ChemicalBook > CAS DataBase List > 2-Bromo-6-fluorobenzonitrile

2-Bromo-6-fluorobenzonitrile

Product Name
2-Bromo-6-fluorobenzonitrile
CAS No.
79544-27-7
Chemical Name
2-Bromo-6-fluorobenzonitrile
Synonyms
2-FLUORO-6-BROMOBENZONITRILE;6-BROMO-2-FLUOROBENZONITRILE;2-BROM;2-Bromo-6-fluorobenzon;2- fluoro-6-bromoxynil;2-Bromo-6-fluorobenzotrile;2-BROMO-6-FLUOROBENZONITRILE;3-bromo-2-cyanofluorobenzene;2-Cyano-3-Fluoro-1-broMobenzene;Benzonitrile, 2-bromo-6-fluoro-
CBNumber
CB6216595
Molecular Formula
C7H3BrFN
Formula Weight
200.01
MOL File
79544-27-7.mol
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2-Bromo-6-fluorobenzonitrile Property

Melting point:
60-61
Boiling point:
254.6±25.0 °C(Predicted)
Density 
1.69±0.1 g/cm3(Predicted)
storage temp. 
Inert atmosphere,Room Temperature
form 
Solid
color 
White to brown
InChIKey
IELGUZKHALDFOO-UHFFFAOYSA-N
CAS DataBase Reference
79544-27-7(CAS DataBase Reference)
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Safety

Hazard Codes 
T,Xi,Xn
Risk Statements 
22-36/37/38
Safety Statements 
26
WGK Germany 
3
Hazard Note 
Toxic
HazardClass 
IRRITANT-HARMFUL
HazardClass 
6.1
HS Code 
2926907090
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Warning
Hazard statements

H302Harmful if swallowed

H312Harmful in contact with skin

H315Causes skin irritation

H319Causes serious eye irritation

H332Harmful if inhaled

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P270Do not eat, drink or smoke when using this product.

P271Use only outdoors or in a well-ventilated area.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

P501Dispose of contents/container to..…

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N-Bromosuccinimide Price

TCI Chemical
Product number
B3183
Product name
2-Bromo-6-fluorobenzonitrile
Purity
>97.0%(GC)
Packaging
5g
Price
$66
Updated
2024/03/01
Alfa Aesar
Product number
H61498
Product name
2-Bromo-6-fluorobenzonitrile, 97%
Packaging
5g
Price
$36.7
Updated
2021/12/16
Alfa Aesar
Product number
H61498
Product name
2-Bromo-6-fluorobenzonitrile, 97%
Packaging
25g
Price
$147
Updated
2021/12/16
TRC
Product number
B692023
Product name
2-Bromo-6-fluorobenzonitrile
Packaging
500mg
Price
$45
Updated
2021/12/16
Matrix Scientific
Product number
018273
Product name
2-Bromo-6-fluorobenzonitrile
Purity
98%
Packaging
25g
Price
$49
Updated
2021/12/16
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2-Bromo-6-fluorobenzonitrile Chemical Properties,Usage,Production

Chemical Properties

Off-white crystalline

Uses

2-Bromo-6-fluorobenzonitrile is used as an initial raw material in the synthesis of  2-bromo-6-fluorobenzoic acid.

Synthesis

2-Amino-6-fluorobenzonitrile (18.0 g, 132 mmol) was dissolved in hot 1,4-dioxane (20 ml), 48% hydrobromic acid (200 ml) was added and the mixture cooled to 0°C before dropwise addition of sodium nitrite (10.5 g, 152 mmol) in water (20 ml) over 1.5 h. The resulting mixture was stirred at 0°C for 1.5 h then poured onto a cooled (0°C) solution of copper(I) bromide (56.8 g, 396 mmol) in 48% hydrobromic acid (50 ml). The solution was stirred at 0°C for 15 min then heated at 50°C for 20 min. The mixture was cooled to ambient temperature, diluted with water (1200 ml) and extracted with ethyl acetate (2 x 400 ml). The combined organics were washed with 10% aqueous ammonia solution (400 ml), water (400 ml) and brine (500 ml), dried over anhydrous magnesium sulfate, filtered and evaporated to give an orange oil. Purification by chromatography on silica 5 gel eluting with isohexane on a gradient of ethyl acetate (2-4%) gave 2-bromo-6-fluorobenzonitrile. White solid, yield (18.5 g, 70%). δH (400 MHz, CDCl3) 7.17-7.23 (1H, ddd, J 8, 8 and 1), 7.44-7.52 (2H, m).

