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Ethyl 4-bromophenylacetate

Product Name
Ethyl 4-bromophenylacetate
CAS No.
14062-25-0
Chemical Name
Ethyl 4-bromophenylacetate
Synonyms
ethyl 2-(4-broMophenyl)acetate;4-bromophenylacetic acid ethyl ester;4-broMoethyl acetate;ETHYL 4-BROMOPHENYLACETATE;ETHYL P-BROMOPHENYLACETATE;2-(4-bromophenyl)butanoate;Ethyl4-Bromophenylacetate>Ethyl 4-bromophenylacetate,99%;Ethyl 4-bromophenylacetate 99%;Ethyl 4-bromophenylacetate ,97%
CBNumber
CB5109173
Molecular Formula
C10H11BrO2
Formula Weight
243.1
MOL File
14062-25-0.mol
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Ethyl 4-bromophenylacetate Property

Melting point:
29-33 °C(lit.)
Boiling point:
88-90°C 0,35mm
Density 
1.389±0.06 g/cm3(Predicted)
Flash point:
>230 °F
storage temp. 
Sealed in dry,Room Temperature
form 
Liquid or Low Melting Solid
color 
Clear colorless to pale yellow
InChI
InChI=1S/C10H11BrO2/c1-2-13-10(12)7-8-3-5-9(11)6-4-8/h3-6H,2,7H2,1H3
InChIKey
ZFDCWHPNBWPPHG-UHFFFAOYSA-N
SMILES
C1(CC(OCC)=O)=CC=C(Br)C=C1
CAS DataBase Reference
14062-25-0(CAS DataBase Reference)
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Safety

Hazard Codes 
Xn,Xi
Risk Statements 
22
Safety Statements 
36
WGK Germany 
3
Hazard Note 
Irritant
HS Code 
29163990
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
631353
Product name
Ethyl 4-bromophenylacetate
Purity
97%
Packaging
5g
Price
$34.05
Updated
2025/07/31
Sigma-Aldrich
Product number
631353
Product name
Ethyl 4-bromophenylacetate
Purity
97%
Packaging
25g
Price
$70.8
Updated
2025/07/31
TCI Chemical
Product number
E0903
Product name
Ethyl 4-Bromophenylacetate
Purity
>98.0%(GC)
Packaging
5g
Price
$23
Updated
2025/07/31
TCI Chemical
Product number
E0903
Product name
Ethyl 4-Bromophenylacetate
Purity
>98.0%(GC)
Packaging
25g
Price
$58
Updated
2025/07/31
TRC
Product number
B680110
Product name
4-Bromo-benzeneaceticAcidEthylEster
Packaging
1g
Price
$50
Updated
2021/12/16
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Ethyl 4-bromophenylacetate Chemical Properties,Usage,Production

Chemical Properties

Clear colorless to pale yellow liquid

Uses

4-Bromo-benzeneacetic Acid Ethyl Ester is used to prepare highly selective and orally active Lysophosphatidic Acid (LPA) receptor-1 antagonists with potent activity on human lung fibroblasts.

Synthesis

64-17-5

1878-68-8

14062-25-0

Preparation of the intermediate 1-bromo-4-(2-methoxy-2-methyldienyl)benzene (1AG-1): 2-(4-bromophenyl)acetic acid (75 g, 340 mmol) was suspended in ethanol (341 mL). Concentrated sulfuric acid (0.682 mL, 12.79 mmol) was added slowly and the reaction mixture was subsequently heated to reflux and maintained for 24 hours. Upon completion of the reaction, the mixture was concentrated to remove the solvent. The residue was diluted with ether and saturated sodium bicarbonate solution for acid-base neutralization. The organic and aqueous layers were carefully separated and the organic layer was subsequently washed with brine and dried over sodium sulfate. The dried organic phase was filtered and the filtrate was concentrated to give ethyl 2-(4-bromophenyl)acetate (80.2 g, 97% yield) as an off-white solid.

References

[1] Patent: WO2010/86820, 2010, A1. Location in patent: Page/Page column 53
[2] Journal of Medicinal Chemistry, 2008, vol. 51, # 21, p. 6665 - 6681
[3] Patent: US2013/79320, 2013, A1. Location in patent: Paragraph 0473; 0474
[4] Patent: WO2013/45451, 2013, A1. Location in patent: Paragraph 51
[5] European Journal of Medicinal Chemistry, 2014, vol. 86, p. 714 - 723

Ethyl 4-bromophenylacetate Preparation Products And Raw materials

Raw materials

Ethanol 4-Bromophenylacetic acid Sulfuric acid

Preparation Products

ETHYL 4-ACETYLBENZOATE
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Ethyl 4-bromophenylacetate Suppliers

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View Lastest Price from Ethyl 4-bromophenylacetate manufacturers

Hebei Chuanghai Biotechnology Co., Ltd
Product
Ethyl 4-bromophenylacetate 14062-25-0
Price
US $0.00-0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
500000kg
Release date
2024-11-04
Honest Joy Holdings Limited
Product
Ethyl 4-bromophenylacetate 14062-25-0
Price
US $0.00/KG
Min. Order
1KG
Purity
99.1%
Supply Ability
100 tons
Release date
2022-01-26
Career Henan Chemical Co
Product
Ethyl 4-bromophenylacetate 14062-25-0
Price
US $1.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
150KG
Release date
2019-07-09

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