3-Thienylmethylamine

Product Name: 3-Thienylmethylamine
CAS No.: 27757-86-4
Chemical Name: 3-Thienylmethylamine
Synonyms: Thiophen-3-ylMethanaMine;3-ThiopheneMethylaMine;BVC;BUTTPARK 121\50-76;RARECHEM AL BW 0778;3-THIENYLMETHYLAMINE;3-thienylmethanamine;3-Thiophenemethanamine;(Thien-3-yl)methylamine;Thiophene-3-methylamine
CBNumber: CB6115175
Molecular Formula: C5H7NS
Formula Weight: 113.18
MOL File: 27757-86-4.mol

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3-Thienylmethylamine Property

Boiling point:: 102°C (15 mmHg)
Density: 1.130
refractive index: 1.5660
storage temp.: under inert gas (nitrogen or Argon) at 2–8 °C
form: clear liquid
pka: 9.57±0.29(Predicted)
color: Colorless to Light yellow
Water Solubility: Slightly soluble in water.
Sensitive: Air Sensitive
InChI: InChI=1S/C5H7NS/c6-3-5-1-2-7-4-5/h1-2,4H,3,6H2
InChIKey: DUDAKCCDHRNMDJ-UHFFFAOYSA-N
SMILES: C1SC=CC=1CN

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Safety

Hazard Codes: C
Risk Statements: 34
Safety Statements: 26-36/37/39-45
RIDADR: 2735
Hazard Note: Corrosive
HazardClass: IRRITANT
HazardClass: 8
PackingGroup: Ⅲ
HS Code: 29349990

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Danger

Hazard statements

H314Causes severe skin burns and eye damage

H318Causes serious eye damage

Precautionary statements

P301+P330+P331IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

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N-Bromosuccinimide Price

TCI Chemical

Product number: T2850
Product name: 3-Thiophenemethylamine
Purity: >97.0%(GC)(T)
Packaging: 1g
Price: $122
Updated: 2025/07/31

TRC

Product number: T430108
Product name: Thiophen-3-ylmethanamine
Packaging: 100mg
Price: $75
Updated: 2021/12/16

Apolloscientific

Product number: OR23203
Product name: 3-(Aminomethyl)thiophene
Purity: 95%
Packaging: 250mg
Price: $29
Updated: 2021/12/16

SynQuest Laboratories

Product number: 7H30-1-Y4
Product name: 3-(Aminomethyl)thiophene
Purity: 95%
Packaging: 250mg
Price: $32
Updated: 2021/12/16

Apolloscientific

Product number: OR23203
Product name: 3-(Aminomethyl)thiophene
Purity: 95%
Packaging: 1g
Price: $102
Updated: 2021/12/16

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3-Thienylmethylamine Chemical Properties,Usage,Production

Chemical Properties

Colorless liquid

Uses

3-Thiophenemethylamineis an important raw material and intermediate used in organic synthesis, pharmaceuticals, agrochemicals and dyestuff.

Synthesis

1641-09-4

27757-86-4

General procedure for the synthesis of 3-aminomethylthiophene from 3-cyanothiophene: Ruthenium(II) complex (1 M) and 2-butanol (5 mL) were added to a 25 mL flask under argon protection and stirred for 5 min at room temperature. Subsequently, KOtBu (0.05 mM) was added and stirring was continued for 5 minutes. Next, 3-cyanothiophene (0.5 mM) was added and the reaction mixture was heated on a hot plate at 120°C for 30 minutes. Upon completion of the reaction, the catalyst was removed by addition of petroleum ether followed by filtration. The filtrate was neutralized with 1 M HCl. The ether layer was purified by short path silica gel column chromatography. Hexadecane was added to the purified filtrate as an internal standard and the yield of the product 3-aminomethylthiophene was determined by gas chromatography (GC).

References

[1] Organic Process Research and Development, 2012, vol. 16, # 1, p. 109 - 116
[2] Chemistry - A European Journal, 2016, vol. 22, # 14, p. 4991 - 5002
[3] Angewandte Chemie - International Edition, 2016, vol. 55, # 47, p. 14653 - 14657
[4] Angew. Chem., 2016, vol. 128, # 47, p. 14873 - 14877,5
[5] Journal of Coordination Chemistry, 2015, vol. 68, # 2, p. 321 - 334

3-Thienylmethylamine Preparation Products And Raw materials

Raw materials

Ammonium hydroxide Nitrogen N,N-Dimethylformamide Nickel 3-Thiophenezoic acid Tetrahydrofuran 3-Bromothiophene Lithium Aluminum Hydride Thionyl chloride n-Butyllithium

Preparation Products

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3-Thienylmethylamine Suppliers

Belgium 1 China 141 Germany 3 India 2 Japan 1 Switzerland 1 United Kingdom 7 United States 18 Global 174

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View Lastest Price from 3-Thienylmethylamine manufacturers

Career Henan Chemical Co

Product: 3-Thienylmethylamine 27757-86-4
Price: US $8.80/KG
Min. Order: 1KG
Purity: 97%-99%
Supply Ability: 100kg
Release date: 2019-07-10

27757-86-4, 3-ThienylmethylamineRelated Search:

Meglumine Cephalothin sodium trimethylamine oxide Thiophene Flunixin meglumine Tetrahydrothiophene Trimethylamine SILIBININ-N-METHYLGLUCAMINE, 95％（HPLC） 3-Thiophenezoic acid 3-Thienylmethanol 2-THIENYLMETHYLAMINE Methylamine 3-Thienylmethylamine

RARECHEM AL BW 0778

BUTTPARK 121\50-76

C-THIOPHEN-3-YL-METHYLAMINE

3-(Aminomethyl)thiophene

(3-thienylmethyl)amine(SALTDATA: HCl)

Thiophen-3-yl-methylamine

(Thien-3-yl)methylamine

3-ThiopheneMethylaMine

Thiophen-3-ylMethanaMine

3-THIENYLMETHYLAMINE

1-(Thien-3-yl)methylamine

Thiophene-3-methylamine

3-Thienylmethylamine ,97%

3-thienylmethanamine

BVC

3-Thiophenemethanamine

3-Thienylmethylamine ISO 9001：2015 REACH

3-Thiophenemethanamine (9CI, ACI)

3-(Aminomethyl)thiophene - [T4026]

27757-86-4

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