2-Bromo-6-fluorobenzonitrile Preparation Products And Raw materials

Raw materials

Preparation Products

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2-Bromo-6-fluorobenzonitrile Suppliers

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View Lastest Price from 2-Bromo-6-fluorobenzonitrile manufacturers

Changzhou Anxuan Chemical Co., Ltd
Product
2-BROMO-6-FLUOROBENZONITRILE 79544-27-7
Price
US $0.00/KG
Min. Order
1KG
Purity
98%
Supply Ability
1MT
Release date
2023-02-15
Career Henan Chemical Co
Product
2-BROMO-6-FLUOROBENZONITRILE 79544-27-7
Price
US $1.00/KG
Min. Order
1KG
Purity
99%
Supply Ability
Customized
Release date
2019-06-27

79544-27-7, 2-Bromo-6-fluorobenzonitrileRelated Search:

3-Fluoro-5-Bromo benzonitrile 2-Bromo-4-fluorobenzonitrile98%,2-Bromo-4-fluorobenzonitrile 98%,2-BROMO-4-FLUOROBENZONITRILE 3-BROMO-5-FLUOROBENZONITRILE,3-Bromo-5-fluorobenzonitrile 98%,3-Bromo-5-fluorobenzonitrile98% 5-BROMO-2-FLUOROBENZONITRILE,5-Bromo-2-fluorobenzonitrile 98%,5-Bromo-2-fluorobenzonitrile98% 2-Bromo-5-fluorobenzonitrile99%,2-Bromo-5-fluorobenzonitrile 99%,2-BROMO-5-FLUOROBENZONITRILE,2-Bromo-5-fluorobenzonitrile, 98+% 2-Bromo-3-fluorobenzonitrile99% 3-BROMO-2-FLUOROBENZONITRILE 4-Bromo-3-fluorobenzonitrile97%,4-BROMO-3-FLUOROBENZONITRILE 4-BROMO-2-FLUOROBENZONITRILE,4-Bromo-2-fluorobenzonitrile 98%,4-Bromo-2-fluorobenzonitrile98%,4-BROMO-2-FLUOROBENZONITRILE 99+% 5-bromo-3-fluorobenzonitrile 3-BROMO-2-FLUOROBENZONITRILE 96% 2-Bromo-6-fluorobenzonitrile 3-BROMO-4-FLUOROBENZONITRILE,3-Bromo-4-fluorobenzonitrile 98%,3-Bromo-4-fluorobenzonitrile98% 2-AMINO-5-BROMO-6-FLUOROBENZONITRILE 2-BROMO-3-FLUOROBENZONITRILE 4-Amino-3-bromo-5-fluorobenzonitrile 2-Bromo-4-flourobenzonitrile 2-AMINO-5-BROMO-6-FLUOROBENZONITRILE 97%

  • 6-BROMO-2-FLUOROBENZONITRILE
  • 2-FLUORO-6-BROMOBENZONITRILE
  • 2-BROMO-6-FLUOROBENZONITRILE
  • 2-Cyano-3-Fluoro-1-broMobenzene
  • 3-bromo-2-cyanofluorobenzene
  • 2- fluoro-6-bromoxynil
  • 2-Bromo-6-fluorobenzotrile
  • 2-Bromo-6-fluorobenzonitrile &gt
  • Benzonitrile, 2-bromo-6-fluoro-
  • 2-BROM
  • 2-Bromo-6-fluorobenzon
  • 79544-27-7
  • Cyanides/Nitriles
  • Organic Building Blocks
  • Nitrogen Compounds
  • Building Blocks
  • C6 to C7
  • Fluorine series
  • cyanide| alkyl bromide| alkyl Fluorine
  • Aromatic Nitriles
  • Nitrile
  • C6 to C7
  • Cyanides/Nitriles
  • Nitrogen Compounds