3',5'-Dibromo-2'-hydroxyacetophenone

Product Name: 3',5'-Dibromo-2'-hydroxyacetophenone
CAS No.: 22362-66-9
Chemical Name: 3',5'-Dibromo-2'-hydroxyacetophenone
Synonyms: 3´,5´-Dibromo-2´AKOS BBS-00006933;TIMTEC-BB SBB005396;-hydroxyacetophenone;2-acetyl-4,6-dibromophenol;3,5-DIBROMO-2-HYDROXYACETOPHENONE;3',5'-DIBROMO-2'-HYDROXYACETOPHENONE;3',5'-Dibromo-2'-hydroxyacetophenone
CBNumber: CB6334637
Molecular Formula: C8H6Br2O2
Formula Weight: 293.94
MOL File: 22362-66-9.mol

More

Less

3',5'-Dibromo-2'-hydroxyacetophenone Property

Melting point:: 108-111 °C(lit.)
Boiling point:: 307.5±42.0 °C(Predicted)
Density: 1.936±0.06 g/cm3(Predicted)
storage temp.: Sealed in dry,Room Temperature
form: powder to crystal
pka: 8.07±0.23(Predicted)
color: White to Yellow to Orange
CAS DataBase Reference: 22362-66-9(CAS DataBase Reference)

More

Less

Safety

Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 26-36
WGK Germany: 3
HS Code: 2914390090

More

Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)

Signal word

Warning

Hazard statements

H315Causes skin irritation

H319Causes serious eye irritation

H335May cause respiratory irritation

Precautionary statements

P261Avoid breathing dust/fume/gas/mist/vapours/spray.

P304+P340IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P405Store locked up.

More

Less

N-Bromosuccinimide Price

TCI Chemical

Product number: D4637
Product name: 3',5'-Dibromo-2'-hydroxyacetophenone
Purity: >98.0%(GC)(T)
Packaging: 5g
Price: $47
Updated: 2024/03/01

TCI Chemical

Product number: D4637
Product name: 3',5'-Dibromo-2'-hydroxyacetophenone
Purity: >98.0%(GC)(T)
Packaging: 25g
Price: $142
Updated: 2024/03/01

Alfa Aesar

Product number: B22413
Product name: 3',5'-Dibromo-2'-hydroxyacetophenone, 99%
Packaging: 5g
Price: $46.65
Updated: 2024/03/01

Alfa Aesar

Product number: B22413
Product name: 3',5'-Dibromo-2'-hydroxyacetophenone, 99%
Packaging: 25g
Price: $133.65
Updated: 2024/03/01

Alfa Aesar

Product number: B22413
Product name: 3',5'-Dibromo-2'-hydroxyacetophenone, 99%
Packaging: 100g
Price: $392
Updated: 2021/12/16

More

Less

3',5'-Dibromo-2'-hydroxyacetophenone Chemical Properties,Usage,Production

Description

3‘,5’-Dibromo-2'-hydroxyacetophenone is a halogenated hydroxyacetophenone derivative which can have good reactivity and is widely used in organic synthesis. Its derivative 5′-bromo-2′-hydroxyacetophenone can be used as a raw material to synthesise a variety of 2-(2-hydroxyphenyl)-1H-indoles by palladium-catalysed reaction with aniline^[1].

Uses

3'',5''-Dibromo-2''-hydroxyacetophenone is a useful reagent in organic synthesis.

Preparation

Preparation by Fries rearrangement of 2,4-dibromophenyl acetate with aluminium chloride without solvent between 150° and 165°.

References

[1] MILAN SUBEDI . Facile Synthesis of 2-(4-Hydroxybiphenyl-3-yl)-1H-indoles from Anilines and 5′-Bromo-2′-hydroxyacetophenone[J]. Synthetic Communications, 2015, 45 14: Pages 1704-1709. DOI:10.1080/00397911.2015.1043390.

3',5'-Dibromo-2'-hydroxyacetophenone Preparation Products And Raw materials

Raw materials

Preparation Products

More

Less

3',5'-Dibromo-2'-hydroxyacetophenone Suppliers

Americas 1 China 51 Europe 1 Germany 3 India 16 Japan 2 Switzerland 1 Ukraine 1 United Kingdom 10 United States 14 Global 100

Meryer (Shanghai) Chemical Technology Co., Ltd.

