3,4-Dihydro-2H-pyran
- Product Name
- 3,4-Dihydro-2H-pyran
- CAS No.
- 110-87-2
- Chemical Name
- 3,4-Dihydro-2H-pyran
- Synonyms
- DHP;DIHYDROPYRAN;3,4-DIHYDROPYRAN;DIHYDROPYRANE;Pyran, dihydro-;dihydro-2H-pyran;3,4-Dihydro-2-pyran;3,4-dihydro-2h-pyra;2,3-DIHYDRO-4H-PYRAN;3,4-Dihydro-2H-pyrane
- CBNumber
- CB5324066
- Molecular Formula
- C5H8O
- Formula Weight
- 84.12
- MOL File
- 110-87-2.mol
3,4-Dihydro-2H-pyran Property
- Melting point:
- -70 °C (lit.)
- Boiling point:
- 86 °C (lit.)
- Density
- 0.922 g/mL at 25 °C (lit.)
- vapor density
- 2.9 (vs air)
- vapor pressure
- 77.8 hPa (20 °C)
- refractive index
- n20/D 1.440(lit.)
- Flash point:
- 4 °F
- storage temp.
- Store below +30°C.
- solubility
- 7.7g/l
- form
- Liquid
- color
- Clear colorless to yellow
- PH
- 7 (5g/l, H2O, 20℃)
- explosive limit
- 1.1-13.8%(V)
- Water Solubility
- 20 g/L (20 ºC)
- BRN
- 103493
- Stability:
- Volatile
- InChIKey
- BUDQDWGNQVEFAC-UHFFFAOYSA-N
- LogP
- 0.690
- CAS DataBase Reference
- 110-87-2(CAS DataBase Reference)
- NIST Chemistry Reference
- 2H-Pyran, 3,4-dihydro-(110-87-2)
- EPA Substance Registry System
- 2H-Pyran, 3,4-dihydro- (110-87-2)
Safety
- Hazard Codes
- F,Xi
- Risk Statements
- 11-36/37/38-36/38-19
- Safety Statements
- 16-26-36-37/39-33-7/9
- RIDADR
- UN 2376 3/PG 2
- WGK Germany
- 3
- RTECS
- UP7700000
- Autoignition Temperature
- 240 °C
- Hazard Note
- Highly Flammable/Irritant
- TSCA
- Yes
- HazardClass
- 3
- PackingGroup
- II
- HS Code
- 29329995
- Toxicity
- LD50 orally in Rabbit: > 4000 mg/kg
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Danger
- Hazard statements
-
H225Highly Flammable liquid and vapour
H315Causes skin irritation
H317May cause an allergic skin reaction
H319Causes serious eye irritation
H412Harmful to aquatic life with long lasting effects
- Precautionary statements
-
P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233Keep container tightly closed.
P273Avoid release to the environment.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
N-Bromosuccinimide Price
- Product number
- D106208
- Product name
- 3,4-Dihydro-2H-pyran
- Purity
- 97%
- Packaging
- 100ml
- Price
- $35.6
- Updated
- 2024/03/01
- Product number
- D106208
- Product name
- 3,4-Dihydro-2H-pyran
- Purity
- 97%
- Packaging
- 500ml
- Price
- $121
- Updated
- 2024/03/01
- Product number
- 8.02971
- Product name
- 3,4-Dihydro-2H-pyran
- Purity
- for synthesis
- Packaging
- 100mL
- Price
- $39.4
- Updated
- 2024/03/01
- Product number
- 8.02971
- Product name
- 3,4-Dihydro-2H-pyran
- Purity
- for synthesis
- Packaging
- 250ML
- Price
- $84
- Updated
- 2024/03/01
- Product number
- D0555
- Product name
- 3,4-Dihydro-2H-pyran
- Purity
- >97.0%(GC)
- Packaging
- 25mL
- Price
- $21
- Updated
- 2024/03/01
3,4-Dihydro-2H-pyran Chemical Properties,Usage,Production
Chemical Properties
colorless to light yellow liqui
Uses
Widely used hydroxyl-protecting reagent3,4-Dihydro-2H-pyran is used as a hydroxyl-protecting reagent in organic synthesis. It acts as an intermediate in synthetic chemistry. It is used to protect various reactive functional groups. It is involved in the polymerization reaction either alone or with unsaturated compound and finds application in polymer industries. Further, it is employed in the preparation of bicyclic compounds of epoxide-fused, halo compounds and allenic alcohols.
Flammability and Explosibility
Flammable
Safety Profile
A flammable and very dangerous fire hazard when exposed to heat or flame; can react vigorously with oxidzing materials. Keep away from heat and open flame. To fight fire, use alcohol foam, CO2, or dry chemical. When heated to decomposition it emits acrid smoke and irritating
Purification Methods
Partially dry dihydropyran with Na2CO3, then fractionally distil it. The fraction b 84-85o is refluxed with Na until hydrogen no longer evolves when fresh Na is added. It is then dried, and distilled again through a 60 x 1.2cm column packed with glass rings [Brandon et al. J Am Chem Soc 72 2120 1950, UV: Elington et al. J Chem Soc 2873 1952, NMR: Bushweller & O'Neil Tetrahedron Lett 4713 1969]. It has been characterised as the 3,5-dinitrobenzoyloxy-tetrahydrofuran derivative, m 103o which forms pale yellow crystals from dihydropyran/Et2O [Woods & Kramer J Am Chem Soc 69 2246 1947]. [Beilstein 17/1 V 181.]
3,4-Dihydro-2H-pyran Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 3,4-Dihydro-2H-pyran manufacturers
- Product
- 3,4-Dihydro-2H-pyran 110-87-2
- Price
- US $0.00/KG
- Min. Order
- 1KG
- Purity
- 99%
- Supply Ability
- 500000kg
- Release date
- 2024-10-28
- Product
- 3,4-Dihydro-2H-pyran 110-87-2
- Price
- US $10.00-1.00/kg
- Min. Order
- 1kg
- Purity
- 0.99
- Supply Ability
- 10 tons
- Release date
- 2023-09-12
- Product
- 3,4-Dihydro-2H-pyran 110-87-2
- Price
- US $10.00/KG
- Min. Order
- 1KG
- Purity
- 99.%
- Supply Ability
- 10 ton
- Release date
- 2024-08-23