Chlorimuron-ethyl

Description References

Product Name: Chlorimuron-ethyl
CAS No.: 90982-32-4
Chemical Name: Chlorimuron-ethyl
Synonyms: DARBAN;CLASSIC;HIT 25VP;DPX-F6025;Classic[R];classic 75df;Chlorimuron Et;Chlorimuron W.P.;CHLORIMURON-ETHYL;Chlorsulfuron-ethyl
CBNumber: CB5421938
Molecular Formula: C15H15ClN4O6S
Formula Weight: 414.82
MOL File: 90982-32-4.mol

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Chlorimuron-ethyl Property

Melting point:: 180-182°C
Density: 1.4727 (rough estimate)
refractive index: 1.6100 (estimate)
storage temp.: Inert atmosphere,2-8°C
solubility: Freely soluble in aqueous solution
pka: 3.78±0.10(Predicted)
form: Solid
color: White to Light Yellow
Water Solubility: 1.018mg/L(temperature not stated)
Stability:: Unstable in DMSO solution
InChIKey: NSWAMPCUPHPTTC-UHFFFAOYSA-N
CAS DataBase Reference: 90982-32-4(CAS DataBase Reference)
EPA Substance Registry System: Chlorimuron-ethyl (90982-32-4)

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Safety

Hazard Codes: Xi
Risk Statements: 36
Safety Statements: 26-36
RIDADR: UN3077 (solid)
RTECS: DG5095000
Hazardous Substances Data: 90982-32-4(Hazardous Substances Data)
Toxicity: LD50 in male, female rats (mg/kg): 4102, 4236 orally (Claus)

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H303May be harmfulif swallowed

H313May be harmful in contact with skin

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

Alfa Aesar

Product number: J66605
Product name: Chlorimuron ethyl, 95%
Packaging: 1g
Price: $31.1
Updated: 2024/03/01

Alfa Aesar

Product number: J66605
Product name: Chlorimuron ethyl, 95%
Packaging: 5g
Price: $93.1
Updated: 2024/03/01

Alfa Aesar

Product number: J66605
Product name: Chlorimuron ethyl, 95%
Packaging: 25g
Price: $230
Updated: 2021/12/16

TRC

Product number: C371273
Product name: Chlorimuron-ethyl
Packaging: 100mg
Price: $50
Updated: 2021/12/16

Matrix Scientific

Product number: 099400
Product name: Ethyl 2-(N-((4-chloro-6-methoxypyrimidin-2-yl)carbamoyl)sulfamoyl)benzoate
Purity: 95+%
Packaging: 10g
Price: $60
Updated: 2021/12/16

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Chlorimuron-ethyl Chemical Properties,Usage,Production

Description

Chlorimuron-ethyl is a kind of post-emergence, foliar applied herbicide which is used without the EU regulatory approval. As an herbicide belonging to the sulfonylurea family, it is commonly used to control the weeds associated with wheat, rice, soybean, barley, potato, and corn. It has advantages of being broad-spectrum, having low use rate, having good crop selectivity as well as being of low toxicity to animals. Its mechanism of action is through suppressing the plant- and microbial-specific enzyme acetolactate synthase (ALS), further blocking the biosynthesis of branched-chain amino acids such as valine, leucine and isoleucine. Through this mechanism, it cause rapid cessation of plant cell division and growth.

References

http://sitem.herts.ac.uk/aeru/ppdb/en/Reports/1145.htm
http://lfse.iae.ac.cn/Article/UploadFiles/201310/2013102910313432.pdf

Chemical Properties

Colorless to off white or pale yellow crystals or powder. Some formulations are listed as “flammable” in the literature. Odorless.

Uses

Chlorimuron-ethyl is used in weed control method as herbicide.

Uses

Herbicide.

Definition

ChEBI: Chlorimuron-ethyl is an ethyl ester resulting from the formal condensation of the carboxy group of chlorimuron with ethanol. A proherbicide for chloimuron, it is used as herbicide for the control of broad-leaved weeds in peanuts, soya beans, and other crops. It has a role as a proherbicide, an EC 2.2.1.6 (acetolactate synthase) inhibitor and an agrochemical. It is a sulfamoylbenzoate, a N-sulfonylurea, an aromatic ether, an ethyl ester, an organochlorine pesticide and a member of pyrimidines. It is functionally related to a chlorimuron. It is a conjugate acid of a chlorimuron-ethyl(1-).

General Description

Colorless crystals. Used as an herbicide.

Reactivity Profile

Chlorimuron-ethyl is a sulfonyl urea, and pyrimidine derivative.

Agricultural Uses

Herbicide: Used to control broadleaf weeds and annual morning glory in soybeans and peanuts. Not listed as registered for use in EU countries. Registered for use in the U.S., except California. There are more than 25 global suppliers.

Trade name

AUTHORITY®; CANOPY® (chlorimuron-ethyl + Metribuzin); CLASSIC®; CONCERT® cancelled; DPX-F6025®; GEMINI®[C]; LOROX®[C]; PREVIEW®[C]; RELIANCE®; SKERMISH®, cancelled; SYNCHRONCY®; SYNCHRONY®[C]

Potential Exposure

A sulfonylurea/pyrimidine derivative herbicide used to control broadleaf weeds and annual morning glory in soybeans and peanuts. Not listed as registered for use in EU countries. Registered for use in the United States and available from more than 25 global suppliers.

Metabolic pathway

Excised soybean seedlings rapidly metabolize 14C- chlorimuron ethyl, but common cocklebur and redroot pigweed, which are sensitive to chlorimuron ethyl, metabolize much more slowly. Two metabolites are primarily identified. By intact corn seedlings, chlorimuron ethyl undergoes biotransformation to give more metabolites and under UV light is photodegraded into smaller fragments.

