Xantphos Pd G3

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Reaction

Product Name: Xantphos Pd G3
CAS No.: 1445085-97-1
Chemical Name: Xantphos Pd G3
Synonyms: XantPhos Pd G3;Pd Catalysts XantPhos-Pd-G3;Xantphos Palladacycle Gen. 3;XantPhos Pd G3[XantPhos Pd G3;Xantphos Palladacycle Gen. 3 ISO 9001：2015 REACH;Methanesulfonato[9,9-dimethyl-4,5-bis(diphenylphosphino)xant...;Methanesulfonato[9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene][2'-amino-1,1'-biphenyl]palladium(I;Methanesulfonato[9,9-diMethyl-4,5-bis(diphenylphosphino)xanthene][2'-aMino-1,1'-biphenyl]palladium(II);Methanesulfonato[9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene][2'-amino-1,1'-biphenyl]palladium(II);methanesulfonato[9,9-dime-4,5-bis(diphenylphosphino)xanthene][2'-amino-1,1'-biphen]pd(ii) ch2cl2 adduct
CBNumber: CB62709871
Molecular Formula: C52H46NO4P2PdS-
Formula Weight: 949.358462
MOL File: 1445085-97-1.mol

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Xantphos Pd G3 Property

Melting point:: 164-167 °C (decomposition)
storage temp.: under inert gas (nitrogen or Argon) at 2–8 °C
form: Powder
color: pale yellow
InChI: InChI=1S/C39H32OP2.C12H10N.CH4O3S.Pd/c1-39(2)33-25-15-27-35(41(29-17-7-3-8-18-29)30-19-9-4-10-20-30)37(33)40-38-34(39)26-16-28-36(38)42(31-21-11-5-12-22-31)32-23-13-6-14-24-32;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h3-28H,1-2H3;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;-1;;
InChIKey: JIMOHYWEUIAPAA-UHFFFAOYSA-N
SMILES: [Pd].S(C([H])([H])[H])(=O)(=O)O[H].P(C1C([H])=C([H])C([H])=C([H])C=1[H])(C1C([H])=C([H])C([H])=C([H])C=1[H])C1=C([H])C([H])=C([H])C2=C1OC1C(=C([H])C([H])=C([H])C=1C2(C([H])([H])[H])C([H])([H])[H])P(C1C([H])=C([H])C([H])=C([H])C=1[H])C1C([H])=C([H])C([H])=C([H])C=1[H].N([H])([H])C1=C([H])C([H])=C([H])C([H])=C1C1=C([H])C([H])=C([H])C([H])=[C-]1

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Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P264Wash hands thoroughly after handling.

P264Wash skin thouroughly after handling.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P302+P352IF ON SKIN: wash with plenty of soap and water.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P321Specific treatment (see … on this label).

P332+P313IF SKIN irritation occurs: Get medical advice/attention.

P362Take off contaminated clothing and wash before reuse.

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N-Bromosuccinimide Price

Sigma-Aldrich

Product number: 763039
Product name: XantPhos Pd G3
Purity: 95%
Packaging: 250MG
Price: $54.2
Updated: 2023/06/20

Sigma-Aldrich

Product number: 763039
Product name: XantPhos Pd G3
Purity: 95%
Packaging: 1G
Price: $164
Updated: 2023/06/20

Sigma-Aldrich

Product number: 932213
Product name: XantPhos Pd G3 ChemBeads
Packaging: 1G
Price: $276
Updated: 2023/06/20

Sigma-Aldrich

Product number: 763039
Product name: XantPhos Pd G3
Purity: 95%
Packaging: 5G
Price: $678
Updated: 2023/06/20

Strem Chemicals

Product number: 46-0957
Product name: Methanesulfonato[9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene][2'-amino-1,1'-biphenyl]palladium(II) dichloromethane adduct, min. 98% [Xantphos Palladacycle Gen. 3]
Packaging: 500mg
Price: $85
Updated: 2024/03/01

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Xantphos Pd G3 Chemical Properties,Usage,Production

Reaction

Catalyst for the Negishi coupling of aryl halides and alkylzinc reagents.
Catalyst for the synthesis of tetraacetylated p-tolyl thioglucose.
Cooperative catalyst for the direct asymmetric α-allylation of acyclic esters.

Uses

Xantphos Pd G3 is used as a catalyst in many reactions. It is a third generation (G3) Buchwald precatalyst. XantPhos Pd G3 is an excellent reagent for palladium catalyzed cross-coupling reactions.

General Description

XantPhos Pd G3 is a third generation (G3) Buchwald precatalyst. It is air, moisture and thermally-stable and is highly soluble in a wide range of common organic solvents. It has long life in solutions. XantPhos Pd G3 is an excellent reagent for palladium catalyzed cross-coupling reactions. Some of its unique features include lower catalyst loadings, shorter reaction time, efficient formation of the active catalytic species and accurate control of ligand: palladium ratio.

