ChemicalBook > CAS DataBase List > 2,4-Dihydroxyacetophenone
2,4-Dihydroxyacetophenone
- Product Name
- 2,4-Dihydroxyacetophenone
- CAS No.
- 89-84-9
- Chemical Name
- 2,4-Dihydroxyacetophenone
- Synonyms
- 1-(2,4-dihydroxyphenyl)ethanone;Ethanone, 1-(2,4-dihydroxyphenyl)-;RESACETOPHENONE;2,4-DHAP;HyMechroMone;NSC 37559;NSC 10883;AKOS 90593;Resoacetophenone;4-Acetoresorcinol
- CBNumber
- CB4391766
- Molecular Formula
- C8H8O3
- Formula Weight
- 152.15
- MOL File
- 89-84-9.mol
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2,4-Dihydroxyacetophenone Property
- Melting point:
- 143-144.5 °C(lit.)
- Boiling point:
- 234.6°C (rough estimate)
- Density
- 1.18 g/mL at 25 °C(lit.)
- refractive index
- 1.4945 (estimate)
- storage temp.
- Inert atmosphere,Room Temperature
- solubility
- DMSO (Slightly), Methanol (Slightly)
- pka
- 7.96±0.18(Predicted)
- form
- Crystalline Powder or Crystals
- color
- Off-white to pink to brown
- PH
- 5 (1g/l, H2O, 20℃)
- Sensitive
- Moisture Sensitive
- Merck
- 14,8140
- BRN
- 1282505
- InChIKey
- SULYEHHGGXARJS-UHFFFAOYSA-N
- LogP
- 1.480 (est)
- CAS DataBase Reference
- 89-84-9(CAS DataBase Reference)
- NIST Chemistry Reference
- Ethanone, 1-(2,4-dihydroxyphenyl)-(89-84-9)
- EPA Substance Registry System
- Ethanone, 1-(2,4-dihydroxyphenyl)- (89-84-9)
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Safety
- Hazard Codes
- Xi
- Risk Statements
- 36/37/38
- Safety Statements
- 26-36-24/25
- WGK Germany
- 2
- RTECS
- AM7525000
- Hazard Note
- Irritant
- TSCA
- Yes
- HS Code
- 29145000
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Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H319Causes serious eye irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P337+P313IF eye irritation persists: Get medical advice/attention.
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N-Bromosuccinimide Price
Sigma-Aldrich
- Product number
- D107409
- Product name
- 2′,4′-Dihydroxyacetophenone
- Purity
- 99%
- Packaging
- 100g
- Price
- $93.9
- Updated
- 2024/03/01
Sigma-Aldrich
- Product number
- D107409
- Product name
- 2′,4′-Dihydroxyacetophenone
- Purity
- 99%
- Packaging
- 500g
- Price
- $110.4
- Updated
- 2024/03/01
TCI Chemical
- Product number
- D0561
- Product name
- 2',4'-Dihydroxyacetophenone
- Purity
- >98.0%(GC)(T)
- Packaging
- 25g
- Price
- $47
- Updated
- 2024/03/01
TCI Chemical
- Product number
- D0561
- Product name
- 2',4'-Dihydroxyacetophenone
- Purity
- >98.0%(GC)(T)
- Packaging
- 100g
- Price
- $120
- Updated
- 2024/03/01
Alfa Aesar
- Product number
- A12066
- Product name
- 2',4'-Dihydroxyacetophenone, 98%
- Packaging
- 50g
- Price
- $37.65
- Updated
- 2024/03/01
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2,4-Dihydroxyacetophenone Chemical Properties,Usage,Production
Chemical Properties
2,4-Dihydroxyacetophenone appears as a yellow-brown to reddish-brown fine crystalline powder. It slowly decomposes in water and can dissolve in hot alcohol, pyridine, and glacial acetic acid. In contrast, it is nearly insoluble in ether, benzene, and chloroform. A reaction with iron chloride causes it to adopt a red hue.
Uses
2,4-Dihydroxyacetophenone (cas# 89-84-9) is a compound useful in organic synthesis. It is also used as intermediate for pharmaceuticals. Reagent for iron as a 10% alcoholic solution. A red color is obtained with ferric ions in slightly acid solution: Cooper, Ind. Eng. Chem. Anal. Ed. 9, 334 (1937).
Definition
ChEBI: 2',4'-dihydroxyacetophenone is a dihydroxyacetophenone that is acetophenone carrying hydroxy substituents at positions 2' and 4'. It has a role as a plant metabolite. It is a member of resorcinols and a dihydroxyacetophenone.
Preparation
Preparation by reaction of acetic acid on resorcinol,
with zinc chloride (Nencki reaction) (94%)
with boron trifluoride
with Amberlite IR-120 (a cation exchange resin, sulfonic acid type) (87%)
with polyphosphoric acid (63%)
with 70% perchloric acid (33%).
Synthesis Reference(s)
Journal of the American Chemical Society, 70, p. 428, 1948 DOI: 10.1021/ja01181a521
Safety Profile
Moderately toxic by ingestion. Experimental reproductive effects. A severe eye irritant. When heated to decomposition it emits acrid smoke and irritating fumes.
Synthesis
2,4-Dihydroxyacetophenone is obtained by the acetylation of resorcinol and acetic acid. In addition, it can also be obtained by reacting resorcinol with chloroacetyl or acetic anhydride in the presence of zinc chloride.
target
Phospholipase (e.g. PLA)
2,4-Dihydroxyacetophenone Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 2,4-Dihydroxyacetophenone manufacturers
Ouhuang Engineering Materials (Hubei) Co., Ltd
- Product
- 4-Acetylresorcinol 89-84-9
- Price
- US $10.00/kg
- Min. Order
- 1kg
- Purity
- 99.6%
- Supply Ability
- 100000
- Release date
- 2024-04-22
Xiamen Work-For-World Medicine Co.,Ltd.
- Product
- 2,4-Dihydroxyacetophenone 89-84-9
- Price
- US $1.00-1.00/kg
- Min. Order
- 1kg
- Purity
- 99%HPLC
- Supply Ability
- kg
- Release date
- 2024-03-27
Hebei Yanxi Chemical Co., Ltd.
- Product
- 2,4-Dihydroxyacetophenone 89-84-9
- Price
- US $20.00-1.00/kg
- Min. Order
- 1kg
- Purity
- 0.99
- Supply Ability
- 10 tons
- Release date
- 2023-11-06
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