Shipping

UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required.

Incompatibilities

Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides, nitrates.

Waste Disposal

Do not discharge into drains or sewers. Dispose of waste material as hazardous waste using a licensed disposal contractor to an approved landfill. Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Incineration with effluent gas scrubbing is recommended. Containers must be disposed of properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office.

Chlorimuron-ethyl Preparation Products And Raw materials

Raw materials

o-Ethoxycarbonylbenzenesulfonamide Pyrimidine, 2-isocyanato- (9CI) Ethanol Dimethyl malonate Toluene 4,6-Dihydroxypyrimidine Triethylamine 2,4-Dichloropyrimidine 4,6-Dichloropyrimidine Saccharin sodium Methanol solution of sodium methoxide Sodium bicarbonate Dichloromethane Oxalyl chloride Sodium carbonate

Preparation Products

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Chlorimuron-ethyl Suppliers

Argentina 1 CHINA 185 France 1 Germany 4 India 12 Japan 2 New Zealand 1 South Korea 1 Switzerland 1 The Netherlands 1 United Kingdom 5 United States 30 Global 244

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View Lastest Price from Chlorimuron-ethyl manufacturers

qingdao trust agri chemical co.,ltd

Product: Chlorimuron-ethyl 90982-32-4
Price: US $0.00/kg
Min. Order: 1kg
Purity: 99
Supply Ability: 20tons
Release date: 2024-07-23

Hebei Weibang Biotechnology Co., Ltd

Product: Chlorimuron-ethyl 90982-32-4
Price: US $10.00/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: 10 mt
Release date: 2021-08-24

Henan Fengda Chemical Co., Ltd

Product: Chlorimuron-ethyl 90982-32-4
Price: US $6.00-0.20/KG
Min. Order: 1KG
Purity: 99%
Supply Ability: g-kg-tons, free sample is available
Release date: 2024-03-28

90982-32-4, Chlorimuron-ethylRelated Search:

Azimsulfuron Anisole Ethanol ALTRENOGEST 4-Methoxyphenylacetone Ethyl cellulose CHLOROETHANE Chlorimuron 4-Methoxybenzylchloride Ethylbenzene 2-Methoxyethanol Ethylparaben Tribenuron methyl Methyl acrylate Tris(trimethylsilyl)phosphate (Trifluoromethoxy)benzene p-Anisidine Epichlorohydrin

2-(((((4-chloro-6-methoxy-2-pyrimidinyl)amino)carbonyl)amino)sulfonyl)benzoica

ethyl2-(((((4-chloro-6-methoxpyrimidin-2-yl)aminol)carbonyl)amino)sulfonyl)benzoate

ethyl2-(((((4-chloro-6-methoxypyrimidin-2-yl)-amino)carbonyl)amino)sulfonyl)b

Ethyl2-(((((4-chloro-6-methoxypyrimidin-2-yl)amino)carbonyl)amino)sulfonyl)benzoate

ETHYL-2-[[[[(4-CHLORO-6-METHOXY-2-PYRIMIDINYL)AMINO]CARBONYL]AMINO]-SULFONYL] BENZOATE

DARBAN

DPX-F6025

Chlorimuron Et

CHLORIMURON-ETHYL

chlorimuron ethyl ester

CLASSIC

CLASSIC 25 DF WEED KILLER(R)

classic 75df

2-[[[[(4-Chloro-6-methoxy-2-pyrimidinyl)amino]carbonyl]amino]sulfonyl]benzoic acid ethyl ester

CHLORIMURON ETHYL, 100MG, NEAT

Classic[R]

Benzoic acid, 2-(4-chloro-6-methoxy-2-pyrimidinyl)aminocarbonylaminosulfonyl-, ethyl ester

Chlorsulfuron-ethyl

Ethyl 2-(4-chloro-6-methoxypyrimidin-2-ylcarbamoyl sulfamcyl benzoate

Chlorimuron W.P.

Ethyl 2-(4-chloro-6-methoxy-2-pyrimidinylcarbamoylsulfamoyl)benzoate

2-（4-chloro-6-methoxylrimidin-2-yl carbamoyl sulfamoyl) ethyl benzoate

Chlorimuron ethyl 100mg [90982-32-4]

HIT 25VP

1-[2-(Ethoxycarbonyl)phenylsulfonyl]-3-(4-chloro-6-methoxypyrimidine-2-yl)urea

2-[(4-Methoxy-6-chloropyrimidine-2-yl)carbamoylsulfamoyl]benzoic acid ethyl ester

2-[[(4-Chloro-6-methoxy-2-pyrimidinyl)carbamoyl]sulfamoyl]benzoic acid ethyl ester

Ethyl 2-(N-((4-chloro-6-methoxypyrimidin-2-yl)carbamoyl)sulfamoyl)benzoate

2-[[[(4-chloro-6-methoxy-2-pyrimidinyl)amino]-oxomethyl]sulfamoyl]benzoic acid ethyl ester

ethyl 2-({[(4-chloro-6-methoxypyrimidin-2-yl)carbamoyl]amino}sulfonyl)benzoate

Chlorimuron-ethyl @100 μg/mL in Acetonitrile

Chlorimuron-ethyl@1000 μg/mL in Acetonitrile

Chlorimuron-ethyl Standard

Chlorimuron-ethyl Solution in Acetonitrile, 1000μg/mL

ethyl2-(((((4-chloro-6-methoxypyrimidin-2-yl)-

90982-32-4

C15H15ClN4O6S

HERBICIDE