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Tetrabutyl titanate

Product Name
Tetrabutyl titanate
CAS No.
5593-70-4
Chemical Name
Tetrabutyl titanate
Synonyms
TITANIUM BUTOXIDE;TNBT;TETRA-N-BUTYL TITANATE;tetrabutoxytitanium;BUTYL TITANATE;TITANIUM(IV) BUTOXIDE;TITANIUM TETRABUTOXIDE;TETRABUTYL ORTHOTITANATE;Tyzor TBT;titaniuM salt
CBNumber
CB6222404
Molecular Formula
C16H36O4Ti
Formula Weight
340.32
MOL File
5593-70-4.mol
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Tetrabutyl titanate Property

Melting point:
-55°C
Boiling point:
206 °C/10 mmHg (lit.)
Density 
1.00 g/mL at 20 °C (lit.)
vapor pressure 
5.6 hPa (20 °C)
refractive index 
n20/D 1.491(lit.)
Flash point:
55 °F
storage temp. 
Store at +2°C to +8°C.
solubility 
Miscible with aliphatic, aromatic, chlorinated and oxygenated solvents.
form 
Liquid
Specific Gravity
0.998
color 
Pale yellow
explosive limit
2.0-12.0%(V)
Water Solubility 
RAPIDLY HYDROLIZED
Sensitive 
Moisture Sensitive
Hydrolytic Sensitivity
7: reacts slowly with moisture/water
BRN 
4148236
Stability:
Stable, but moisture sensitive. Flammable. Incompatible with water, moisture, strong oxidizing agents, strong acids.
InChIKey
YHWCPXVTRSHPNY-UHFFFAOYSA-N
LogP
0.84 at 25℃
CAS DataBase Reference
5593-70-4(CAS DataBase Reference)
NIST Chemistry Reference
Tetrabutoxytitanium(5593-70-4)
EPA Substance Registry System
Tetrabutyl titanate (5593-70-4)
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Safety

Hazard Codes 
Xi,T
Risk Statements 
10-36/37/38-67-41-37/38-45
Safety Statements 
16-26-39-24/25-53
RIDADR 
UN 1993 3/PG 3
WGK Germany 
1
RTECS 
XR1585000
F 
21
TSCA 
Yes
HazardClass 
8
PackingGroup 
III
HS Code 
29051900
Hazardous Substances Data
5593-70-4(Hazardous Substances Data)
Toxicity
LD50 orally in Rabbit: 3122 mg/kg
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Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H226Flammable liquid and vapour

H315Causes skin irritation

H318Causes serious eye damage

H335May cause respiratory irritation

H336May cause drowsiness or dizziness

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P233Keep container tightly closed.

P240Ground/bond container and receiving equipment.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

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N-Bromosuccinimide Price

Sigma-Aldrich
Product number
8.21084
Product name
Tetra-n-butyl orthotitanate
Purity
forsynthesis
Packaging
100mL
Price
$40.9
Updated
2024/03/01
Sigma-Aldrich
Product number
8.21084
Product name
Tetra-n-butyl orthotitanate
Purity
forsynthesis
Packaging
500mL
Price
$136
Updated
2024/03/01
Sigma-Aldrich
Product number
244112
Product name
Titanium(IV) butoxide
Purity
reagent grade, 97%
Packaging
5g
Price
$42.1
Updated
2024/03/01
Sigma-Aldrich
Product number
8.21084
Product name
Tetra-n-butyl orthotitanate
Purity
forsynthesis
Packaging
10Kg
Price
$640
Updated
2024/03/01
Sigma-Aldrich
Product number
244112
Product name
Titanium(IV) butoxide
Purity
reagent grade, 97%
Packaging
2kg
Price
$282
Updated
2024/03/01
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Tetrabutyl titanate Chemical Properties,Usage,Production

Chemical Properties

colourless to light yellow viscous liquid

Uses

Ester exchange reactions; heat-resistant paints (up to 500C); improving adhesion of paints, rubber, and plastics to metal surfaces; cross-linking agent; condensation catalyst.

Uses

Titanium(IV) n-butoxide is used in the preparation of nanosized titania powders in the anatase form and ferroelectric bismuth titanate thin films. It is also used as intermediates, paint additives, coating additives, processing aids and as process regulators. It is involved in the preparation of nanocrystalline titanium dioxide powders at room temperature.

