ChemicalBook > CAS DataBase List > 3-Bromoanisole

3-Bromoanisole

Product Name
3-Bromoanisole
CAS No.
2398-37-0
Chemical Name
3-Bromoanisole
Synonyms
1-BROMO-3-METHOXYBENZENE;META BROMO ANISOLE;M-BROMOANISOLE;3-Methoxybromobenzene;3-Methoxyphenyl bromide;M-Bro;NSC 82293;3-BROMOANISOLE;3-BROMO ANISOL;5-bromoanisole
CBNumber
CB4384971
Molecular Formula
C7H7BrO
Formula Weight
187.03
MOL File
2398-37-0.mol
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3-Bromoanisole Property

Melting point:
2 °C
Boiling point:
210-211 °C(lit.)
Density 
1.490 g/mL at 20 °C
vapor pressure 
38.39Pa at 25℃
refractive index 
n20/D 1.563(lit.)
Flash point:
200 °F
storage temp. 
Sealed in dry,Room Temperature
solubility 
DMSO (Sparingly), Methanol (Slightly)
form 
Liquid
Specific Gravity
1.477
color 
Clear colorless to slightly yellow-brown
PH
5.5 (H2O, 20℃)
Water Solubility 
Miscible in methanol, benzene, hexane, toluene and dichloromethane. Practically insoluble in water.
BRN 
1524687
Stability:
Stable. Combustible. Incompatible with strong oxidising agents, strong acids reducing agents.
InChIKey
PLDWAJLZAAHOGG-UHFFFAOYSA-N
LogP
3.03
CAS DataBase Reference
2398-37-0(CAS DataBase Reference)
NIST Chemistry Reference
Benzene, 1-bromo-3-methoxy-(2398-37-0)
EPA Substance Registry System
m-Bromoanisole (2398-37-0)
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Safety

Hazard Codes 
Xi
Safety Statements 
23-24/25
WGK Germany 
3
F 
8
Hazard Note 
Irritant
TSCA 
T
HS Code 
29093038
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H412Harmful to aquatic life with long lasting effects

Precautionary statements

P273Avoid release to the environment.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
B56498
Product name
3-Bromoanisole
Purity
≥98%
Packaging
25g
Price
$54.8
Updated
2024/03/01
Sigma-Aldrich
Product number
B56498
Product name
3-Bromoanisole
Purity
≥98%
Packaging
100g
Price
$130
Updated
2024/03/01
TCI Chemical
Product number
B0545
Product name
3-Bromoanisole
Purity
>98.0%(GC)
Packaging
25g
Price
$33
Updated
2024/03/01
TCI Chemical
Product number
B0545
Product name
3-Bromoanisole
Purity
>98.0%(GC)
Packaging
250g
Price
$100
Updated
2024/03/01
Alfa Aesar
Product number
A15625
Product name
3-Bromoanisole, 98+%
Packaging
25g
Price
$37.65
Updated
2024/03/01
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3-Bromoanisole Chemical Properties,Usage,Production

Chemical Properties

3-Bromoanisole, also known as m-Bromoanisole, is a clear colorless to pale yellow oily liquid. The boiling point is 210-211°C (100kPa), 105°C (2.13kPa), the relative density is 1.477, the refractive index is 1.5635, and the flash point is 93°C. It is soluble in alcohol, ether, benzene, and carbon disulfide, but insoluble in water. It is commonly used as a raw material for organic synthesis.

Uses

3-Bromoanisole used in chemical reaction as intermediates to obtain target materials such as dyes, pharmaceuticals, perfumes, photoinitiators and agrochemicals.

Preparation

3-Bromoanisole is synthesized through a reaction between m-bromophenol and dimethyl sulfate. The synthesis method involves the following steps:
Dissolve m-bromophenol in a sodium hydroxide solution.
Slowly add dimethyl sulfate dropwise to the solution while stirring.
Heat the mixture and allow it to react for 1 hour.
Cool the reaction mixture to separate the colorless oil formed.
Extract the water layer with ether.
Dry the ether extract and then distill it to recover the ether.
Distill the residue obtained after recovering the ether, along with the colorless oil, under reduced pressure.
This distillation process results in the production of m-bromoanisole as the final product.
The overall yield of m-bromoanisole achieved through this process is 90%.

