2-METHYLACETANILIDE
- Product Name
- 2-METHYLACETANILIDE
- CAS No.
- 120-66-1
- Chemical Name
- 2-METHYLACETANILIDE
- Synonyms
- O-ACETOTOLUIDE;O-TOLYLACETAMIDE;Acet-o-toluidide;O-ACETOTOLUIDIDE;O-ACETOTOLUIDINE;2-ACETOTOLUIDINE;2-ACETAMIDOTOLUENE;ACETYL-O-TOLUIDINE;O-METHYLACETANILIDE;2-Methylacetaniline
- CBNumber
- CB5746022
- Molecular Formula
- C9H11NO
- Formula Weight
- 149.19
- MOL File
- 120-66-1.mol
2-METHYLACETANILIDE Property
- Melting point:
- 109-112 °C
- Boiling point:
- 296 °C
- Density
- 1.16
- refractive index
- 1.5279 (estimate)
- Flash point:
- 296°C
- storage temp.
- Sealed in dry,Room Temperature
- solubility
- It is slightly soluble in acetone, chloroform, toluene, benzene.
- form
- Solid
- pka
- 15.13±0.70(Predicted)
- color
- Needles
- Merck
- 14,74
- BRN
- 2207054
- CAS DataBase Reference
- 120-66-1(CAS DataBase Reference)
- EPA Substance Registry System
- o-Acetotoluidide (120-66-1)
Safety
- Hazard Codes
- Xn
- Risk Statements
- 36/37/38-22
- Safety Statements
- 37/39-26-36-36/37
- RTECS
- AN2900000
- Hazard Note
- Harmful
- TSCA
- Yes
- HS Code
- 29242990
- Hazardous Substances Data
- 120-66-1(Hazardous Substances Data)
- Toxicity
- mma-sat 1 mg/plate NTPTB* JAN 82
Hazard and Precautionary Statements (GHS)
- Symbol(GHS)
-
- Signal word
- Warning
- Hazard statements
-
H302Harmful if swallowed
H315Causes skin irritation
H319Causes serious eye irritation
H335May cause respiratory irritation
- Precautionary statements
-
P261Avoid breathing dust/fume/gas/mist/vapours/spray.
P264Wash hands thoroughly after handling.
P264Wash skin thouroughly after handling.
P270Do not eat, drink or smoke when using this product.
P280Wear protective gloves/protective clothing/eye protection/face protection.
P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405Store locked up.
P501Dispose of contents/container to..…
N-Bromosuccinimide Price
- Product number
- S554383
- Product name
- O-ACETOTOLUIDIDE
- Purity
- Aldrich
- Packaging
- 250mg
- Price
- $179
- Updated
- 2024/03/01
- Product number
- A0063
- Product name
- o-Acetotoluidine
- Purity
- >98.0%(GC)
- Packaging
- 25g
- Price
- $42
- Updated
- 2024/03/01
- Product number
- A13235
- Product name
- 2'-Methylacetanilide, 98+%
- Packaging
- 25g
- Price
- $37.65
- Updated
- 2024/03/01
- Product number
- A13235
- Product name
- 2'-Methylacetanilide, 98+%
- Packaging
- 100g
- Price
- $131.65
- Updated
- 2024/03/01
- Product number
- M275315
- Product name
- o-Methylacetanilide
- Packaging
- 1g
- Price
- $120
- Updated
- 2021/12/16
2-METHYLACETANILIDE Chemical Properties,Usage,Production
Chemical Properties
WHITE TO OFF-WHITE CRYSTALLINE POWDER
Uses
Acetanilide is used as an inhibitor of peroxides and?stabilizer for cellulose ester varnishes.?It is used as an intermediate for the synthesis of?rubber accelerators, dyes and dye intermediate and camphor. It is used as a precursor in penicillin synthesis and other pharmaceuticals including painkillers and intermediates.
Uses
o-Methylacetanilide is a substituted acetanilide that is used as precursor for various pharmaceuticals including their intermediates.
Definition
ChEBI: 2`-Methylacetanilide is a member of toluenes.
Synthesis Reference(s)
Journal of the American Chemical Society, 106, p. 5759, 1984 DOI: 10.1021/ja00331a073
Organic Syntheses, Coll. Vol. 5, p. 650, 1973
General Description
Colorless crystals. Insoluble in water.
Air & Water Reactions
Water insoluble.
Reactivity Profile
2-METHYLACETANILIDE is an amide. Amides react with azo and diazo compounds to generate toxic gases. Flammable gases are formed by the reaction of organic amides with strong reducing agents. Amides are very weak bases (weaker than water). Imides are less basic yet and in fact react with strong bases to form salts. That is, they can react as acids. Mixing amides with dehydrating agents such as P2O5 or SOCl2 generates the corresponding nitrile. The combustion of these compounds generates mixed oxides of nitrogen (NOx).
Health Hazard
ACUTE/CHRONIC HAZARDS: Toxic. Hazardous decomposition products.
Safety Profile
Moderately toxic by ingestion.Mutation data reported. When heated to decomposition it emits toxic fumes of NOx.
Purification Methods
Crystallise the toluidide from hot H2O (solubility 1g/210mL), EtOH or aqueous EtOH. UV: max 230 and 280nm (EtOH). [Beilstein 12 H 792, 12 I 376, 12 II 439, 12 III 1853, 12 IV 1755.]
2-METHYLACETANILIDE Preparation Products And Raw materials
Raw materials
Preparation Products
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View Lastest Price from 2-METHYLACETANILIDE manufacturers
- Product
- 2-METHYLACETANILIDE 120-66-1
- Price
- US $1.00/kg
- Min. Order
- 1kg
- Purity
- 98%
- Supply Ability
- 100KG
- Release date
- 2018-12-21