ChemicalBook > CAS DataBase List > 4-Chlorothiophenol

4-Chlorothiophenol

Product Name
4-Chlorothiophenol
CAS No.
106-54-7
Chemical Name
4-Chlorothiophenol
Synonyms
4-CHLOROBENZENETHIOL;4-Chloro;PARA-CHLOROTHIOPHENOL;NSC 229564;orothiophenoL;p-Chlorthiofenol;4-CHLOROTHIOPENOL;4-chlorthiophenol;AKOS BBS-00004252;CHLOROTHIOPHENOL-4
CBNumber
CB6130893
Molecular Formula
C6H5ClS
Formula Weight
144.62
MOL File
106-54-7.mol
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4-Chlorothiophenol Property

Melting point:
49-51 °C(lit.)
Boiling point:
205-207 °C(lit.)
Density 
1.1911
refractive index 
1.5480
Flash point:
>230 °F
storage temp. 
2-8°C
solubility 
methanol: soluble
pka
pK1:5.9 (25°C)
form 
Crystalline Solid
color 
White to almost white
Water Solubility 
insoluble
Sensitive 
Stench/Lachrymatory
BRN 
605971
InChIKey
VZXOZSQDJJNBRC-UHFFFAOYSA-N
CAS DataBase Reference
106-54-7(CAS DataBase Reference)
NIST Chemistry Reference
Benzenethiol, 4-chloro-(106-54-7)
EPA Substance Registry System
Benzenethiol, 4-chloro- (106-54-7)
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Safety

Hazard Codes 
C
Risk Statements 
22-34-36/37-20/21/22
Safety Statements 
26-36/37/39-45-27
RIDADR 
UN 3261 8/PG 2
WGK Germany 
3
RTECS 
DC1050000
F 
9-13-23
Hazard Note 
Corrosive/Lachrymatory/Stench
TSCA 
Yes
HazardClass 
8
PackingGroup 
III
HS Code 
29309090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

Precautionary statements

P260Do not breathe dust/fume/gas/mist/vapours/spray.

P270Do not eat, drink or smoke when using this product.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P301+P312IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
125237
Product name
4-Chlorothiophenol
Purity
97%
Packaging
5g
Price
$45.8
Updated
2024/03/01
Sigma-Aldrich
Product number
125237
Product name
4-Chlorothiophenol
Purity
97%
Packaging
100g
Price
$110
Updated
2024/03/01
TCI Chemical
Product number
C0129
Product name
4-Chlorobenzenethiol
Purity
>98.0%(GC)(T)
Packaging
25g
Price
$41
Updated
2024/03/01
TCI Chemical
Product number
C0129
Product name
4-Chlorobenzenethiol
Purity
>98.0%(GC)(T)
Packaging
500g
Price
$140
Updated
2024/03/01
Alfa Aesar
Product number
B23838
Product name
4-Chlorothiophenol, 97%
Packaging
25g
Price
$24.65
Updated
2024/03/01
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4-Chlorothiophenol Chemical Properties,Usage,Production

Chemical Properties

white to almost white crystalline solid

Uses

Oil additives, agricultural chemicals, plasticizers, rubber chemical, dyes, wetting agents, and stabilizers.

Uses

4-Chlorothiophenol was used to modify poly(vinyl chloride) and to synthesize poly(vinyl chloride) with halogen groups.

Synthesis Reference(s)

The Journal of Organic Chemistry, 27, p. 4455, 1962 DOI: 10.1021/jo01059a081
Synthetic Communications, 18, p. 575, 1988 DOI: 10.1080/00397918808064014

General Description

4-Chlorothiophenol undergoes oxidative coupling catalyzed by iron(III)-tetra phenyl prophyrin to form disulfides.

Hazard

Toxic by ingestion.

Purification Methods

Recrystallise the thiophenol from aqueous EtOH. The SMe ether has m 129o and the SEt ether has m 64o. [D'Sousa et al. J Org Chem 52 1720 1987, Beilstein 6 H 326, 6 I 149, 6 III 1034.]

4-Chlorothiophenol Preparation Products And Raw materials

Raw materials

Chlorosulfonic acid Chlorobenzene Sulfuric acid

Preparation Products

2-CHLORO-9-(3-(DIMETHYLAMINO)PROPYL)-TH& 5-CHLORO-3-METHYLBENZO[B]THIOPHENE-2-SULFONAMIDE 5-CHLORO-3-METHYLBENZO[B]THIOPHENE 5-CHLORO-BENZO[B]THIOPHENE-3-CARBOXYLIC ACID 1-(5-CHLOROBENZO[B]THIOPHEN-3-YL)ETHANONE CHLOROMETHYL 4-CHLOROPHENYL SULFIDE CARBOPHENOTHION 2-Chlorothioxanthone 5-CHLOROBENZOTHIOPHENE (5-CHLORO-1-BENZOTHIOPHEN-3-YL)METHANOL 5-CHLORO-3-METHYLBENZO[B]THIOPHENE-2-SULFONYL CHLORIDE 2-(4-chlorophenylthio)benzoic acid 4-(4-CHLOROPHENYLTHIO)-3-NITROBENZALDEHYDE (5-CHLORO-1-BENZOTHIOPHEN-3-YL)METHYLAMINE 3-(Bromomethyl)-5-chlorobenzo[b]thiophene
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4-Chlorothiophenol Suppliers

Americas 1 Belgium 1 China 177 Europe 4 France 1 Germany 3 India 38 Japan 10 Slovakia 1 South Korea 1 Switzerland 4 The Netherlands 1 Ukraine 1 United Kingdom 17 United States 33 Global 293
Suzhou ChemWe Chemical Co., Ltd.
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View Lastest Price from 4-Chlorothiophenol manufacturers

Hebei Weibang Biotechnology Co., Ltd
Product
4-Chlorothiophenol 106-54-7
Price
US $10.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
100 mt
Release date
2024-11-18
Hebei Chuanghai Biotechnology Co,.LTD
Product
4-Chlorothiophenol 106-54-7
Price
US $5.00-2.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
10000kg
Release date
2024-09-20
Hebei Mojin Biotechnology Co., Ltd
Product
4-Chlorothiophenol 106-54-7
Price
US $0.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
50000KG/month
Release date
2023-06-21

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