References

Application of Anisole, 2-Bromoanisole and 3-Bromoanisole as Overcharge Protection Additives in Lithium-Ion Batteries DOI:10.6023/A12110964
S. Ramalingam; S. Periandy. Spectroscopic investigation, computed IR intensity, Raman activity and vibrational frequency analysis on 3-bromoanisole using HF and DFT (LSDA/MPW1PW91) calculations. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. 2011, 78 (2), 835-843. DOI:10.1016/j.saa.2010.12.043
Bobby Glover; Kimberly A. Harvey; Bing Liu; Matthew J. Sharp; and Maria F. Tymoschenko. Regioselective Palladium-Catalyzed Arylation of 3-Carboalkoxy Furan and Thiophene. Org. Lett. 2003, 5 (3), 301-304. DOI:10.1021/ol027266q

3-Bromoanisole Preparation Products And Raw materials

Raw materials

Sodium bromate Benzene Hydrogen Government regulation Methanol Sulfuric acid 3-Bromophenol

Preparation Products

Tramadol hydrochloride 3-Methoxyphenylboronic acid 2-Chloro-5-methoxyphenylboronic acid Tramadol
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View Lastest Price from 3-Bromoanisole manufacturers

Hebei Mujin Biotechnology Co.,Ltd
Product
3-Bromoanisole 2398-37-0
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-09-07
HEBEI SHENGSUAN CHEMICAL INDUSTRY CO.,LTD
Product
3-Bromoanisole 2398-37-0
Price
US $99.00-66.00/kg
Min. Order
0.00100000kg
Purity
99%
Supply Ability
5000
Release date
2024-08-12
HEBEI SHENGSUAN CHEMICAL INDUSTRY CO.,LTD
Product
3-Bromoanisole 2398-37-0
Price
US $999.00-666.00/ton
Min. Order
1ton
Purity
99%
Supply Ability
5000
Release date
2024-08-13

2398-37-0, 3-BromoanisoleRelated Search:

1,2-Dibromobenzene 1,3-Dibromobenzene 2-Bromobenzonitrile 3-Bromobenzonitrile 3-Bromofluorobenzene 3-(Trifluoromethoxy)bromobenzene 3-Bromobenzyl alcohol 3-Nitrobenzyl bromide (3-NITROPHENYL)ACETIC ACID METHYL ESTER 3-Nitroacetophenone 3-Bromobenzyl bromide 3-Nitrobenzaldehyde 1-Bromo-3-iodobenzene 3-Bromobenzaldehyde 3-Bromobenzoic acid Bromine 2-BROMO-4,5-METHYLENEDIOXYCINNAMIC ACID 1-Bromo-3,4,5-trimethoxybenzene

  • M-BROMOANISOLE
  • META BROMO ANISOLE
  • 5-bromoanisole
  • 3-BROMO ANISOL
  • 3-BROMOANISOLE
  • TIMTEC-BB SBB007886
  • BROMOANISOLE(3-)
  • 1-BROMO-3-METHOXYBENZENE
  • 3-Methoxy-1-bromobenzene
  • 3-Methoxybromobenzene
  • 3-Methoxyphenyl bromide
  • Anisole, m-bromo-
  • m-Anisyl bromide
  • m-Bromomethoxybenzene
  • m-Bromophenyl methyl ether
  • 1-bromo-3-methoxy-benzen
  • 1-Bromo-3-methoxybenzene, 3-Bromophenyl methyl ether
  • BroMobenzene between Methyl ether
  • M-BROMO ANISOLE (3-BROMO ANISOLE)
  • 3-Bromoanisole≥ 99.5% (GC)
  • m-bromonisole(3-bromoanisole)
  • M-Bromoanisole (3-Bromoanisole) 99.5%
  • m-BROMOANISOLE pure
  • 3-Bromoanisole,1-Bromo-3-methoxybenzene
  • m-Bromoanisole 1g [2398-37-0]
  • 3-BromoanisoleDISC 05/08/02
  • m-bromoanisole(MBA)
  • 3-BROMOANISOLE, 98+%
  • 3-Bromoanisole99%
  • 3-BROMO ANISOLE FOR SYNTHESIS
  • NSC 82293
  • Benzene, 1-bromo-3-methoxy-
  • m-Bromophenyl methyl ethe
  • m-Bromophenylmethylether
  • m-Methoxybromobenzene
  • m-Methoxyphenyl bromide
  • m-Bromoanisoles
  • 3-BroMoanisole, 99+% 100ML
  • 3-BroMoanisole, 99+% 25ML
  • M-Bro
  • 3-Bromoanisole &gt
  • 3-Bromoanisole ISO 9001：2015 REACH
  • Meta Bromo Anisole (3-Bromo Anisole)
  • Meta Bromo Anisole (MBA)
  • 3-Bromoanisole pure, 98%
  • 1-Bromo-3-Methoxybenzene 3-Bromoanisole
  • M-bromophenyl ether
  • 3-Bromoanisole 98% For Synthesis
  • 3-Bromoanisol in isopropanol
  • Meta bromobenzyl ether
  • Phloroglucinol Impurity 242
  • 2398-37-0
  • 2938-37-0
  • 2398-38-0
  • ARYL HALIDE
  • Ethers
  • Organic Building Blocks
  • Oxygen Compounds