ChemicalBook > CAS DataBase List > Ethyl p-nitrobenzoate

Ethyl p-nitrobenzoate

Product Name: Ethyl p-nitrobenzoate
CAS No.: 99-77-4
Chemical Name: Ethyl p-nitrobenzoate
Synonyms: ETHYL 4-NITROBENZOATE;PNBA-ME;4-(ethoxycarbonyl)nitrobenzene;AKOS B029802;Benzocaine Impurity;RARECHEM AL BI 0193;Ethyl p-nitrobenzoat;ETHYL P-NITROBENZOATE;Ethyl4-Nitrobenzoate>4-Nitrobenzoicacidester
CBNumber: CB5339776
Molecular Formula: C9H9NO4
Formula Weight: 195.17
MOL File: 99-77-4.mol

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Ethyl p-nitrobenzoate Property

Melting point:: 55-59 °C (lit.)
Boiling point:: 182 °C
Density: 1.3544 (rough estimate)
refractive index: 1.5700 (estimate)
storage temp.: 2-8°C
solubility: Chloroform (Slightly), Ethyl Acetate (Slightly)
form: Crystalline Powder
color: Yellow
Merck: 14,3832
BRN: 1912879
InChI: InChI=1S/C9H9NO4/c1-2-14-9(11)7-3-5-8(6-4-7)10(12)13/h3-6H,2H2,1H3
InChIKey: PHWSCBWNPZDYRI-UHFFFAOYSA-N
SMILES: C(OCC)(=O)C1=CC=C([N+]([O-])=O)C=C1
CAS DataBase Reference: 99-77-4(CAS DataBase Reference)
NIST Chemistry Reference: Ethyl 4-nitrobenzoate(99-77-4)
EPA Substance Registry System: Ethyl 4-nitrobenzoate (99-77-4)

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Safety

Risk Statements: 33
Safety Statements: 22-24/25
WGK Germany: 3
RTECS: DH5600000
TSCA: Yes
HS Code: 29163990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H303May be harmfulif swallowed

Precautionary statements

P270Do not eat, drink or smoke when using this product.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P403Store in a well-ventilated place.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: PHR2225
Product name: Ethyl 4-Nitrobenzoate
Purity: Pharmaceutical Secondary Standard; Certified Reference Material
Packaging: 100MG
Price: $386
Updated: 2025/07/31

Sigma-Aldrich

Product number: 72940
Product name: Ethyl 4-nitrobenzoate
Purity: ≥98.0% (GC)
Packaging: 100g
Price: $57.9
Updated: 2025/07/31

Sigma-Aldrich

Product number: 1265300
Product name: Ethyl 4-nitrobenzoate
Purity: United States Pharmacopeia (USP) Reference Standard
Packaging: 40mg
Price: $1180
Updated: 2025/07/31

TCI Chemical

Product number: N0485
Product name: Ethyl 4-Nitrobenzoate
Purity: >98.0%(GC)
Packaging: 25g
Price: $41
Updated: 2025/07/31

TRC

Product number: E937558
Product name: Ethyl 4-nitrobenzoate
Packaging: 10g
Price: $60
Updated: 2021/12/16

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Ethyl p-nitrobenzoate Chemical Properties,Usage,Production

Chemical Properties

yellow crystalline powder

Uses

Ethyl 4-Nitrobenzoate is used in preparation of p-dimethylaminobenzoate compounds.

General Description

Pharmaceutical secondary standards for application in quality control provide pharma laboratories and manufacturers with a convenient and cost-effective alternative to the preparation of in-house working standards

Purification Methods

Dissolve it in Et2O and wash it with aqueous alkali, then the ether is evaporated and the solid recrystallised from EtOH. [Beilstein 13 H 3787, 13 IV 1074.]

Ethyl p-nitrobenzoate Preparation Products And Raw materials

Raw materials

4-Nitrobenzoic acid

Preparation Products

Benzocaine

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View Lastest Price from Ethyl p-nitrobenzoate manufacturers

Henan Fengda Chemical Co., Ltd

Product: Ethyl p-nitrobenzoate 99-77-4
Price: US $100.00-1.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: g-kg-tons, free sample is available
Release date: 2023-12-25

Hong Kong Tiansheng New Material Trading Co., Ltd

Product: Ethyl 4-nitrobenzoate 99-77-4
Price: US $12.80/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 1000tons
Release date: 2021-12-28

Hong Kong Tiansheng New Material Trading Co., Ltd

Product: Ethyl 4-nitrobenzoate 99-77-4
Price: US $15.00/Kg/Bag
Min. Order: 1Kg/Bag
Purity: 99%
Supply Ability: 10TONS
Release date: 2022-01-10

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O2NC6H4CO2C2H5

Organic Building Blocks

Esters

Building Blocks

Carbonyl Compounds

C8 to C9

FINE Chemical & INTERMEDIATES

Aromatic Esters

C8 to C9

Carbonyl Compounds

Esters