Tel: 021-61259108 18621169109
Fax: 86-21-61259102
Email: market03@meryer.com
Country: China
ProdList: 40228
Advantage: 62

Alfa Aesar

Tel: 400-6106006
Fax: 021-67582001/03/05
Email: saleschina@alfa-asia.com
Country: China
ProdList: 30123
Advantage: 84

TCI (Shanghai) Development Co., Ltd.

Tel: 021-67121386
Fax: 021-67121385
Email: Sales-CN@TCIchemicals.com
Country: China
ProdList: 24529
Advantage: 81

Energy Chemical

Tel: 021-021-58432009 400-005-6266
Fax: 021-58436166
Email: sales8178@energy-chemical.com
Country: China
ProdList: 44688
Advantage: 61

Tianjin heowns Biochemical Technology Co., Ltd.

Tel: 400 638 7771
Email: sales@heowns.com
Country: China
ProdList: 14435
Advantage: 57

TOKYO CHEMICAL INDUSTRY CO., LTD.

Tel: 03-36680489
Fax: 03-3668-0520
Email: Sales-JP@TCIchemicals.com
Country: Japan
ProdList: 28387
Advantage: 80

TCI Europe

Tel: 320-37350700
Fax: +32 (0)37350701
Email: sales@tcieurope.eu
Country: Europe
ProdList: 23671
Advantage: 75

TCI AMERICA

Tel: 800-4238616
Fax: +1-888-520-1075 / +1-503-283-1987
Email: sales@tciamerica.com
Country: Americas
ProdList: 23653
Advantage: 75

Bide Pharmatech Ltd.

Tel: 400-164-7117 13681763483
Fax: +86-21-61629029
Email: product02@bidepharm.com
Country: China
ProdList: 41462
Advantage: 60

Shanghai Tombiopharma Chemical Co. Ltd.

Tel: 13391076197
Email: tombiopharma@163.com
Country: China
ProdList: 4987
Advantage: 55

More

Less

View Lastest Price from 3',5'-Dibromo-2'-hydroxyacetophenone manufacturers

Career Henan Chemica Co

Product: 3',5'-Dibromo-2'-hydroxyacetophenone 22362-66-9
Price: US $9.20/ASSAYS
Min. Order: 1KG
Purity: 99%
Supply Ability: Customized
Release date: 2020-10-27

22362-66-9, 3',5'-Dibromo-2'-hydroxyacetophenoneRelated Search:

2-Bromoacetophenone 2',6'-Dihydroxyacetophenone 2',5'-Dihydroxyacetophenone 3,5-Dihydroxyacetophenone 3-Nitroacetophenone 3'-Hydroxyacetophenone 2-HYDROXYACETOPHENONE Chalcone 4'-Hydroxyacetophenone 2',4',6'-Trihydroxyacetophenone monohydrate 2'-Hydroxyacetophenone Acetophenone 4-Nitroacetophenone 2,4-Dihydroxyacetophenone 4'-Methylacetophenone 2,5'-DIBROMO-2'-HYDROXYACETOPHENONE 3',5'-DIBROMO-4'-HYDROXYACETOPHENONE,3,5-DIBROMO-4-HYDROXYACETOPHENONE 6,8-DIBROMOFLAVONE

3',5'-DIBROMO-2'-HYDROXYPHENYLPROPIOPHENONE

3',5'-DIBROMO-2'-HYDROXYACETOPHENONE

3,5-DIBROMO-2-HYDROXYACETOPHENONE

AKOS BBS-00006933

1-(3,5-DIBROMO-2-HYDROXYPHENYL)ETHANONE

TIMTEC-BB SBB005396

1-(3,5-DIBROMO-2-HYDROXYPHENYL)-1-ETHANONE

,5&acute

3&acute

-Dibromo-2&acute

-hydroxyacetophenone

3' 5'-DIBROMO-2'-HYDROXYACETOPHENONE 9&

1-(3,5-dibromo-2-hydroxyphenyl)ethan-1-one

6,8-dibromo-2-oxo-1-benzopyran-3-carboxylic acid

3',5'-Dibromo-2'-hydroxyacetophenone &gt

Ethanone, 1-(3,5-dibromo-2-hydroxyphenyl)-

3',5'-Dibromo-2'-hydroxyacetophenone

2-acetyl-4,6-dibromophenol

22362-66-9

Br2C6H2OHCOCH3

C8H6O2Br2

Building Blocks

C7 to C8

Carbonyl Compounds

Ketones

Organic Building Blocks

Aromatic Acetophenones & Derivatives (substituted)