ChemicalBook > CAS DataBase List > CYCLOPENTYLZINC BROMIDE

CYCLOPENTYLZINC BROMIDE

Product Name
CYCLOPENTYLZINC BROMIDE
CAS No.
171860-68-7
Chemical Name
CYCLOPENTYLZINC BROMIDE
Synonyms
CYCLOPENTYLZINC BROMIDE;Zinc, bromocyclopentyl-;bromozinc(1+),cyclopentane;cyclopentylzinc(II) broMide;cyclopentylzinc bromide solution;Cyclopentylzinc bromide, 0.50 M in THF;Cyclopentylzinc bromide solution 0.5 in THF;Cyclopentylzinc broMide solution 0.5 M in THF;Cyclopentylzinc broMide, 0.5 M solution in THF, SpcSeal;CYCLOPENTYLZINC BROMIDE, 0.5M SOLUTION I N TETRAHYDROFURAN
CBNumber
CB6381277
Molecular Formula
C5H9BrZn
Formula Weight
214.42
MOL File
171860-68-7.mol
More
Less

CYCLOPENTYLZINC BROMIDE Property

Density 
0.955 g/mL at 25 °C
Flash point:
1 °F
storage temp. 
2-8°C
Water Solubility 
Reacts with water.
Sensitive 
Air Sensitive
Exposure limits
ACGIH: TWA 50 ppm; STEL 100 ppm (Skin)
OSHA: TWA 200 ppm(590 mg/m3)
NIOSH: IDLH 2000 ppm; TWA 200 ppm(590 mg/m3); STEL 250 ppm(735 mg/m3)
More
Less

Safety

Hazard Codes 
F,Xn
Risk Statements 
11-14-19-22-36/37/38-40-36/37
Safety Statements 
16-26-33-36-36/37
RIDADR 
UN 3399 4.3/PG 2
WGK Germany 
1
HazardClass 
4.3
HS Code 
29319090
More
Less

Hazard and Precautionary Statements (GHS)

Symbol(GHS)
Signal word
Danger
Hazard statements

H225Highly Flammable liquid and vapour

H261In contact with water releases flammable gas

H302Harmful if swallowed

H314Causes severe skin burns and eye damage

H315Causes skin irritation

H318Causes serious eye damage

H319Causes serious eye irritation

H333May be harmful if inhaled

H335May cause respiratory irritation

H351Suspected of causing cancer

Precautionary statements

P210Keep away from heat/sparks/open flames/hot surfaces. — No smoking.

P223Keep away from any possible contact with water, because of violent reaction and possible flash fire.

P231+P232Handle under inert gas. Protect from moisture.

P280Wear protective gloves/protective clothing/eye protection/face protection.

P303+P361+P353IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

P305+P351+P338IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

P370+P378In case of fire: Use … for extinction.

P402+P404Store in a dry place. Store in a closed container.

P403+P235Store in a well-ventilated place. Keep cool.

P405Store locked up.

More
Less

N-Bromosuccinimide Price

Sigma-Aldrich
Product number
498041
Product name
Cyclopentylzinc bromide solution
Purity
0.5 M in THF
Packaging
50ml
Price
$335
Updated
2024/03/01
Alfa Aesar
Product number
H58764
Product name
Cyclopentylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal? bottles
Packaging
50ml
Price
$213.65
Updated
2024/03/01
Rieke Metals
Product number
2028
Product name
Cyclopentylzincbromide
Packaging
50mL
Price
$280
Updated
2021/12/16
Rieke Metals
Product number
2429
Product name
Cyclopentylzincbromide
Packaging
50mL
Price
$290
Updated
2021/12/16
Matrix Scientific
Product number
121890
Product name
Cyclopentylzincbromide
Purity
0.50MinTHF97%
Packaging
50ml
Price
$425
Updated
2021/12/16
More
Less

CYCLOPENTYLZINC BROMIDE Chemical Properties,Usage,Production

Uses

Cyclopentylzinc bromide is an organozinc reagent that can be used in:

  • The synthesis of polyfunctional indoles by reacting with various aryldiazonium salts via Fischer indole synthesis.
  • Negishi cross-coupling reactions with various haloarenes in presence of Pd-complex catalyst.
  • The preparation of aryl alkyl ketones by alkylation of aryl N-methyl-N-tosyl or N-benzyl-N-(tert-butoxycarbonyl) amide derivatives in the presence of Ni catalyst and imidazolidinylidene ligand.

CYCLOPENTYLZINC BROMIDE Preparation Products And Raw materials

Raw materials

Preparation Products

More
Less

CYCLOPENTYLZINC BROMIDE Suppliers

3B Scientific Corporation
Tel
--
Fax
--
Email
sales@3bsc.com
Country
United States
ProdList
6718
Advantage
47
Rieke Metals, Inc.
Tel
--
Fax
--
Email
sales@riekemetals.com
Country
United States
ProdList
6509
Advantage
69
Riedel-de Haen AG
Tel
--
Fax
--
Country
United States
ProdList
6773
Advantage
87
Matrix Scientific
Tel
--
Fax
--
Email
sales@matrixscientific.com
Country
United States
ProdList
6632
Advantage
80

171860-68-7, CYCLOPENTYLZINC BROMIDERelated Search:


  • CYCLOPENTYLZINC BROMIDE
  • cyclopentylzinc bromide solution
  • CYCLOPENTYLZINC BROMIDE, 0.5M SOLUTION I N TETRAHYDROFURAN
  • Cyclopentylzinc bromide solution 0.5 in THF
  • Cyclopentylzinc broMide, 0.5M in THF, packaged under Argon in resealable CheMSeal^t bottles
  • cyclopentylzinc(II) broMide
  • Cyclopentylzinc broMide solution 0.5 M in THF
  • Cyclopentylzinc broMide, 0.5 M solution in THF, SpcSeal
  • Zinc, bromocyclopentyl-
  • Cyclopentylzinc bromide, 0.50 M in THF
  • Cyclopentylzinc bromide, Packaged under Argon in resealable ChemSeal? bottles
  • Cyclopentylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal&trade
  • bromozinc(1+),cyclopentane
  • 171860-68-7
  • C5H9BrZn
  • C5H9ZnBr
  • Organozinc Halides
  • Organometallic Reagents
  • Reike and Organozinc Reagents
  • Alkyl
  • Alkyl
  • Organozinc Halides
  • Reike and Organozinc Reagents