETHYLAMINE
  • (S)-(-)-A-(1-NAPHTHYL)ETHYLAMINE
  • (S)-(-)-(1-Naphthyl)ethylamine
  • (s)-1-naphthalenemethanamin
  • (S)-alpha-Methyl-1-naphthalenemethanamine
  • 1-(1-Naphthyl)ethanamine
  • 1-Naphthalenemethanamine, alpha-methyl-, (S)-
  • L-alpha-(1-Naphthyl)ethylamine, (-)-
  • S-(-)-1-(alpha-Naphthyl)ethylamine
  • 1-Naphthalenemethanamine, .alpha.-methyl-, (.alpha.S)-
  • (s)-(-)-α-methyl-1-naphthalenemethylamine
  • (S)-(-)-1-(Naphth-1-yl)ethylamine
  • (S)-1-(1-naphthyl)ethylamine,99%e.e.
  • (S)-(-)-1-(1-Naphthyl)ethylamine&gt
  • (S)-(-)-1-(1-Naphthyl)ethylamine, 99%, reagent grade
  • 1-Naphthalenemethanamine, α-methyl-, (αS)-
  • (S)-(-)-1-(1-Naphthyl)ethylamine (Cinacalcet Impurity)
  • Cinacalcet Impurity 73
  • 10420-89-0
  • Amines
  • Analytical Chromatography Product Catalog
  • Asymmetric Synthesis
  • Chiral Derivatization
  • Derivatization Reagents
  • Organic Building Blocks
  • Optical Resolution
  • Enantiomer Excess & Absolute Conefiguration Determination
  • e.e. / Absolute Conefiguration Determination (NMR)
  • Chiral Building Blocks