Uses

Titanium(IV) butoxide is a sourcing material for the preparation of titanium oxide (TiO2) which can further be used in a variety of applications such as dye sensitized solar cells (DSSCs), photo-catalytic and self-cleaning based coatings.

General Description

A water-white to pale-yellow liquid with an alcohol-like odor. About the same density as water. Flash point 170°F. Contact may irritate or cause burns.

Air & Water Reactions

Soluble in water. Reacts with water to form butanol and titanium dioxide, the reaction is not generally thought to be hazardous.

Reactivity Profile

Organometallics are strongly reactive with many other groups. Incompatible with acids and bases. Organometallics are good reducing agents and therefore incompatible with oxidizing agents. Often reactive with water to generate toxic or flammable gases. Generally highly toxic. Often react on contact with tissues to give toxic products.

Health Hazard

LIQUID: Irritating to skin and eyes. If swallowed will cause nausea and vomiting.

Fire Hazard

Combustible. Containers may explode in fire. May give off dense white smoke. Containers may explode.

Flammability and Explosibility

Flammable

Safety Profile

Suspected carcinogen. A poison by intravenous route. Moderately toxic by ingestion. See n-BUTYL ALCOHOL and TITANIUM COMPOUNDS. Flammable when exposed to heat or flame. To fight fire, use water, spray, foam, dry chemical. Incompatible with oxidizing materials. When heated to decomposition it emits acrid and irritating fumes.

Purification Methods

Dissolve it in *C6H6, filter if solid is present, evaporate and vacuum fractionate through a Widmer 24inch column (p 11). The ester hydrolyses when exposed to air to give hydrated ortho-titanic acid. The titanium content can be determined thus: weigh a sample (ca 0.25g) into a weighed crucible and cover it with 10mL of H2O and a few drops of conc HNO3. Heat (hot plate) carefully till most of the H2O has evaporated. Cool and add more H2O (10mL) and conc HNO3 (2mL), and evaporate carefully (no spillage) to dryness and ignite the residue at 600-650o/1hour. Weigh the residual TiO2. [Bradley et al. J Chem Soc 2773 1952, Speer J Org Chem 14 655 1949, Beilstein 1 II 398, 1 III 1515, 1 IV 1415.]

Tetrabutyl titanate Preparation Products And Raw materials

Raw materials

(S)-tert-Butyl 6-amino-2-((tert-butoxycarbonyl)amino)hexanoate hydrochloride 4-Chlorobenzaldehyde Toluene Titanium tetrachloride 1-Butanol

Preparation Products

1,2,5,6,9,10-Hexabromocyclododecane Diphenyl isophthalate
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Tetrabutyl titanate Suppliers

Americas 1 Belgium 1 China 362 Europe 2 France 1 Germany 6 India 21 Japan 6 Singapore 1 Switzerland 1 United Kingdom 5 United States 27 USA 1 Global 435
HBCChem, Inc.
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Aladdin Scientific
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United States Biological
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City Chemical LLC
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View Lastest Price from Tetrabutyl titanate manufacturers

Hebei Zhuanglai Chemical Trading Co.,Ltd
Product
tetrabutyl titanate 5593-70-4
Price
US $10.00/kg
Min. Order
1kg
Purity
99%
Supply Ability
20ton
Release date
2024-05-06
WUHAN FORTUNA CHEMICAL CO., LTD
Product
Tetrabutyl titanate 5593-70-4
Price
US $0.00/KG
Min. Order
1KG
Purity
98%min
Supply Ability
30tons/month
Release date
2023-01-16
Baoji Guokang Bio-Technology Co., Ltd.
Product
Tetrabutyl titanate 5593-70-4
Price
US $1451.00/L
Min. Order
200L
Purity
80-98%
Supply Ability
2000T
Release date
2021-06-03

5593-70-4, Tetrabutyl titanateRelated Search:

ZIRCONIUM N-BUTOXIDE TITANIUM ISOBUTOXIDE TITANIUM Piperonyl butoxide Titanium Rutile Barium titanate Titanium tetraisopropanolate Titanium ethoxide Tazobactam Diphenylmethyl Ester Titanium propoxide Ethyl methyl carbonate Diethyl carbonate Propylene carbonate Dimethyl carbonate LEAD TITANIUM OXIDE Magnesium titanium oxide CALCIUM TITANATE Titanium Butoxide

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