2-METHYLACETANILIDE

ChemicalBook > CAS DataBase List > 2-METHYLACETANILIDE

2-METHYLACETANILIDE

Product Name: 2-METHYLACETANILIDE
CAS No.: 120-66-1
Chemical Name: 2-METHYLACETANILIDE
Synonyms: O-ACETOTOLUIDE;O-TOLYLACETAMIDE;Acet-o-toluidide;O-ACETOTOLUIDIDE;O-ACETOTOLUIDINE;2-ACETOTOLUIDINE;2-ACETAMIDOTOLUENE;ACETYL-O-TOLUIDINE;O-METHYLACETANILIDE;2-Methylacetaniline
CBNumber: CB5746022
Molecular Formula: C9H11NO
Formula Weight: 149.19
MOL File: 120-66-1.mol

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2-METHYLACETANILIDE Property

Melting point:: 109-112 °C
Boiling point:: 296 °C
Density: 1.16
refractive index: 1.5279 (estimate)
Flash point:: 296°C
storage temp.: Sealed in dry,Room Temperature
solubility: It is slightly soluble in acetone, chloroform, toluene, benzene.
form: Solid
pka: 15.13±0.70(Predicted)
color: Needles
Merck: 14,74
BRN: 2207054
CAS DataBase Reference: 120-66-1(CAS DataBase Reference)
EPA Substance Registry System: o-Acetotoluidide (120-66-1)

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Safety

Hazard Codes: Xn
Risk Statements: 36/37/38-22
Safety Statements: 37/39-26-36-36/37
RTECS: AN2900000
Hazard Note: Harmful
TSCA: Yes
HS Code: 29242990
Hazardous Substances Data: 120-66-1(Hazardous Substances Data)
Toxicity: mma-sat 1 mg/plate NTPTB* JAN 82

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H302Harmful if swallowed

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: S554383
Product name: O-ACETOTOLUIDIDE
Purity: Aldrich
Packaging: 250mg
Price: $179
Updated: 2024/03/01

TCI Chemical

Product number: A0063
Product name: o-Acetotoluidine
Purity: >98.0%(GC)
Packaging: 25g
Price: $42
Updated: 2024/03/01

Alfa Aesar

Product number: A13235
Product name: 2'-Methylacetanilide, 98+%
Packaging: 25g
Price: $37.65
Updated: 2024/03/01

Alfa Aesar

Product number: A13235
Product name: 2'-Methylacetanilide, 98+%
Packaging: 100g
Price: $131.65
Updated: 2024/03/01

TRC

Product number: M275315
Product name: o-Methylacetanilide
Packaging: 1g
Price: $120
Updated: 2021/12/16

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2-METHYLACETANILIDE Chemical Properties,Usage,Production

Chemical Properties

WHITE TO OFF-WHITE CRYSTALLINE POWDER

Uses

Acetanilide is used as an inhibitor of peroxides and?stabilizer for cellulose ester varnishes.?It is used as an intermediate for the synthesis of?rubber accelerators, dyes and dye intermediate and camphor. It is used as a precursor in penicillin synthesis and other pharmaceuticals including painkillers and intermediates.

Uses

o-Methylacetanilide is a substituted acetanilide that is used as precursor for various pharmaceuticals including their intermediates.

Definition

ChEBI: 2`-Methylacetanilide is a member of toluenes.

Synthesis Reference(s)

Journal of the American Chemical Society, 106, p. 5759, 1984 DOI: 10.1021/ja00331a073
Organic Syntheses, Coll. Vol. 5, p. 650, 1973

General Description

Colorless crystals. Insoluble in water.

Air & Water Reactions

Water insoluble.

Reactivity Profile

2-METHYLACETANILIDE is an amide. Amides react with azo and diazo compounds to generate toxic gases. Flammable gases are formed by the reaction of organic amides with strong reducing agents. Amides are very weak bases (weaker than water). Imides are less basic yet and in fact react with strong bases to form salts. That is, they can react as acids. Mixing amides with dehydrating agents such as P2O5 or SOCl2 generates the corresponding nitrile. The combustion of these compounds generates mixed oxides of nitrogen (NOx).

Health Hazard

ACUTE/CHRONIC HAZARDS: Toxic. Hazardous decomposition products.

Safety Profile

Moderately toxic by ingestion.Mutation data reported. When heated to decomposition it emits toxic fumes of NOx.

Purification Methods

Crystallise the toluidide from hot H2O (solubility 1g/210mL), EtOH or aqueous EtOH. UV: max 230 and 280nm (EtOH). [Beilstein 12 H 792, 12 I 376, 12 II 439, 12 III 1853, 12 IV 1755.]

2-METHYLACETANILIDE Preparation Products And Raw materials

Raw materials

Acetic anhydride o-Toluidine Acetic acid

Preparation Products

2-Methyl-5-nitroaniline 2-Methyl-6-nitroaniline

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View Lastest Price from 2-METHYLACETANILIDE manufacturers

Career Henan Chemical Co

Product: 2-METHYLACETANILIDE 120-66-1
Price: US $1.00/kg
Min. Order: 1kg
Purity: 98%
Supply Ability: 100KG
Release date: 2018-12-21

120-66-1, 2-METHYLACETANILIDERelated Search:

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2-ACETAMIDOTOLUENE

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2'-METHYLACETANILIDE

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ACETO-O-AMINOTOLUENE

N-acetyl-2-toluidine

ACETYLORTHO-TOLUIDINE

N-ACETYL-ORTHO-TOLUIDINE

2-Acetylaminotoluene

N-(o-Methylphenyl)acetamide

o-Acetotoluidide,99%

N-(2-Methylphenyl)acetamide, 2-Acetamidotoluene

2-Methylacetanilide, 98+%

N-Ac-2-methylaniline

o-Acetotoluidine &gt

2'-methylacetanilide

120-66-1

CH3CONHC6H4CH3

Anilines, Amides & Amines