Xantphos Pd G3 Preparation Products And Raw materials

Raw materials

Preparation Products

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View Lastest Price from Xantphos Pd G3 manufacturers

WUHAN FORTUNA CHEMICAL CO., LTD

Product: Xantphos Palladacycle Gen. 3 1445085-97-1
Price: US $0.00/KG
Min. Order: 25KG
Purity: 98%min
Supply Ability: 30tons/month
Release date: 2023-01-29

Hebei Guanlang Biotechnology Co,.LTD

Product: [1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II) 1445085-97-1
Price: US $8.70/g
Min. Order: 10g
Purity: 99%
Supply Ability: 10000kg
Release date: 2021-07-16

Wuhan LPBchem Technology Co.,Ltd

Product: Xantphos Pd G3 1445085-97-1
Price: US $10.00-10.00/g
Min. Order: 1g
Purity: 0.98
Supply Ability: 50kg
Release date: 2020-12-01

1445085-97-1, Xantphos Pd G3Related Search:

XantPhos-Pd-G2 tBuXPhos-Pd-G3 XantPhos Pd G4 XPhos Pd G3 SPhos Palladacycle Gen. 4 XPhos Pd G4 BrettPhos Pd G3 XPhos Pd G2 RuPhos Pd G1 Methyl t--Butyl Ether Adduct SPhos Pd G2 BrettPhosPalladacycle Palladacycle Gen. 3 t-BuXphos Palladacycle Gen. 4 RuPhos Palladacycle Gen. 4 t-BuBrettPhos Palladacycle Gen. 3 SPhos Pd G3 SPhos Pd G1, Methyl t-Butyl Ether Adduct RuPhos Pd G2

Methanesulfonato[9,9-diMethyl-4,5-bis(diphenylphosphino)xanthene][2'-aMino-1,1'-biphenyl]palladiuM(II) dichloroMethane adduct, Min. 98%

Methanesulfonato[9,9-diMethyl-4,5-bis(diphenylphosphino)xanthene][2'-aMino-1,1'-biphenyl]palladium(II)

Methanesulfonato[9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene][2'-amino-1,1'-biphenyl]palladium(I

METHANESULFONATO[9,9-DIMETHYL-4,5-BIS(DIPHENYLPHOSPHINO)XANTHENE][2'-AMINO-1,1'-BIPHENYL]PALLADIUM(II)DICHLOROMETHANEADDUCT,MIN.98%[XANTPHOSPALLADACYCLEGEN.3]

Xantphos Palladacycle Gen. 3

Methanesulfonato[4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene](2-amino-1,1-biphenyl-2-yl)palladium(II)

Methanesulfonato[9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene][2'-amino-1,1'-biphenyl]palladium(II) dichloromethane adduct,[Xantphos Palladacycle Gen. 3]

Methanesulfonato[9,9-diMethyl-4,5-bis(diphenylphosphino)xanthene][2'-aMino-1,1'-biphenyl]palladiuM(II) dichloroMethane adduct

4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene][2’-amino-2-biphenylyl][(methylsulfonyl)oxy]palladium(II)

methanesulfonato[9,9-dime-4,5-bis(diphenylphosphino)xanthene][2'-amino-1,1'-biphen]pd(ii) ch2cl2 adduct

Xantphos Palladacycle Gen. 3 ISO 9001：2015 REACH

Pd Catalysts XantPhos-Pd-G3

Methanesulfonato[9,9-dimethyl-4,5-bis(diphenylphosphino)xant...

Methanesulfonato[9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene](2'-amino-1,1'-biphenyl-2-yl)palladium(II) (Xantphos Pd G3)

[(4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene)-2-(2′-amino-1,1′-biphenyl)]palladium(II) methanesulfonate/XantPhosPdG3

XantPhos Pd G3[XantPhos Pd G3

2'-(Amino-κN)[1,1'-biphenyl]-2-yl-κC][[5-(diphenylphosphino)-9,9-dimethyl-9H-xanthen-4-yl]diphenylphosphine-κP](methanesulfonato-κO)palladium

XantPhos Pd G3

Methanesulfonato[9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene][2'-amino-1,1'-biphenyl]palladium(II)

2'-(Amino-κN)[1,1'-biphenyl]-2-yl-κC][[5-(diphenylphosphino)-9,9-dimethyl-9H-xanthen-4-yl]diphenylphosphine-κP](methanesulfonato-κO)palladium

Methanesulfonato [(R)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthalene] (2'-amino-1,1'-biphenyl-2-yl)palladium(II)，R-Binap Pd G3

1445085-97-1

C52H45NO4P2PdS

C39H32OP2C13H13NO3PdS

Buchwald Ligands&Precatalysts

Buchwald Precatalysts Series