2-(4-BROMOPHENYL)PROPAN-2-OL
- Product Name
- 2-(4-BROMOPHENYL)PROPAN-2-OL
- CAS No.
- 2077-19-2
- Chemical Name
- 2-(4-BROMOPHENYL)PROPAN-2-OL
- Synonyms
- p-Bromocumyl alcohol;2-(4-BroMophenyl)-2-propanol;2-(4-BROMOPHENYL)PROPAN-2-OL;4-Bromophenyldimethylcarbinol;2-(4-Bromophenyl)-2-propanol,98%;Benzenemethanol, 4-bromo-α,α-dimethyl-;4-Bromo-alpha,alpha-dimethylbenzyl Alcohol;p-Bromo-alpha,alpha-dimethylbenzyl alcohol
- CBNumber
- CB52467765
- Molecular Formula
- C9H11BrO
- Formula Weight
- 215.09
- MOL File
- 2077-19-2.mol
2-(4-BROMOPHENYL)PROPAN-2-OL Property
- Melting point:
- 45.6℃
- Boiling point:
- 75-85℃ /0.1mm
- Density
- 1.356
- refractive index
- 1.5520
- storage temp.
- Sealed in dry,Room Temperature
- form
- Solid
- pka
- 14.29±0.29(Predicted)
- color
- White
- Water Solubility
- Slightly soluble in water (1.4 g/L) (25°C)
Safety
- HS Code
- 2905599890
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P321Specific treatment (see … on this label).
P332+P313IF SKIN irritation occurs: Get medical advice/attention.
P362Take off contaminated clothing and wash before reuse.
N-Bromosuccinimide Price
- Product number
- B5274
- Product name
- 2-(4-Bromophenyl)-2-propanol
- Purity
- >98.0%(GC)
- Packaging
- 1g
- Price
- $120
- Updated
- 2025/07/31
- Product number
- B5274
- Product name
- 2-(4-Bromophenyl)-2-propanol
- Purity
- >98.0%(GC)
- Packaging
- 5g
- Price
- $359
- Updated
- 2025/07/31
- Product number
- B698528
- Product name
- 2-(4-Bromophenyl)-2-propanol
- Packaging
- 100mg
- Price
- $65
- Updated
- 2021/12/16
- Product number
- B698528
- Product name
- 2-(4-Bromophenyl)-2-propanol
- Packaging
- 250mg
- Price
- $75
- Updated
- 2021/12/16
- Product number
- FB143935
- Product name
- 2-(4-Bromophenyl)propan-2-ol
- Packaging
- 2g
- Price
- $225
- Updated
- 2021/12/16
2-(4-BROMOPHENYL)PROPAN-2-OL Chemical Properties,Usage,Production
Uses
It is an important raw material and intermediate used in organic synthesis, pharmaceuticals, agrochemicals and dyestuffs. It is a medicine intermediate.
Synthesis
75-16-1
99-90-1
2077-19-2
1. 1-(4-Bromophenyl)ethanone (9.25 g, 46.5 mmol) was dissolved in tetrahydrofuran (200 mL). 2. The reaction system was cooled at -50 °C in a low temperature bath. 3. An ether solution of methylmagnesium bromide (3 M, 46.5 mL, 139 mmol) was added slowly and dropwise over 15 minutes. 4. After the dropwise addition, the reaction system was allowed to warm gradually to room temperature and stirring was continued for 20 hours. 5. Upon completion of the reaction, the reaction was quenched with saturated aqueous ammonium chloride solution. 6. The reaction mixture was extracted with ethyl acetate and the organic phases were combined. 7. The organic phase was dried with anhydrous magnesium sulfate, filtered and concentrated under reduced pressure to obtain the crude product as an oil. 8. The crude product was purified by silica gel column chromatography (eluent: 0-20% ethyl acetate/hexane gradient elution) to afford the target product 2-hydroxy-2-(4-bromophenyl)propane (9.1 g, 46.2 mmol, 91% yield). 9. The product was identified by mass spectrometry (MS). 9. The product was characterized by mass spectrometry (ESI): m/z 197.1 [M]? , 199.1 [M+2]?
References
[1] Journal of Medicinal Chemistry, 1995, vol. 38, # 17, p. 3368 - 3383
[2] Patent: WO2010/62571, 2010, A1. Location in patent: Page/Page column 92
[3] Journal of the Chemical Society - Perkin Transactions 1, 1997, # 15, p. 2169 - 2174
[4] Journal of the American Chemical Society, 1971, vol. 93, p. 6877 - 6887
[5] Journal of the American Chemical Society, 1999, vol. 121, # 14, p. 3557 - 3558
2-(4-BROMOPHENYL)PROPAN-2-OL Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 2-(4-BROMOPHENYL)PROPAN-2-OL manufacturers
- Product
- 2-(4-BROMOPHENYL)PROPAN-2-OL 2077-19-2
- Price
- US $101.00-1.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- g-kg-tons, free sample is available
- Release date
- 2023-12-28
- Product
- 2-(4-BROMOPHENYL)PROPAN-2-OL 2077-19-2
- Price
- US $2.00/KG
- Min. Order
- 1g
- Purity
- 98%MIN
- Supply Ability
- ASK
- Release date
- 2020-01-07